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Phase-change foamied insulation board based on phenolic foam waste, and preparation method thereof

A foam insulation board and phenolic foam technology, applied in the field of building materials, can solve the problems of less storage capacity of phase change materials, shorten the service life of building materials, and low mechanical strength of building materials, so as to improve indoor comfort and thermal insulation performance , Solve the effect of liquid phase leakage

Inactive Publication Date: 2020-12-01
张瑞水
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the methods of applying phase change materials to building materials mainly include: 1) Porous material adsorption method: add porous building materials to molten phase change materials, and use the capillary adsorption force of the material pores to adsorb the phase change materials on the surface of the material. 2) direct addition method: phase change material is used as a component of building materials, and physical doping is directly carried out in the preparation stage of building materials; 3) microcapsule method is to wrap phase change material particles into a layer of stable performance Polymer membranes, which are solid particles with a core-shell structure formed by sealing them in microcapsules formed by polymer membranes; but the above methods all have shortcomings, such as the materials prepared by the porous material adsorption method will lose The problem of liquid phase leakage occurs. The direct addition method will cause less storage of phase change materials. During long-term use, phase change materials are prone to phase separation of building materials, thereby reducing the service life of building materials. Although the microencapsulation method can isolate phase change materials Direct contact with the external environment solves the problem of liquid phase leakage, but all phase change materials are used as the inner core material, and the building materials have low mechanical strength and are prone to creep, especially after the internal phase change materials are all converted into liquid phase, and the production Expensive, high technical requirements, need to use a large amount of phase change substances

Method used

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  • Phase-change foamied insulation board based on phenolic foam waste, and preparation method thereof
  • Phase-change foamied insulation board based on phenolic foam waste, and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A preparation method of a phase-change foam insulation board based on phenolic foam waste, comprising the following steps:

[0026] S1: Preparation of organic phase-change thermal insulation material: in parts by mass, heat and melt 10 parts of capric acid, 0.8 parts of myristic acid, and 6 parts of myristyl alcohol at 65°C, add an emulsifier, stir evenly, and then add 100 parts of porous polymer Styrene microspheres, in an environment with a vacuum degree of 0.03MPa and a temperature of 40°C, stirred and adsorbed for 1h, then cooled and crystallized at 15°C for 2h, stirred continuously during the crystallization process, and then added 30 parts of silicone styrene-acrylic emulsion. Under the irradiation of a 100W ultraviolet lamp, after curing at 25°C to form a film, an organic phase change thermal insulation material is obtained;

[0027] S2: Prepare an alkali activator: mix sodium hydroxide, trisodium phosphate, and sodium citrate evenly in a mass ratio of 1:1:0.5; ...

Embodiment 2

[0037] A preparation method of a phase-change foam insulation board based on phenolic foam waste, comprising the following steps:

[0038] S1: Preparation of organic phase-change thermal insulation material: in parts by mass, heat and melt 12.5 parts of capric acid, 1.5 parts of myristic acid, and 7 parts of myristyl alcohol at 70°C, add an emulsifier, stir evenly, and then add 100 parts of porous polymer Styrene microspheres, under the environment of vacuum degree of 0.05MPa and temperature of 45°C, stirred and adsorbed for 1.5h, then cooled and crystallized at 15°C for 4h, stirred continuously during the crystallization process, and then added 35 parts of silicone styrene-acrylic emulsion, in Under the irradiation of a UV lamp with a power of 100W, after curing at 25°C to form a film, an organic phase change thermal insulation material is obtained;

[0039] S2: Prepare an alkali activator: mix sodium hydroxide, trisodium phosphate, and sodium citrate evenly according to a ma...

Embodiment 3

[0049] A preparation method of a phase-change foam insulation board based on phenolic foam waste, comprising the following steps:

[0050] S1: Preparation of organic phase-change thermal insulation material: in parts by mass, heat and melt 15 parts of capric acid, 2 parts of myristic acid, and 8 parts of myristyl alcohol at 70°C, add an emulsifier, stir evenly, and then add 100 parts of porous polymer Styrene microspheres, in an environment with a vacuum degree of 0.07MPa and a temperature of 50°C, stirred and adsorbed for 2 hours, then cooled and crystallized at 20°C for 6 hours, stirred continuously during the crystallization process, and then added 40 parts of silicone styrene-acrylic emulsion. Under the irradiation of a 100W ultraviolet lamp, after curing at 25°C to form a film, an organic phase change thermal insulation material is obtained;

[0051] S2: Prepare the alkali activator: mix sodium hydroxide, trisodium phosphate, and sodium citrate evenly according to the mas...

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Abstract

The invention discloses a phase-change foamed insulation board based on phenolic foam waste, and a preparation method thereof. The phase-change foamed insulation board comprises, by mass, 30-40 partsof phenolic foam waste, 15-25 parts of an organic phase-change thermal insulation material, 25-35 parts of cement, 15-20 parts of fly ash, 10-15 parts of desulfurized gypsum powder, 2-3 parts of an alkali activator, 1-1.5 parts of a silane coupling agent, 3-4 parts of a foaming agent A, 5-10 parts of a foaming agent B and 30-40 parts of water. The foamed insulation board is prepared by taking thephenolic foam waste as the raw material for the first time, so that the foamed insulation board has the characteristics of light weight, fire prevention, heat preservation, heat insulation and flame retardance, opens up a new thought for resource utilization of the phenolic foam waste and improves the added value of the phenolic foam waste.

Description

technical field [0001] The invention belongs to the technical field of building materials, and in particular relates to a phase-change foam insulation board based on phenolic foam waste and a preparation method thereof. Background technique [0002] Phenolic foam is foamed from thermosetting phenolic resin. It is known as the "king of thermal insulation materials" and is a new generation of thermal insulation, fireproof and sound insulation materials. Phenolic foam has the characteristics of light weight, fireproof, non-combustible in case of open flame, smokeless, non-toxic, non-dripping, wide range of operating temperature (-196~+200℃), non-shrinking and non-brittle in low temperature environment. Due to the high closed cell rate of phenolic foam, low thermal conductivity, good thermal insulation performance, and certain water resistance and water vapor permeability, at the same time, because phenolic foam has a benzene ring structure, it is dimensionally stable. Compared ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B28/14C04B38/10C04B38/02C04B24/12C04B24/20C04B20/10C04B103/42C04B111/40C04B111/28C04B18/20C04B16/08C04B24/08C04B24/02
CPCC04B20/1051C04B28/144C04B38/02C04B38/10C04B40/0039C04B2103/42C04B2111/28C04B2111/40C04B18/20C04B16/08C04B24/085C04B24/026C04B7/00C04B18/08C04B22/062C04B24/06C04B22/16C04B24/42C04B22/106C04B24/129C04B24/10C04B24/20C04B24/122C04B24/14Y02W30/91
Inventor 张瑞水陈晓敏
Owner 张瑞水
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