Ultra-thin electronic glass fiber cloth surface treatment fluid and preparation method thereof

A technology of electronic glass fiber cloth and surface treatment liquid, which is applied in fiber processing, textile material processing, liquid/gas/vapor textile processing, etc. The cloth is prone to problems such as bubble delamination and adverse effects on the performance of copper clad laminates, to achieve the effect of improving heat resistance and ion migration resistance, improving heat resistance and ion migration resistance, and maintaining mechanical properties.

Active Publication Date: 2020-08-25
山东兴国大成电子材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The applicant found through research that the existing surface treatment liquid has the following problems: First, the electronic glass fiber cloth treated with the existing surface treatment liquid has poor heat resistance, and the electronic glass fiber cloth is prone to bubble stratification after long-term high-temperature cooking Problem; secondly, the electronic glass fiber cloth treated with the existing surface treatment liquid and the ion migration resistance are not good, which has a negative impact on the performance of the copper clad laminate

Method used

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  • Ultra-thin electronic glass fiber cloth surface treatment fluid and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0030] Embodiments 1 to 5 are specific examples of an ultra-thin electronic glass fiber cloth surface treatment liquid and a preparation method thereof of the present invention, wherein embodiment 1 is the best implementation mode.

[0031] Y-Aminopropyltrimethoxysilane, CAS: 13822-56-5, Zouping Mingxing Chemical Co., Ltd., content ≥99%;

[0032] N-(2-aminoethyl)-3-aminopropyltrimethoxysilane, CAS: 1760-24-3, Zibo Linzi Qiquan Industry and Trade Co., Ltd., content ≥99%;

[0033] 3-(2,3-Glycidyloxypropoxy)propyltrimethoxysilane, CAS: 2530-83-8, Zibo Linzi Qiquan Industry and Trade Co., Ltd., content ≥99%;

[0034] Acetic acid, Yantai Sunkang Biotechnology Co., Ltd., content ≥ 99.5%;

[0035] Citric acid, Yantai Sunkang Biotechnology Co., Ltd., content ≥99.5%;

[0036] Defoamer, Zhuhai Zhanyang Chemical Co., Ltd., defoamer SS-013A.

[0037] Example 1

[0038] The present embodiment comprises the following raw materials by weight: 98 parts of water, surface treatment agent [Y...

Embodiment 2

[0043] The present embodiment comprises the following raw materials by weight: 98 parts of water, surface treatment agent [Y-aminopropyltrimethoxysilane and N-(2-aminoethyl)-3-aminopropyltrimethoxysilane by weight 1:1 mixing] 1.2 parts, 0.5 parts of acetic acid, 0.008 parts of defoamer;

Embodiment

[0044] The preparation method of embodiment, comprises the following steps:

[0045] 1) Control the water temperature to 30°C, add the surface treatment agent and defoamer to the water in parts by weight, and stir evenly to obtain a mixed solution;

[0046] 2) Add a weak acid to the mixed solution in parts by weight to obtain the surface treatment solution for ultra-thin electronic glass fiber cloth.

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Abstract

The invention provides ultra-thin electronic glass fiber cloth surface treatment fluid and a preparation method thereof, and belongs to the technical field of electronic grade glass fiber surface treatment. The ultra-thin electronic glass fiber cloth surface treatment fluid comprises the following raw materials in parts by weight: 98 parts of water, 1.1 to 1.5 parts of surface treating agent, 0.1to 1 part of weak acid, and 0.002 to 0.01 part of antifoaming agent; the surface treating agent comprises Y-aminopropyltrimethoxysilane and N-(2-aminoethyl)-3-aminopropyltrimethoxysilane; and the Y-aminopropyltrimethoxysilane and the N-(2-aminoethyl)-3-aminopropyltrimethoxysilane are mixed according to a weight ratio of 1.1 to 1.3:1. The ultra-thin electronic glass fiber cloth surface treatment fluid provided by the invention increases the bonding force between resins and glass fiber cloths, improves the heat resistance and ion migration resistance of electronic glass fiber cloths, and makes the electronic glass fiber cloths more suitable for manufacturing high-end printed circuit copper clad laminates.

Description

technical field [0001] An ultra-thin electronic glass fiber cloth surface treatment liquid and a preparation method thereof belong to the technical field of electronic grade glass fiber surface treatment. Background technique [0002] Electronic glass fiber cloth woven from electronic grade glass fiber, referred to as electronic glass fiber cloth, is an essential basic material for copper clad laminate and printed circuit board industry, and its performance determines the quality of copper clad laminate and printed circuit board to a large extent. Electrical properties, mechanical properties, dimensional stability and other important properties. [0003] The warp and weft yarns used in the electronic glass fiber cloth for copper clad laminates, each yarn is made of a single fiber with a diameter of 5-9um and a number of 400-800 single filaments. During the drawing process, the surface is coated with a layer of sizing agent to ensure that each The adhesion of the ply yarn al...

Claims

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Application Information

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IPC IPC(8): D06M13/513D06B3/18
CPCD06M13/513D06B3/18D06M2200/50
Inventor 李宝明郑木松王登宝崔淑利齐贵山亓顺利
Owner 山东兴国大成电子材料有限公司
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