Composite adsorbent for efficiently removing mixed pollutants in wastewater and preparation method of composite adsorbent
A composite adsorption and pollutant technology, applied in water pollutants, alkali metal compounds, water/sewage treatment, etc., to achieve the effect of high reusability, high yield and simple reaction conditions
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[0030] The present embodiment prepares the composite adsorbent for efficiently removing antibiotics and heavy metal ions in wastewater according to the following steps:
[0031] Step 1, preparation of nano-flaky zinc oxide microsphere material
[0032] Under magnetic stirring, 3 mmol of zinc acetate Zn(Ac) 2 2H 2 O, 6mmol urea CO(NH 2 ) 2 Dissolve 0.3mmol trisodium citrate in 75mL deionized water, continue to stir for 30min, then transfer to a 100mL stainless steel autoclave lined with Teflon, and react in an oven at 120°C for 6h;
[0033] After the reaction, the obtained product was washed sequentially with deionized water and absolute ethanol, and dried in a vacuum oven at 80°C for 12 hours to obtain zinc carbonate and zinc hydroxide precursors, which were designated as ZHC precursors;
[0034] The ZHC precursor was calcined in the air at 300°C for 2 hours to obtain nano-flaky zinc oxide microspheres;
[0035] Step 2. Preparation of ZnO@Zn-MO-74 composite material
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