High-flame-retardant DOPO functionalized graphene oxide/ZIF-8 composite material and preparation method thereof
A technology of ZIF-8 and composite materials, which is applied in the field of high flame-retardant DOPO functionalized graphene oxide/ZIF-8 composite materials and its preparation, achieving good environmental compatibility, low cost and simple process
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[0020] The invention relates to a preparation method of a highly flame-retardant DOPO functionalized graphene oxide / ZIF-8 composite material.
[0021] Specifically, it is realized by the following steps:
[0022] Dissolve 1.5-3.0 parts of zinc nitrate in 8 parts of deionized water, stir magnetically for 10 minutes, then add 0.3-0.6 parts of DOPO functionalized graphene oxide, stir and sonicate for 30 minutes to obtain solution A; 28.7-57.4 parts of 2-methylimidazole Dissolve in 80 parts of deionized water, stir magnetically for 10 minutes to obtain solution B, pour solution B into solution A, stir for 120 minutes; centrifuge at 10,000 r / min for 10 minutes, wash with deionized water several times, and dry at 65°C to obtain D-GO / ZIF-8 composite. The above proportions are parts by weight.
Embodiment 1
[0024] Dissolve 1.5 parts of zinc nitrate in 8 parts of deionized water, stir magnetically for 10 minutes, then add 0.3 parts of DOPO functionalized graphene oxide, stir and sonicate for 30 minutes to obtain solution A; 28.7 parts of 2-methylimidazole are dissolved in 80 parts of deionized In water, magnetically stirred for 10 minutes to obtain solution B. Pour solution B into solution A and stir for 120 minutes; centrifuge at 10,000 r / min for 10 minutes, wash with deionized water several times, and dry at 65°C to obtain D-GO / ZIF-8 composite material . The above proportions are parts by weight.
[0025] Wherein, the preparation method of DOPO functionalized graphene oxide:
[0026] (1) Synthesis of phosphorus-containing silicon compound:
[0027] In a 50 mL reaction vessel, add 2.27 g of 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, 1.11 g of γ-aminopropyltriethoxysilane, and 0.32 g of paraformaldehyde Dissolve it in 30 mL of chloroform, and stir for 24 h at a reactio...
Embodiment 2
[0031] 2.3 parts of zinc nitrate were dissolved in 8 parts of deionized water, stirred magnetically for 10 minutes, then 0.5 parts of DOPO functionalized graphene oxide was added, stirred and ultrasonically treated for 30 minutes to obtain solution A; 43.0 parts of 2-methylimidazole was dissolved in 80 parts of deionized In water, magnetically stirred for 10 minutes to obtain solution B. Pour solution B into solution A and stir for 120 minutes; centrifuge at 10,000 r / min for 10 minutes, wash with deionized water several times, and dry at 65°C to obtain D-GO / ZIF-8 composite material . The above proportions are parts by weight.
[0032] Wherein, the preparation method of DOPO functionalized graphene oxide is the same as that in Example 1.
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