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Permeable closed amphoteric emulsion for primer and preparation method thereof

A technology of sealing and primer, applied in the direction of primer, coating, etc., can solve the problems of vigorous promotion and application of unsealable primer, wall foundation reinforcement performance that cannot be loosened, and insufficient maintenance time of cement substrate, etc., to achieve excellent Penetration reinforcement performance, improvement of permeability performance, and strong anti-salinity performance

Inactive Publication Date: 2020-06-05
广东巴德富新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the mainstream primer product on the market is anionic acrylate emulsion, which has good stability after being formulated with primer, and its performance basically meets the requirements of the market under normal circumstances, but in actual construction projects, there are often problems caused by irregular construction. As a result, the maintenance time of the cement base material is not enough, the base material is alkaline or the salt content is too high, and the exterior wall paint is pan-alkaline or blooming, which seriously affects customer satisfaction, and the film-forming primer commonly used in the market cannot be loose The wall base provides reinforcement
[0003] Cationic acrylate emulsion has excellent penetration reinforcement and anti-salt alkali resistance, but because of its unique cationicity, it has certain defects in paint preparation and workability, and cannot be used on the closed primer. Promote application

Method used

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  • Permeable closed amphoteric emulsion for primer and preparation method thereof
  • Permeable closed amphoteric emulsion for primer and preparation method thereof
  • Permeable closed amphoteric emulsion for primer and preparation method thereof

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preparation example Construction

[0033] In addition, the present invention also provides a method for preparing the amphoteric emulsion for the penetration-blocking primer, comprising the following steps:

[0034] 1) Preparation of pre-emulsion: Add 1.5-3.75 parts of emulsifier and 40-85 parts of deionized water into the emulsification tank under normal temperature and pressure. After fully stirring and dissolving, slowly add the formula amount of benzene while stirring Ethylene, n-butyl acrylate in formulated amount, isooctyl acrylate in formulated amount, glycidyl methacrylate in formulated amount, cationic monomer in formulated amount, anionic monomer in formulated amount, hydrophilic monomer in formulated amount, 0.4 - 2 parts of cross-linking monomer and 0.3-1.2 parts of initiator, fully stirred for 30-40 minutes to obtain a pre-emulsion;

[0035] 2) Preparation of seed emulsion: under normal temperature and pressure, add the remaining amount of emulsifier and the remaining amount of deionized water into...

Embodiment 1

[0039] An amphoteric emulsion for a penetrating and sealing primer, made of the following raw materials in parts by mass: 60 parts of deionized water, 50 parts of styrene, 5 parts of n-butyl acrylate, 5 parts of isooctyl acrylate, and 2 parts of emulsifier Parts, 2 parts of glycidyl methacrylate, 3 parts of lauryl methacrylate, 3 parts of methyl erucate, 2 parts of cationic monomer, 2 parts of anionic monomer, 1 part of cross-linking monomer, hydrophilic 3 parts of monomer, 1 part of initiator.

[0040] The emulsifier is mixed with N-(ethyl 1,2-dicarboxylate)-N-octadecylamine sulfosuccinate sodium salt and polyethylene glycol methacrylate at a mass ratio of 2:1. The cross-linking monomer adopts trimethylolpropane trimethacrylate.

[0041] The cationic monomer is mixed with acryloyloxyethyl trimethyl ammonium chloride and dimethyl diallyl ammonium chloride at a mass ratio of 1:1. The anionic monomer adopts acrylic acid.

[0042] The hydrophilic monomer is mixed with acrylami...

Embodiment 2

[0052] An amphoteric emulsion for a penetrating and sealing primer, made of the following raw materials in parts by mass: 70 parts of deionized water, 60 parts of styrene, 10 parts of n-butyl acrylate, 10 parts of isooctyl acrylate, and 3 parts of emulsifier 5 parts, glycidyl methacrylate 5 parts, lauryl methacrylate 5 parts, methyl erucate 5 parts, cationic monomer 5 parts, anionic monomer 3 parts, crosslinking monomer 2 parts, hydrophilic 5 parts of monomer, 1.5 parts of initiator.

[0053] The emulsifier is mixed with cetyltrimethylammonium bromide and allyloxypolyoxyethylene ether in a mass ratio of 5:1.

[0054] The crosslinking monomer is mixed with vinyl tris(methoxyethoxy)silane and pentaerythritol triallyl ether in a mass ratio of 1:1.

[0055] The cationic monomer is mixed with acryloyloxyethyltrimethylammonium chloride, dimethyldiallylammonium chloride and dimethylaminoethyl methacrylate in a mass ratio of 1:2:1.

[0056] The anionic monomer is mixed with acrylic ...

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Abstract

The invention discloses a permeable closed amphoteric emulsion for a primer. The amphoteric emulsion is prepared from the following raw materials in parts by weight: 50 to 110 parts of deionized water; 10-60 parts of styrene, 5 to 20 parts of n-butyl acrylate; 5-20 parts of iso-octyl acrylate, 2-5 parts of an emulsifier, 2-5 parts of glycidyl methacrylate, 2-5 parts of dodecyl methacrylate, 2-5 parts of methyl erucate, 2-5 parts of a cationic monomer, 2-5 parts of an anionic monomer, 0.5-2.5 parts of a crosslinking monomer, 1-5 parts of a hydrophilic monomer and 0.5-2 parts of an initiator. The emulsion is zwitter-ionic amphoteric emulsion for permeable closed primer, and has excellent paint preparation stability, excellent permeation reinforcing performance and salt and alkali flooding resistance.

Description

technical field [0001] The invention relates to an amphoteric emulsion for a penetrating sealing primer and a preparation method thereof, belonging to the field of primer emulsions. Background technique [0002] With the gradual advancement of economic development and urbanization, architectural coatings have gradually become the main material for building interior and exterior wall decoration, and the role of primers has attracted more and more attention. At present, the mainstream primer product on the market is anionic acrylate emulsion, which has good stability after being formulated with primer, and its performance basically meets the requirements of the market under normal circumstances, but in actual construction projects, there are often problems caused by irregular construction. As a result, the maintenance time of the cement base material is not enough, the base material is alkaline or the salt content is too high, and the exterior wall paint is pan-alkaline or blo...

Claims

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Application Information

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IPC IPC(8): C08F212/08C08F220/18C08F220/32C08F222/14C08F220/34C08F226/02C08F220/06C08F220/56C08F220/20C08F220/28C08F230/08C08F216/12C08F222/02C08F216/14C08F2/26C08F2/30C08F2/28C09D125/14C09D5/00
CPCC08F212/08C09D5/002C09D125/14C08F2/26C08F2/30C08F2/28
Inventor 黄顺基唐兵张稹韩庆强
Owner 广东巴德富新材料有限公司
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