Method for preparing co-sensitized thin film through bidirectional diffusion technology

A co-sensitization and bi-directional technology, applied in the field of nanomaterials, can solve problems such as the difficulty in preparing co-sensitized films, and achieve the effect of solving the problem of space occupation competition

Inactive Publication Date: 2020-05-15
NANCHANG HANGKONG UNIVERSITY
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  • Summary
  • Abstract
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  • Claims
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Problems solved by technology

However, the existing technology is to immerse the semiconductor film in the dye solution. This method only passively controls the adsorption of the dye in one direction, which not only causes the occupation of the dye molecules, the amount of adsorption and the interaction between the dye molecules. Contradictions, and this method is difficult to prepare co-sensitized films containing more than two dye adsorption layers

Method used

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Embodiment Construction

[0020] Embodiments of the present invention will be described in detail below through examples, so that the realization process of how to apply technical means to solve technical problems and achieve technical effects in the present invention can be fully understood and implemented accordingly.

[0021] A method for preparing a co-sensitized film by bidirectional diffusion technology, engraving a back-shaped groove on the conductive surface of conductive glass, and then filling polyethylene into the back-shaped groove; TiO 2 The paste is printed on conductive glass with back-groove, and sintered at 510°C for 30 minutes to form nanoporous TiO 2 film. Inject the dye a into the return groove, and through the capillary phenomenon, the a surface of the nano-semiconductor film will autonomously absorb and diffuse to make the entire TiO 2 The a surface of the film is adsorbed with dye a to form a single dye-sensitized TiO 2 film. To protect the back-shaped groove, use a high-press...

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Abstract

The invention discloses a method for preparing a co-sensitized thin film through a bidirectional diffusion technology. The film comprises the following steps of: (1) etching a clip-shaped groove on aconductive glass substrate; (2) filling polyethylene into the clip-shaped groove; (3) preparing a nano-porous semiconductor film on the conductive glass; (4) sintering the conductive glass in a mufflefurnace; (5) injecting a dye a into the clip-shaped groove in the sintered conductive glass; (6) after the adsorption is completed, injecting glass repair resin into the clip-shaped groove, and curing the glass repair resin to enable the resin to completely replace air in glass gaps, so that the glass and the resin are completely bonded into a whole; and (7) immersing the semiconductor thin filmadsorbed with the dye a into a second dye b solution to prepare the co-sensitized thin film. According to the invention, a plurality of dye adsorption layers can be obtained, and dye molecules of eachadsorption layer do not interfere with each other.

Description

technical field [0001] The invention relates to the technical field of nanometer materials, in particular to a method for preparing co-sensitized thin films by bidirectional diffusion technology. Background technique [0002] Solar photovoltaic power generation provides a good solution to the environmental problems caused by energy shortage and non-renewable energy consumption, and solar cells as power generation components have also received extensive attention from researchers. There are many kinds of solar cells, but due to their low cost (only 1 / 5-1 / 10 of silicon-based solar cells), non-toxic, non-polluting, high theoretical conversion efficiency, and simple preparation process, dye-sensitized solar cells have attracted much attention. people's eyes. And as a new type of solar cell, the working principle of DSSC cell is completely different from that of traditional solar cells, and has become a hot research topic at present. [0003] In the initial research of DSSC cel...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G9/042H01G9/20
CPCH01G9/20H01G9/2031Y02E10/542
Inventor 施菁刘伟庆吴宗建毛志敏蔡洪峰赵思瑞
Owner NANCHANG HANGKONG UNIVERSITY
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