Micro-powder soil conditioner and preparation method thereof
A technology of soil conditioner and micropowder, which is applied in the direction of soil conditioning materials, chemical instruments and methods, and other chemical processes. It can solve the problems of poor water absorption and inability to act quickly, so as to increase water absorption and improve soil organic matter. content, improving soil organic matter and fertility
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Embodiment 1
[0044] Embodiment 1 basic performance detection method
[0045] Determination of sulfonation degree:
[0046] Weigh with an analytical balance and heat to dissolve to accurately prepare 0.001M CTAB solution;
[0047] Weigh 0.2g of sulfonated humic acid sample, add it into 500mL of distilled water to swell for 12 hours, then dilute to 1L;
[0048] Take 10mL sulfonated humic acid sample solution and add 30mL distilled water to dilute, and titrate with 0.001M CTAB solution;
[0049] During the titration, the conductivity was measured with a conductivity meter until the conductivity vs. CTAB solution volume curve showed an obvious turning point and terminated;
[0050] Calculate the sulfonation degree=103CV / m×100%, C is the CTAB concentration (mol / L), V is the volume (L) of the turning point CTAB, and m is the lignite sulfonated humic acid mass (g).
[0051] Surface tension measurement
[0052] Accurately prepare 1% (w / v) humic acid / sulfonated humic acid, and use SITA t-100 su...
Embodiment 2
[0058] The preparation of embodiment 2 brown coal humate potassium
[0059] Use a crusher to crush the lignite to fine particles below 15 mesh;
[0060] Add the fine particles to 0.6 times the mass of 20% H 2 O 2 In the solution, stir at 50 degrees Celsius for 30 minutes;
[0061] The obtained mixture was added to 1.5 times the mass of 1.5% KOH aqueous solution, and the stirring was continued for 30 minutes at 60 degrees Celsius;
[0062] The solid was removed by centrifugation and filtered, and concentrated HCl was added to the obtained filtrate with stirring to adjust the pH to a large amount of black precipitation;
[0063] The precipitated precipitate is filtered and dried, and the obtained filter cake is the lignite potassium humate.
[0064] In addition, upon verification by the applicant, H 2 O 2 Oxidation is not an essential step, and removing this step will reduce the yield by about 10%; in practice, this step can be chosen according to the raw material compositio...
Embodiment 3
[0065] The preparation of embodiment 3 sulfonated lignite potassium humate
[0066] Dissolve potassium lignite humate in 10 times the mass of water, add 1% mass of H 2 SO 4 and 4% mass K 2 SO 3 , and reacted for 2 hours at 50 degrees Celsius;
[0067] The solution was dried to obtain potassium sulfonated lignite humate product (1).
[0068] Use 8%H 2 SO 4 Sulfonation is carried out under similar conditions to obtain sulfonated lignite potassium humate product (2).
[0069] Use 5%K 2 SO 3 Sulfonation is carried out under similar conditions to obtain sulfonated lignite potassium humate product (3).
[0070] Use 3%H 2 SO 4 and 3%K 2 SO 3 Sulfonation is carried out under similar conditions to obtain sulfonated lignite potassium humate product (4).
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