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Preparation method of light-transmitting heat-insulating glass

A technology of insulating glass and preparation steps, applied in the direction of coating, etc., can solve the problems of general thermal insulation performance and light transmission of insulating glass, and achieve the effects of reducing the induced dipole moment, narrowing the particle size distribution, and reducing scattering

Inactive Publication Date: 2020-05-08
梁官生
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] The main technical problem to be solved by the present invention is to provide a method for preparing light-transmitting and heat-insulating glass in view of the current defects of light-transmitting and heat-insulating performance of heat-insulating glass

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] The silane coupling agent is: γ-aminopropyltriethoxysilane

[0035] Preparation of the dispersion:

[0036] In terms of parts by weight, add 30 parts of absolute ethanol and 5 powders of hydroxyapatite powder to the ultrasonic oscillator, and use the frequency of 30kHz to ultrasonically vibrate for 5min to obtain a suspension, which is placed in a cone with a stirrer In the conical flask, add 18 parts of tetrabutyl titanate to the Erlenmeyer flask at a dropping rate of 4 mL / min with a dropping funnel, start the stirrer at the same time, and start stirring at a speed of 300 r / min for 10 min to obtain a dispersion;

[0037] Preparation of silicon-titanium composite rubber powder:

[0038] In parts by weight, add 4 parts of acetic acid solution with a mass fraction of 20% and 20 parts of silica sol to 80 parts of the above-mentioned dispersion liquid, stir and disperse for 1 hour, and then stand and age for 2 days to obtain a dry sol. The dry sol was air-dried in a hot a...

Embodiment 2

[0049] The silane coupling agent is: γ-(2,3-epoxypropoxy)propyltrimethoxysilane

[0050] Preparation of the dispersion:

[0051] In parts by weight, add 35 parts of absolute ethanol and 6 powders of hydroxyapatite powder to the ultrasonic oscillator, with a frequency of 32.5kHz, ultrasonic vibration for 6min to obtain a suspension, which is placed in a mixer with a stirrer In the Erlenmeyer flask, add 19 parts of tetrabutyl titanate into the Erlenmeyer flask at a dropping rate of 4.5mL / min with a dropping funnel, start the stirrer at the same time, start stirring at a speed of 350r / min for 12.5min to obtain a dispersion ;

[0052] Preparation of silicon-titanium composite rubber powder:

[0053] In terms of parts by weight, add 4.5 parts of acetic acid solution and 25 parts of silica sol with a mass fraction of 20% to 85 parts of the above-mentioned dispersion liquid, stir and disperse for 1.5 hours, and then stand and age for 2.5 days to obtain a dry sol. The obtained dry ...

Embodiment 3

[0064] The silane coupling agent is: γ-methacryloxypropyltrimethoxysilane

[0065] Preparation of the dispersion:

[0066] In parts by weight, add 40 parts of absolute ethanol and 7 powders of hydroxyapatite powder to the ultrasonic oscillator, and ultrasonically vibrate for 7 minutes at a frequency of 35 kHz to obtain a suspension, which is placed in a cone with a stirrer In the conical flask, add 20 parts of tetrabutyl titanate to the Erlenmeyer flask with a dropping funnel at a dropping rate of 5mL / min, start the stirrer at the same time, start stirring at a speed of 400r / min for 15min to obtain a dispersion;

[0067] Preparation of silicon-titanium composite rubber powder:

[0068] In parts by weight, 5 parts of acetic acid solution with a mass fraction of 20% and 30 parts of silica sol were added to 90 parts of the above-mentioned dispersion liquid, stirred and dispersed for 2 hours, and left to stand for aging for 3 days to obtain a dry sol. The dry sol was air-dried i...

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Abstract

The invention belongs to the technical field of glass material preparation, and particularly relates to a preparation method of light-transmitting heat-insulating glass. According to the method, skimmilk and silicon-titanium composite rubber powder are mixed, dispersed, coated, packaged with a polytetrafluoroethylene plate and air-dried to obtain the light-transmitting heat-insulating glass, theheat-insulating glass takes PMMA organic glass as matrix glass, and the heat-insulating effect is achieved through a hydroxyapatite aerogel layer on the surface; the silicon-titanium coated hydroxyapatite aerogel is aerogel compositely coated with silicon dioxide and titanium dioxide and has high strength, the skim milk is oxidized through sodium hypochlorite and then subjected to hydroxyl modification, the adhesiveness between aerogel microspheres is improved, the induced dipole moment is reduced through zinc tin oxide between the aerogel and the glass, and the visible light transmittance isimproved; after the current-carrying light-transmitting glue solution is cured, a layered zinc tin oxide film can be formed, so that the sensitivity of the light-transmitting heat-insulating glass tovisible light is improved, near-infrared light is absorbed, the light transmittance is improved, the heat-insulating property is improved, and the light-transmitting heat-insulating glass has a wide application prospect.

Description

technical field [0001] The invention belongs to the technical field of glass material preparation, and in particular relates to a method for preparing light-transmitting heat-insulating glass. Background technique [0002] Insulating glass is a kind of performance glass, they do not significantly absorb visible light, but absorb a lot of heat-generating near-infrared light. At present, the high heat insulation performance of energy-saving glass is mainly reflected in the performance of blocking infrared and ultraviolet rays in solar radiation. If the glass cannot effectively block the heat of outdoor sunlight from entering the room, the thermal radiation of the heated glass will increase the temperature in the space, thereby reducing the comfort. At present, commercially available insulating glass absorbs short-wave radiation in sunlight, which makes the transmittance of visible light very low, thereby affecting the light transmittance of the glass. And it is greatly affec...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J7/04C08L33/12
CPCC08J7/042C08J2333/12C08J2479/02C08J2489/00
Inventor 梁官生
Owner 梁官生
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