A preparation method of a high-nickel ternary material with a transition metal element concentration gradient and the prepared material
A transition metal element, concentration gradient technology, used in electrical components, structural parts, battery electrodes, etc., can solve the problems of abnormal growth of primary particles, interdiffusion of transition metal elements, etc., to improve cycle performance, thermal stability, crystallization, etc. Good, the effect of suppressing abnormal growth
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Embodiment 1
[0030] The high-nickel ternary material with transition metal element concentration gradient of this embodiment, its precursor core chemical composition is Ni 0.83 co 0.12 mn 0.05 (OH) 2 , the chemical composition of the shell is Ni 0.5 co 0.2 mn 0.3 (OH) 2 , in this embodiment, the core-shell structure of the precursor is the method of high-speed mechanical fusion to crush Ni 0.5 co 0.2 mn 0.3 (OH) 2 Tightly coated with Ni 0.83 co 0.12 mn 0.05 (OH) 2 Formed above, the precursor core / shell mass ratio is 10:1, and the average chemical composition of the final precursor is Ni 0.800 co 0.127 mn 0.073 (OH) 2 .
[0031] Its preparation method is:
[0032] Step 1. Prepare the mixture: Ni according to the molecular formula 0.800 co 0.127 mn 0.073 (OH) 2 , calculate its molar ratio of 1:1 LiOH·H 2 The mass ratio of O. The above precursors were mixed with 3% LiOH·H 2O is added into the mixing material tank and fully mixed and stirred until uniform to obtain the...
Embodiment 2
[0036] The high-nickel ternary material with transition metal element concentration gradient of this embodiment, its precursor core chemical composition is Ni 0.95 co 0.025 mn 0.025 (OH) 2 , the contents of Ni, Co, and Mn elements gradually change from the core to the outside, until the composition is Ni 0.8 co 0.1 mn 0.1 (OH) 2 , and Ni 0.5 co 0.2 mn 0.3 (OH) 2 In this example, the gradient structure precursor is prepared by the co-precipitation method, and the core-shell structure is obtained by crushing Ni after high-speed mechanical fusion 0.5 co 0.2 mn 0.3 (OH) 2 It is formed by tightly covering the gradient precursor, the core / shell mass ratio is 10:1, and the average chemical composition of the final precursor is Ni 0.875 co 0.050 mn 0.075 (OH) 2 .
[0037] Its preparation method is:
[0038] Step 1. Precursor modification: the above Ni 0.875 co 0.050 mn 0.075 (OH) 2 Precursor with 0.5% nano-additive ZrO 2 Mixing and performing high-speed mechanic...
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