A kind of antibacterial flame retardant fiber and preparation method thereof
A technology of flame-retardant fiber and flame-retardant cellulose, which is applied in the field of preparation of antibacterial and flame-retardant fibers, can solve problems such as uneven mixing of flame retardants and antibacterial agents, low moisture regain of polyester fibers, secondary injury to people, etc., and achieve antibacterial Durable and stable flame retardant performance, excellent mechanical properties, and the effect of alleviating resource shortage
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[0042] The preparation method of a kind of antibacterial flame retardant fiber involved in the present invention is specifically implemented according to the following steps:
[0043] Step 1, collect the white pure cotton waste textiles, and then wash and dry the collected white pure cotton waste textiles and then pulverize them;
[0044] In step 2, the pulverized white pure cotton waste textiles are subjected to oxygen bleaching with hydrogen peroxide, the mass fraction of hydrogen peroxide is 8 to 12%, the treatment temperature is controlled at 60 to 90°C, bleached for 50 to 80 minutes, and then dried to obtain cellulose raw material;
[0045] Step 3, treating the cellulose raw material obtained in step 2 with 10-20% sodium hydroxide or 45% sodium carbonate solution for 1-3 hours, and drying at 80-90° C. to obtain alkali cellulose;
[0046]In step 4, the alkali cellulose prepared in step 3 is mixed with a hydroxy-containing phosphorus flame retardant, and then a cross-linki...
Embodiment 1
[0061] A method for preparing antibacterial and flame retardant fibers, which is specifically implemented according to the following steps:
[0062] Step 1, collect the white pure cotton waste textiles, and then wash and dry the collected white pure cotton waste textiles and then pulverize them;
[0063] In step 2, the pulverized material is subjected to oxygen bleaching with hydrogen peroxide, the mass fraction of hydrogen peroxide is 12%, the treatment temperature is controlled at 60° C., bleached for 80 minutes, and dried to obtain cellulose raw materials;
[0064] Step 3, treating the cellulose raw material with 10% sodium hydroxide solution for 3 hours, and drying at 80°C to obtain alkali cellulose;
[0065] Step 4, mixing alkali cellulose with a certain mass fraction of a hydroxy-containing phosphorus flame retardant, and using urea as a cross-linking agent to make the flame retardant and alkali cellulose undergo a hydroxylation cross-linking reaction to prepare flame re...
Embodiment 2
[0078] A method for preparing antibacterial and flame retardant fibers, which is specifically implemented according to the following steps:
[0079] Step 1, collect the white pure cotton waste textiles, and then wash and dry the collected white pure cotton waste textiles and then pulverize them;
[0080] In step 2, the pulverized material is subjected to oxygen bleaching with hydrogen peroxide, the mass fraction of hydrogen peroxide is 10%, the treatment temperature is controlled at 70 ° C, bleached for 60 min, and dried to obtain cellulose raw materials;
[0081] Step 3, treating the bleached product in step 1 with 20% sodium hydroxide solution for 4 hours, and drying at 85°C to obtain alkali cellulose;
[0082] In step 4, the alkali cellulose is mixed with a certain mass fraction of a hydroxy-containing phosphorus-based flame retardant, and urea is used as a cross-linking agent to make the flame retardant and the alkali cellulose undergo a hydroxylation and cross-linking rea...
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