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A kind of antibacterial flame retardant fiber and preparation method thereof

A technology of flame-retardant fiber and flame-retardant cellulose, which is applied in the field of preparation of antibacterial and flame-retardant fibers, can solve problems such as uneven mixing of flame retardants and antibacterial agents, low moisture regain of polyester fibers, secondary injury to people, etc., and achieve antibacterial Durable and stable flame retardant performance, excellent mechanical properties, and the effect of alleviating resource shortage

Active Publication Date: 2022-06-14
SHAANXI YUANFENG TEXTILE TECH RES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Polyester-based fibers will produce molten droplets when used, causing secondary damage to the human body. At the same time, polyester fibers have low moisture regain and poor fabric comfort; Chinese patent "Preparation method of antibacterial and flame-retardant protein viscose fiber", publication : CN102304783A, in the process of preparing antibacterial flame-retardant fiber, just flame retardant slurry, protein glue and chitosan solution are mixed evenly with viscose spinning solution, what adopt is the mixing of physical method, easily cause flame retardant Inhomogeneous mixing with antibacterial agents, resulting in unstable antibacterial and flame retardant functions of fibers, and defects such as not being resistant to washing; the flame retardant fabric developed by antibacterial and flame retardant acrylic fibers has a "smoldering" phenomenon, resulting in a decrease in the flame retardant performance of the fabric

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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  • A kind of antibacterial flame retardant fiber and preparation method thereof
  • A kind of antibacterial flame retardant fiber and preparation method thereof
  • A kind of antibacterial flame retardant fiber and preparation method thereof

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preparation example Construction

[0042] The preparation method of a kind of antibacterial flame retardant fiber involved in the present invention is specifically implemented according to the following steps:

[0043] Step 1, collect the white pure cotton waste textiles, and then wash and dry the collected white pure cotton waste textiles and then pulverize them;

[0044] In step 2, the pulverized white pure cotton waste textiles are subjected to oxygen bleaching with hydrogen peroxide, the mass fraction of hydrogen peroxide is 8 to 12%, the treatment temperature is controlled at 60 to 90°C, bleached for 50 to 80 minutes, and then dried to obtain cellulose raw material;

[0045] Step 3, treating the cellulose raw material obtained in step 2 with 10-20% sodium hydroxide or 45% sodium carbonate solution for 1-3 hours, and drying at 80-90° C. to obtain alkali cellulose;

[0046]In step 4, the alkali cellulose prepared in step 3 is mixed with a hydroxy-containing phosphorus flame retardant, and then a cross-linki...

Embodiment 1

[0061] A method for preparing antibacterial and flame retardant fibers, which is specifically implemented according to the following steps:

[0062] Step 1, collect the white pure cotton waste textiles, and then wash and dry the collected white pure cotton waste textiles and then pulverize them;

[0063] In step 2, the pulverized material is subjected to oxygen bleaching with hydrogen peroxide, the mass fraction of hydrogen peroxide is 12%, the treatment temperature is controlled at 60° C., bleached for 80 minutes, and dried to obtain cellulose raw materials;

[0064] Step 3, treating the cellulose raw material with 10% sodium hydroxide solution for 3 hours, and drying at 80°C to obtain alkali cellulose;

[0065] Step 4, mixing alkali cellulose with a certain mass fraction of a hydroxy-containing phosphorus flame retardant, and using urea as a cross-linking agent to make the flame retardant and alkali cellulose undergo a hydroxylation cross-linking reaction to prepare flame re...

Embodiment 2

[0078] A method for preparing antibacterial and flame retardant fibers, which is specifically implemented according to the following steps:

[0079] Step 1, collect the white pure cotton waste textiles, and then wash and dry the collected white pure cotton waste textiles and then pulverize them;

[0080] In step 2, the pulverized material is subjected to oxygen bleaching with hydrogen peroxide, the mass fraction of hydrogen peroxide is 10%, the treatment temperature is controlled at 70 ° C, bleached for 60 min, and dried to obtain cellulose raw materials;

[0081] Step 3, treating the bleached product in step 1 with 20% sodium hydroxide solution for 4 hours, and drying at 85°C to obtain alkali cellulose;

[0082] In step 4, the alkali cellulose is mixed with a certain mass fraction of a hydroxy-containing phosphorus-based flame retardant, and urea is used as a cross-linking agent to make the flame retardant and the alkali cellulose undergo a hydroxylation and cross-linking rea...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Abstract

The invention discloses a preparation method of an antibacterial and flame-retardant fiber, which specifically comprises: washing and drying the collected white pure cotton waste fabrics, crushing them, then using hydrogen peroxide for oxygen bleaching, drying, and then using sodium hydroxide or sodium carbonate solution Processing and drying to obtain alkali cellulose; mixing alkali cellulose / hydroxyl-containing phosphorus flame retardant and cross-linking agent to make the mixture undergo a hydroxylation cross-linking reaction to prepare flame-retardant cellulose, and combine flame-retardant cellulose with The nano antibacterial sol is mixed to prepare a cellulose solution, and then spun to obtain primary fibers, and the primary fibers are treated to obtain antibacterial and flame-retardant fibers. The invention also discloses a method for preparing the antibacterial and flame-retardant fabric. The invention discloses a method for preparing antibacterial and flame-retardant fibers. The antibacterial and flame-retardant fibers are prepared by using waste and old white pure cotton fabrics, which can make full use of resources and reduce environmental pollution. The antibacterial and flame-retardant fabrics prepared by using the fibers have long-lasting antibacterial and flame-retardant properties. Stable and washable, after 50 times, the antibacterial and flame retardant properties still meet the standard requirements.

Description

technical field [0001] The invention belongs to the technical field of preparation methods of functional textiles, and relates to a preparation method of antibacterial and flame retardant fibers. The invention also discloses a method for preparing antibacterial and flame retardant fabrics by using the self-made fibers. Background technique [0002] In recent years, with the development of society and economy, the country's emphasis on security, the introduction of the military-civilian integration development strategy, the rapid development of textile technology, and the continuous improvement of enterprise safety awareness, especially due to textile ignition or combustion-supporting effects on personal and property Immeasurable losses, many foreign countries have passed strict laws and regulations, requiring special industries such as fire protection, electric power, petrochemical, metallurgy, etc., to use flame retardant fabrics. During the use of flame retardant fabrics, ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01F2/24D01F1/07D01F1/10D02G3/04D02G3/44D03D15/50D03D15/513D03D15/283D03D15/47D03D15/225
CPCD01F2/24D01F1/103D01F1/07D02G3/045D02G3/449D02G3/443D10B2201/22D10B2331/04D10B2321/101D10B2331/021D10B2401/13D03D15/47D03D15/513
Inventor 侯琳樊争科赵雷徐炎炎孙凯飞
Owner SHAANXI YUANFENG TEXTILE TECH RES
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