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Benzoxazine resin-based composite material with ablation resistance and heat insulation and forming method of benzoxazine resin-based composite material

A benzoxazine resin and benzoxazine technology, applied in the field of composite materials, can solve problems such as seldom mentioned in research, fracture, and high product brittleness, and achieve flexible molecular design, good product manufacturability, and low curing The effect of shrinkage

Inactive Publication Date: 2019-11-26
西安长峰机电研究所
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, when the resin is used alone, due to the high rigidity of the benzene ring, the product is brittle, and the product is prone to stretching or breaking, which limits the use of the resin
[0004] In the current research, it is reported that benzoxazine resin and epoxy resin are blended and molded to form a phenolic-like network structure, but domestic research on the blending modification of benzoxazine resin and epoxy resin is rarely mentioned, and it is used in molding production blank

Method used

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  • Benzoxazine resin-based composite material with ablation resistance and heat insulation and forming method of benzoxazine resin-based composite material
  • Benzoxazine resin-based composite material with ablation resistance and heat insulation and forming method of benzoxazine resin-based composite material
  • Benzoxazine resin-based composite material with ablation resistance and heat insulation and forming method of benzoxazine resin-based composite material

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Embodiment Construction

[0016] The present invention will be further described below in conjunction with the examples, and the present invention includes but not limited to the following examples.

[0017] See Table 2 for the matrix components and formulations involved in the fiber-reinforced benzoxazine resin-based composite material provided by the present invention.

[0018] Table 2 Formulation design of fiber reinforced benzoxazine resin matrix composites

[0019] serial number Matrix components Proportion (weight) effect 1 Benzoxazine resin 30~40 Matrix resin 2 boron phenolic resin 60~70 Matrix resin 3 E-44 epoxy resin 0~20 toughened resin 4 acetone 100 solvent 5 Acrylonitrile carbon fiber 160 reinforced fiber

[0020] The preparation method of fiber reinforced benzoxazine resin-based composite material premix provided by the invention comprises the following steps:

[0021] Before the preparation of the mixture of the present inv...

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Abstract

The invention provides a benzoxazine resin-based composite material with ablation resistance and heat insulation and a forming method of the benzoxazine resin-based composite material. The benzoxazineresin-based composite material comprises the components: in parts by weight, 30-40 parts of benzoxazine resin, 60-70 parts of boron phenol resin, 100 parts of acetone and 160 parts of acrylonitrile carbon fiber, and curing is performed at a temperature of 200-210 DEG C and a pressure of 4-15 MPa for 20-30 min. On the premise that no reduction of ablation resistance of nozzles and performance of heat-insulation expansion sections, linings of partitions, outer linings of the partitions, backings of the partitions and other components of solid rocket engines is ensured, the defect rate of products is reduced, the toughness of the resin matrix is improved, and the subsequent processability of molded products is improved.

Description

technical field [0001] The invention relates to a composite material, which is used for the ablation-resistant and heat-insulating lining of solid rocket motor nozzle expansion section, clapboard inner, outer lining and backing, and is also suitable for ablation-resistant and higher temperature-resistant grades. High-strength FRP products. Background technique [0002] At present, the ablation-resistant and heat-insulating linings of commonly used solid rocket motors are mostly made of carbon fiber / boron phenolic molded. Boron phenolic resin has higher heat resistance and instantaneous high temperature resistance than ordinary phenolic resin. In addition, fiber-reinforced plastics have high mechanical strength, good ablation resistance and wear resistance, and can meet the requirements of solid rocket motors for thermal insulation structural parts. Requirements. At present, this kind of scheme is widely used, the cost is relatively low, and the process maturity is high, bu...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L61/14C08L61/34C08L63/00C08K7/06
CPCC08L61/14C08L61/34C08L2201/08C08L2205/03C08L2205/02C08L2203/18C08L63/00C08K7/06
Inventor 邹敏耿志刚张宁
Owner 西安长峰机电研究所
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