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A method for fabricating thick-film thermocouples on three-dimensional surfaces based on laser direct writing process

A laser direct writing, three-dimensional surface technology, applied in the field of laser micromachining and film sensor, can solve problems such as excessive roughness, peeling, limited workpiece size, etc., to achieve the effect of breaking through application limitations and improving reliability

Active Publication Date: 2022-01-07
HUAZHONG UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] (1) When the film thickness is less than 500nm, there will be a size effect, which affects the accuracy of the thermocouple; when the film thickness is greater than 4000nm, the efficiency of the traditional thin film process is too low, and the film quality cannot be guaranteed;
[0007] (2) The commonly used magnetron sputtering technology and electron beam evaporation technology need to be carried out in a closed protective atmosphere, the hardware cost is large, and the workpiece size is limited (Li Fuguo, Huang Luquan. Research on the dynamic characteristics of thin film thermocouples[J]. Journal of Instrumentation, 1996(3):316-318.);
[0008] (3) The performance of thin-film thermocouples is greatly affected by the complexity of substrate morphology and surface roughness, so it is not suitable for non-destructive transient temperature measurement on large and complex surfaces;
[0009] (4) The structure of the film is relatively fragile, and it is easy to peel off in the scouring environment
Gao Qiaoxia.Analysis of the Influencing Factors of Screen Printing Quality[J].Guangdong Printing,2017(3):39-40.] It is difficult to accurately control the dimensional accuracy of printing;
[0015] (3) Screen printing technology is also difficult to be used in the preparation of sensors on the surface of large curved parts;
[0016] (4) The surface roughness of the workpiece will affect the performance stability of the thermocouple prepared by screen printing

Method used

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  • A method for fabricating thick-film thermocouples on three-dimensional surfaces based on laser direct writing process

Examples

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Effect test

preparation example Construction

[0059] 4. Preparation of Direct Write Wires

[0060] Coat the Pt / PtRh electronic paste on the surface of the dielectric layer with a micro-pen, and dry the wires on the curved surface at 80°C to 150°C for 10min to 20min. Drying can promote the shape retention and curing of the electronic paste. For wires in flat parts, you can choose not to dry, and directly write with laser.

[0061] Then, the coaxial laser is used to carry out laser cladding along the path running with the micropen. During the cladding process, the interaction between the laser and the electronic paste is used to promote the discharge of the organic phase (removal of glue), so that the Pt / PtRh Remelt solidification and vitrification of the inorganic phase (high temperature adhesive). The technological parameters adopted by the micropen and the laser are determined according to the physical models in the corresponding steps. For thermocouple samples on a flat surface, the preparation time shall not exceed 3...

Embodiment 1

[0068] Example 1 Preparation of a sensor array for nickel-based superalloy turbine blades with a surface temperature of 1000°C

[0069] Select two kinds of commercial Pt / PtRh electronic pastes, and adjust the viscosity of the two pastes to the interval of 50-150mPa s through diluents, then by mixing diluents (including but not limited to terpineol, ethanol, etc.), or Thickener (including but not limited to carboxymethyl cellulose, etc.), to adjust the viscosity of the electronic paste to 50-150mPa·s.

[0070] Use a three-dimensional scanner to read the characteristic values ​​of the surface topography and size of the turbine blade, and use computer-aided design software (such as ProE software) to analyze these characteristic values ​​as the design basis. The design objects include but are not limited to the windward edge of the blade. Use computer-aided design software to design the motion trajectory of the thermal spraying ABB robot arm and the Huake Micro Pen direct writing...

Embodiment 2

[0073] Example 2 Ceramic Matrix Composite (CMC) Turbine Blade Surface 1200°C Sensor Array

[0074] To detect the surface roughness of CMC turbine blades, local or overall polishing is required for ceramic surfaces with an average roughness Ra>0.7μm. Polishing methods include but are not limited to laser polishing, mechanical polishing and chemical polishing. Prioritize stress-free polishing of the surface where the thermocouple is to be prepared using a CNC process. The surface roughness of the polished plane is Ra≤0.7μm.

[0075] 1. Material modification

[0076] Select commercial Pt / PtRh two kinds of electronic pastes, measure their viscosities respectively, the viscosities of Pt and PtRh two kinds of electronic pastes are respectively 45mPa·s and 200mPa·s, both of which are not in the range of 50-150mPa·s, then by mixing Organic substances such as terpineol and ethanol, or inorganic powders below 1um such as lime mud and feldspar are added to it, and the viscosity of the...

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Abstract

The invention discloses a method for preparing a thick-film thermocouple on a three-dimensional surface based on a laser direct writing process, and relates to the technical field of laser micromachining and film sensors. The process parameters of the composite direct writing; S3: prepare an insulating medium layer on the curved surface of the thermocouple to be prepared; S4, apply the electronic paste on the surface of the insulating medium layer with a micro-pen respectively to prepare Pt wires and PtRh wires, two The minimum included angle of the wires is not less than 45°; S5: At the hot junction of the two wires, use a laser for precise spot welding, and use a micropen to pre-prepare Pt paste at the hot junction before spot welding. The size of the thermocouple prepared by the method of the invention is between the thermocouples prepared by the thin film process and the traditional thick film process, which can make the thermocouple have good stability and fast response speed at the same time. Ability to fabricate thermocouples on curved surfaces of complex dimensions.

Description

technical field [0001] The invention relates to the technical fields of laser micromachining and film sensors, in particular to a processing method for preparing thick-film thermocouples on a three-dimensional surface based on a laser direct writing process. Background technique [0002] In aerospace vehicles, gas turbines, heavy machinery and other fields, real-time monitoring of the temperature of key parts of equipment is an important means to ensure the safe operation of equipment. These important equipment generally require that when installing sensors, the internal structure must not be damaged, otherwise it will bring new safety hazards. And as the service temperature increases, these surfaces with complex curved surfaces need to use thermal barrier coatings for thermal protection, and the sensor needs to have good compatibility with thermal barrier coatings. Therefore, the use of high-quality temperature sensors to achieve non-destructive transient temperature measu...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B81C1/00
CPCB81C1/00206B81C1/00349
Inventor 曾晓雁欧阳韬源吕铭刘建国
Owner HUAZHONG UNIV OF SCI & TECH
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