Heat insulation material for cold-chain logistics and preparation method thereof
A technology of thermal insulation materials and cold chain logistics, applied in the field of thermal insulation materials and its preparation, can solve the problems of poor safety and environmental protection, large deformation coefficient, poor thermal insulation effect, etc., and achieve improved weather resistance and aging resistance, flame retardancy and durability Good low temperature performance and good heat preservation effect
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Embodiment 1
[0025] A thermal insulation material for cold chain logistics, made of the following raw materials in parts by weight: 4 parts of N-vinyl o-phenylimine, 2 parts of 2-vinyl-1H-benzimidazole, 2-vinyl- 10 parts of 4,6-diamino-1,3,5-triazine / carboxyl-terminated polyurethane polycondensate, 0.5 parts of allyl pentafluorobenzene, 0.5 parts of vinyltrimethoxysilane, 0.5 parts of sodium dodecylsulfonate 1 part, 1 part of magnesium hydroxide, 0.1 part of triazine-based micro-nano ball rod, and 0.4 part of azobisisobutyronitrile.
[0026] The preparation method of the 2-vinyl-4,6-diamino-1,3,5-triazine / carboxyl-terminated polyurethane polycondensate comprises the following steps: 2-vinyl-4,6-diamino-1 , 3,5-triazine, carboxyl-terminated polyurethane, phenylphosphoric acid, 2-ethoxy-1-ethoxycarbonyl-1,2-dihydroquinoline, tetrachlorobenzoquinone, dimethyl sulfoxide were added to the high-pressure reaction In the autoclave, fill the autoclave with nitrogen, raise the temperature to 150°C,...
Embodiment 2
[0030] An insulation material for cold chain logistics, made of the following raw materials in parts by weight: 4.3 parts of N-vinyl o-phenylimine, 2.5 parts of 2-vinyl-1H-benzimidazole, 2-vinyl- 13 parts of 4,6-diamino-1,3,5-triazine / carboxyl-terminated polyurethane condensation polymer, 0.8 part of allyl pentafluorobenzene, 0.8 part of vinyltrimethoxysilane, sodium sulfate of fatty alcohol polyoxyethylene ether 0.7 parts, 1.5 parts of calcium hydroxide, 0.15 parts of triazine-based micro-nano ball rods, and 0.55 parts of azobisisoheptanonitrile.
[0031] The preparation method of the 2-vinyl-4,6-diamino-1,3,5-triazine / carboxyl-terminated polyurethane polycondensate comprises the following steps: 2-vinyl-4,6-diamino-1 ,3,5-triazine, carboxyl-terminated polyurethane, phenylphosphinic acid, 2-ethoxy-1-ethoxycarbonyl-1,2-dihydroquinoline, 1,4-naphthoquinone, N,N-dihydroquinone Add methylformamide into the autoclave, fill the autoclave with helium, raise the temperature to 155°C...
Embodiment 3
[0035] A thermal insulation material for cold chain logistics, made of the following raw materials in parts by weight: 4.5 parts of N-vinyl o-phenylimine, 3 parts of 2-vinyl-1H-benzimidazole, 2-vinyl- 15 parts of 4,6-diamino-1,3,5-triazine / carboxyl-terminated polyurethane condensation polymer, 1.3 parts of allyl pentafluorobenzene, 1.2 parts of vinyltrimethoxysilane, 1 part of sodium bicarbonate, sea foam 2 parts of stone, 0.2 part of triazine-based micro-nano ball stick, and 0.55 part of benzoyl peroxide.
[0036] The preparation method of the 2-vinyl-4,6-diamino-1,3,5-triazine / carboxyl-terminated polyurethane polycondensate comprises the following steps: 2-vinyl-4,6-diamino-1 , 3,5-triazine, carboxyl-terminated polyurethane, triphenyl phosphate, 2-ethoxy-1-ethoxycarbonyl-1,2-dihydroquinoline, tetrachlorobenzoquinone, N-methylpyrrolidone added Into the autoclave, fill the autoclave with neon gas, raise the temperature to 160°C, maintain a constant pressure under the pressure...
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