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Plasma emission spectrum interference correction method

A technology of emission spectrum and plasma, which is applied in the field of spectral detection, can solve problems such as mutual interference of detection results, application environment restrictions, detection accuracy and sensitivity limitations, etc., and achieve the effect of improving accuracy, detecting element range, and expanding application range

Active Publication Date: 2019-09-06
安徽创谱仪器科技有限公司
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AI Technical Summary

Problems solved by technology

[0003] In principle, LIBS technology can analyze samples in any physical state. However, in practical applications, the emitted light waves with wavelengths in the vacuum ultraviolet band are easily absorbed and scattered by the atmosphere or dust and smoke, and cannot be applied to the detection of most production sites. Therefore, the detection The wavelength range is limited not only by the detection instrument, but also by the application environment
In addition, limited by the detection accuracy and sensitivity of the detection instrument, when the characteristic spectral lines of the plasma emission light produced by the ablation of different elements are similar, the detection results will interfere with each other, which makes LIBS technology unable to be widely used in production applications.

Method used

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Embodiment 1

[0054] Step 1: Detect alloy materials containing C elements and Fe elements, and obtain such as figure 2 The plasmon emission spectrum shown;

[0055] Step 2: Since the spectral resolution of the detection instrument is 0.01nm, in combination with the plasma emission spectrum obtained in step 1 and the information shown in Table 1 in the Atomic Spectra Database (Atomic Spectra Database), select the 247.80nm-247.90nm band as the spectrum to be analyzed Section (10), determine that the analysis line A is C I 247.86nm, and the interference line B is Fe II 247.86nm, and obtain the spectral line parameters such as high-level energy, degeneracy, and transition probability of the analysis line A and the analysis line B;

[0056] Among them, C I 247.86nm is the characteristic spectral line of C element atom at the wavelength of 247.86nm; Fe II247.86nm is the characteristic spectral line of Fe monovalent ion at the wavelength of 247.86nm. That is, the corresponding element of the ana...

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Abstract

The invention, which belongs to the technical field of spectrum detection, particularly relates to a plasma emission spectrum interference correction method. Calculation is performed based on other characteristic spectrum line information of a corresponding element of an interference line B in a corrected spectral segment 20 to obtain a spectrum line intensity of the interference line B; and thusa to-be-analyzed spectrum peak 11 is decomposed conveniently to obtain a spectrum line intensity of an analysis line A, thereby completing e correction of the spectral interference. The method has thefollowing technical effects: the spectrum line can be decomposed accurately based on the intensity relationship of the same type of emission spectrum lines in a same ion state in the plasma emissionspectrum theory and the detection and calculation of the emission intensity of the spectrum line being easy to affect are realized, so that the accuracy of the component detection result is improved and the detection element range is extended. Therefore, the application range of LIBS technology is further expanded.

Description

technical field [0001] The invention belongs to the technical field of spectrum detection, in particular to a plasma emission spectrum interference correction method. Background technique [0002] Laser-Induced Breakdown Spectroscopy (LIBS) technology has the distinctive characteristics of fast detection speed, complete element types, and no need for sample preparation. It is considered to be the most promising online component detection technology. This technology focuses a high-energy pulsed laser on the surface of the detection sample to ablate the sample to generate plasma, and then analyzes the plasma emission spectrum to determine the material composition and content of the sample. [0003] In principle, LIBS technology can analyze samples in any physical state. However, in practical applications, the emitted light waves with wavelengths in the vacuum ultraviolet band are easily absorbed and scattered by the atmosphere or dust and smoke, and cannot be applied to the de...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N21/71
CPCG01N21/718
Inventor 潘从元李朝阳安宁
Owner 安徽创谱仪器科技有限公司
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