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Low-combustion-heat polyvinyl chloride composite and preparing method thereof

A polyvinyl chloride and composite material technology, applied in the field of fireproof building materials, can solve the problems of inapplicable polymer composite materials, many components in a flame retardant system, low water loss decomposition temperature, etc., achieving simple formula and process, avoiding mechanical properties. The effect of poor and high decomposition temperature

Active Publication Date: 2019-08-27
ZHEJIANG YASHA DECORATION +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the low dehydration decomposition temperature (-100°C) of the components used in this formula system, such as hydrated salt, etc., it can only be mixed at room temperature, molded, and freeze-dried, which cannot be applied to conventional sheet materials. Polymer composites prepared by melt blending
Patent CN 102558653A discloses a class A fireproof core material prepared by using magnesium hydroxide as a heat-inhibiting compound; the filling amount of magnesium hydroxide in the matrix is ​​as high as 80-90% (weight percentage), such a high magnesium hydroxide The amount of filling will inevitably lead to a sharp increase in material cost and a decrease in mechanical properties. Its applicability is relatively limited, and it is difficult to apply to materials with high mechanical properties.
Chinese patent CN103396629A discloses a smoke-suppressing, flame-retardant and sound-insulating PVC material, which uses antimony oxide, dodecabromodiphenyl ether, zinc borate, ferrocene and aluminum hydroxide as flame-retardant components to achieve the purpose of smoke-suppressing and flame-retardant; However, the flame retardant system used involves many components and the formula is relatively complicated.

Method used

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  • Low-combustion-heat polyvinyl chloride composite and preparing method thereof
  • Low-combustion-heat polyvinyl chloride composite and preparing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] 1) Dry 28 parts of aluminum hydroxide (1 μm), 31 parts of zinc carbonate (30 μm), 31 parts of magnesium carbonate (30 μm), and 21 parts of calcium carbonate (50 μm) at 110° C. for 2 hours to remove moisture; Use as a heat suppressing compound.

[0033] 2) Add the above heat-suppressing compound with 30 parts of polyvinyl chloride resin, 2.5 parts of chlorinated polyvinyl chloride resin, 0.5 parts of ethylene-vinyl acetate copolymer, 3 parts of heat stabilizer, 0.5 parts of polyethylene wax, chlorinated polyvinyl chloride resin Put 0.5 parts of paraffin into a high-speed mixer, and under the action of high-speed stirring at 1300rpm, raise the temperature of the raw material to 120°C, then change to 650rpm and stir at a low speed, under the action of cooling water and stirring, reduce the temperature of the raw material to 50°C, and then at 200rpm The material is discharged at a low speed to complete the premixing of PVC mixture.

[0034] 3) Melt and blend the pre-mixed ...

Embodiment 2

[0036] 1) Dry 97 parts of aluminum hydroxide (3μm) and 150 parts of calcium carbonate (50μm) at 80°C for 3 hours to remove moisture; then use it as a heat-inhibiting compound.

[0037] 2) Then mix the above-mentioned heat-suppressing compound with 60 parts of polyvinyl chloride resin, 1.5 parts of acrylate resin, 4.5 parts of chlorinated polyvinyl chloride resin, 0.2 parts of acrylonitrile-butadiene-styrene polymer, and 1.2 parts of heat stabilizer 1.2 parts of polyethylene wax and 1.2 parts of stearic acid are placed in a high-speed mixer, and the temperature of the raw materials is raised to 120°C under the action of 950rpm high-speed stirring, and then changed to 475rpm and low-speed stirring. Under the action of cooling water and stirring, the raw materials The temperature is lowered to 80°C, and then the material is discharged at a low speed of 130rpm to complete the premixing of PVC mixture.

[0038] 3) Melt and blend the pre-mixed materials on a double-roller mill at 18...

Embodiment 3

[0040] 1) Dry 40 parts of magnesium hydroxide (5μm), 40 parts of layered double hydroxide (20μm), and 80 parts of magnesium carbonate (30μm) at 110°C for 2 hours to remove moisture; things to use.

[0041] 2) Then mix the above-mentioned heat-suppressing compound with 40 parts of polyvinyl chloride resin, 0.5 part of methacrylic acid-butadiene-styrene polymer, 5.5 parts of acrylate resin, 2.4 parts of heat stabilizer, 0.8 part of stearic acid, Put 0.8 parts of polyethylene wax and 0.8 parts of silicone powder into a high-speed mixer, raise the temperature of the raw materials to 120°C under the action of high-speed stirring at 860rpm, then change to 430rpm and stir at a low speed, and reduce the temperature of the raw materials under the action of cooling water and stirring Lower the temperature to 80°C, and then discharge the material at a low speed of 70rpm to complete the premixing of PVC mixture.

[0042] 3) Mix and extrude the pre-mixed materials in a twin-screw extruder...

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Abstract

The invention provides a low-combustion-heat polyvinyl chloride composite and a preparing method thereof. The low-combustion-heat polyvinyl chloride composite has the combustion heat of A2 grade, hasgood mechanical performance and forming processing performance, and is simple in formula and low in preparing cost. The composite comprises polyvinyl chloride resin, an impact modifier, a heat-inhibiting compound, a thermal stabilizer and a flow modifier, wherein the heat-inhibiting compound is the combination of hydroxide and carbonate. The composite comprises, by weight, 30-60 parts of polyvinylchloride resin, 3-6.2 parts of the impact modifier, 28-100 parts of hydroxide, 80-150 parts of carbonate, 1.2-3 parts of the thermal stabilizer and 1-2.4 parts of the flow modifier.

Description

technical field [0001] The invention relates to the technical field of fireproof building materials, in particular to a fireproof polyvinyl chloride composite board material and a preparation method thereof. Background technique [0002] In recent years, major vicious fires in public places have occurred from time to time. Using flame retardant products and fire safety design technology to build a reliable passive fire protection system is one of the important means to avoid vicious fire accidents from the source. For this reason, the country officially implemented the "Classification of Combustion Behavior of Building Materials and Products" (GB 8624-2006) standard on March 1, 2007. In this national standard, the combustion calorific value (PCS) of materials is an important criterion for measuring the combustion performance classification of building materials and products. [0003] Due to the advantages of light weight and easy processing, polymer composite materials hav...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L27/06C08L27/24C08L23/08C08L23/06C08L91/06C08L55/02C08L33/04C08L23/28C08L51/04C08K13/02C08K3/22C08K3/26
CPCC08K2003/2224C08K2003/2227C08K2003/265C08K2003/267C08K2201/003C08L27/06C08L2201/02C08L2201/08C08L2205/02C08L2205/035C08L2205/06C08L27/24C08L23/0853C08L23/06C08L91/06C08K13/02C08K3/22C08K3/26C08L33/04C08L55/02C08K5/09C08L51/04C08L83/04C08L23/286
Inventor 丁欣欣范萍周东珊钟明强丁泽成王文广李林陈枫余广
Owner ZHEJIANG YASHA DECORATION
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