A kind of method that utilizes aluminum ash and carbide slag to prepare calcium aluminate
A technology of calcium carbide slag and calcium aluminate, which is applied in the preparation of calcium aluminate, alkaline earth metal aluminate/alumina/aluminum hydroxide, etc.
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Embodiment 1
[0026] The aluminum ash is treated according to the process of catalytic hydrolysis-acidolysis-washing. The catalytic hydrolysis section: the liquid-solid ratio is 2ml / g, the reaction temperature is 70°C, the reaction time is 1h, and the cycle times of the hydrolyzate is 3 times; the acidolysis section: the liquid-solid ratio is 3ml / g, reaction temperature 80℃, reaction time 1h, hydrochloric acid concentration 100g / l; sintering section: molding pressure 20MPa, calcination temperature 1000℃, calcination time 0.5h. The prepared calcium aluminate has 90% soluble alumina, 54% alumina content and 34% calcium oxide.
Embodiment 2
[0028] The aluminum ash is treated according to the process of catalytic hydrolysis-acidolysis-washing. The catalytic hydrolysis section: the liquid-solid ratio is 3ml / g, the reaction temperature is 85°C, the reaction time is 2h, and the cycle times of the hydrolyzate is 5 times; the acidolysis section: the liquid-solid ratio is 4ml / g, reaction temperature 80℃, reaction time 1h, hydrochloric acid concentration 150g / l; sintering section: molding pressure 100MPa, calcination temperature 1100℃, calcination time 1h. The prepared calcium aluminate has 92% soluble alumina, 56% alumina content and 22% calcium oxide.
Embodiment 3
[0030] The aluminum ash is treated according to the process of catalytic hydrolysis-acidolysis-washing. The catalytic hydrolysis section: the liquid-solid ratio is 3ml / g, the reaction temperature is 95°C, the reaction time is 3h, and the cycle times of the hydrolyzate is 6 times; the acidolysis section: the liquid-solid ratio is 5ml / g, reaction temperature 95°C, reaction time 2h, hydrochloric acid concentration 200g / l; sintering section: molding pressure 120MPa, calcination temperature 1200°C, calcination time 1h. The prepared calcium aluminate has 96% soluble alumina, 60% alumina content and 28% calcium oxide.
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