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Carbonized bacterial cellulose-cadmium sulfide composite photocatalytic material as well as preparation method and application thereof

A technology of bacterial cellulose and composite photocatalysis, which is applied in the direction of catalyst activation/preparation, chemical instruments and methods, physical/chemical process catalysts, etc., can solve problems that are still in its infancy and require further research. Achieve high photocatalytic hydrogen production performance, simple operation, and mild conditions

Active Publication Date: 2019-07-12
WUHAN UNIV OF TECH
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AI Technical Summary

Problems solved by technology

At present, the research work on bacterial cellulose and its derivative materials at home and abroad has gone deep into the modification and modification of bacterial cellulose and the preparation of its composite materials. Combining the structure and performance characteristics of bacterial cellulose, bacterial fibers with different properties have been prepared. derivatives and bacterial cellulose-based composites, but the research in all aspects is still in its infancy, and further research is needed

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  • Carbonized bacterial cellulose-cadmium sulfide composite photocatalytic material as well as preparation method and application thereof
  • Carbonized bacterial cellulose-cadmium sulfide composite photocatalytic material as well as preparation method and application thereof

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Embodiment Construction

[0018] In order to enable those skilled in the art to better understand the technical solution of the present invention, the present invention will be further described in detail below in conjunction with examples.

[0019] The main components and concentrations in medium A are: 25.0 g / L, tryptone 5.0 g / L, yeast extract 5.0 g / L, citric acid 1 g / L, Na 2 HPO 4 2 g / L, K 2 HPO 4 1 g / L, pH=5.0.

[0020] 1): Obtaining bacterial cellulose airgel: Gluconacetobacter xylinum preserved in a freeze-drying tube Gluconacetobacter xylinus ATCC 700178 Activated in basal medium A, to be Gluconacetobacter xylinus After dynamic culture for 96 hours, the obtained product was collected, washed successively with distilled water and 0.5M hydroxide solution, and then washed with distilled water until neutral, and finally the bacterial cellulose airgel was collected after vacuum freeze-drying.

[0021] 2): Preparation of bacterial cellulose-cadmium sulfide composite material: 0.1 g bacteria...

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Abstract

The invention relates to a carbonized bacterial cellulose-cadmium sulfide composite photocatalytic material as well as a preparation method and application thereof. The photocatalytic material is prepared by using the following methods: 1) inoculating Gluconacetobacter xylinus into a culture medium A, carrying out dynamic culture for 96 hours, collecting a bacterial cellulose product, washing, drying, and further carrying out vacuum freeze drying so as to obtain bacterial cellulose aerogel; 2) dissolving a fixed amount of thiourea and cadmium sulfide into ultrapure water, adding a proper amount of the bacterial cellulose aerogel, and carrying out a hydrothermal reaction at a high temperature and high pressure; 3) carrying out high-temperature calcining on the bacterial cellulose aerogel-cadmium sulfide compound product in a tubular furnace, thereby obtaining the carbonized bacterial cellulose-cadmium sulfide composite photocatalytic material. The preparation method provided by the invention has the advantages of being simple in operation, low in cost, and the like. The obtained carbonized bacterial cellulose-cadmium sulfide composite photocatalytic material can be used as a catalyst in water hydrogen generation of photocatalysis splitting.

Description

technical field [0001] The invention relates to a carbon fiber-cadmium sulfide composite photocatalytic material and its preparation method and application. Background technique [0002] Since the 21st century, with the rapid development of science and technology, productivity has been significantly improved, creating huge wealth for human beings. While people use science and technology to create wealth, they also bring a series of problems such as excessive energy consumption and serious damage to the ecological environment. Faced with this situation, heterogeneous photocatalytic technology using semiconductors and renewable solar energy is considered as one of the most promising processes to alleviate or even solve the world's energy supply crisis and environmental pollution. Water-splitting photocatalytic hydrogen production technology has been favored by a large number of researchers because of its environmental friendliness, renewable reuse and other advantages. As a ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J27/04B01J37/08B01J37/10C01B3/04
CPCB01J27/04B01J37/084B01J37/10C01B3/042C01B2203/1041C01B2203/0277B01J35/39Y02E60/36
Inventor 张甜江山皮埃尔
Owner WUHAN UNIV OF TECH
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