Optical adhesive layer, manufacturing method of optical adhesive layer, optical film with adhesive layer, and image display device
A technology of adhesive layer and adhesive, which is applied in the field of optical film, can solve problems such as deformation of the adhesive layer, and achieve the effect of suppressing foaming and high bonding reliability
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Embodiment 1
[0146] (Preparation of (meth)acrylic polymer (A1))
[0147] A monomer mixture containing 99 parts of butyl acrylate and 1 part of 4-hydroxybutyl acrylate was charged into a 4-necked flask equipped with a stirring blade, a thermometer, a nitrogen gas introduction tube, and a condenser. Further, 0.1 part of 2,2'-azobisisobutyronitrile was added as a polymerization initiator to 100 parts of the above-mentioned monomer mixture together with 85 parts of ethyl acetate and 15 parts of toluene, and nitrogen gas was introduced while stirring slowly to carry out nitrogen replacement. After that, the liquid temperature in the flask was maintained at around 55° C., and the polymerization reaction was carried out for 30 minutes to prepare a (meth)acrylic polymer (A1) with a weight average molecular weight (Mw) of 1.44 million and Mw / Mn=1.75. solution.
[0148] (Preparation of Adhesive Composition)
[0149] With respect to 100 parts of solid content of the solution of the above-mentioned ...
Embodiment 2~18、 and comparative example 1~5
[0173] In Examples 2 to 18 and Comparative Examples 1 to 5, the production methods of the above-mentioned (meth)acrylic polymers (A2) to (A12) were changed in the same manner as in Example 1, and the changes were made as shown in Table 1. The types of monomers, their mixing ratios, and the production conditions were controlled to prepare (meth)acrylic polymers with the polymer properties (weight-average molecular weight (MW), polydispersity coefficient (Mw / Mn)) shown in Table 1. Solutions of (A2) to (A12).
[0174] In addition, except that the type or amount of the crosslinking agent was changed as shown in Table 1 with respect to each obtained (meth)acrylic polymer solution, an acrylic adhesive set was prepared in the same manner as in Example 1. solution of substances. Moreover, the polarizing film with an adhesive layer was produced similarly to Example 1 using the solution of the said acrylic adhesive composition.
[0175] The following evaluations were performed about t...
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