Simulated leather texture polyurethane leather for automobile and preparation method of simulated leather texture polyurethane leather
A technology of polyurethane leather and imitation leather, which is applied to chemical instruments and methods, vehicle parts, pre-treated surfaces, etc. It can solve the problems of low VOC and environmental protection, poor aging resistance, heavy odor, etc., and improve the bonding firmness , Improve mechanical properties, clear surface texture
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Embodiment 1
[0066] A kind of artificial leather texture polyurethane leather for automobiles, comprising successively laminated 1.5mm thick base cloth layer superfine fiber non-woven fabrics (weight per unit area is 200g / m 2 ), a 0.05mm thick TPU hot melt adhesive layer, a composite layer consisting of a 0.05mm thick TPU film layer and a 0.05mm thick PU layer.
[0067] The preparation raw material of described TPU hot-melt adhesive layer comprises following raw material component by weight part:
[0068]
[0069] The preparation method of the polyester polyol is as follows: mix 1 mol of sebacic acid, 2.5 mol of terephthalic acid and 4.0 mol of ethylene glycol, then add 0.003 mol of isopropyl zirconate, heat up to 160°C for polycondensation reaction to obtain decane Diacid polyester polyol (weight average molecular weight 1500);
[0070] The flame retardant comprises by weight percentage: 30wt% dimethyl phosphite, 35wt% ammonium polyphosphate, 35wt% pentaerythritol;
[0071] The prepa...
Embodiment 2
[0081] A kind of artificial leather texture polyurethane leather for automobiles, comprising successively stacked 3.0mm thick base cloth layer superfine fiber non-woven fabrics (weight per unit area is 400g / m 2 ), a 0.1mm thick TPU hot melt adhesive layer, a composite layer consisting of a 0.1mm thick TPU film layer and a 0.1mm thick PU layer.
[0082] The preparation raw material of described TPU hot-melt adhesive layer comprises following raw material component by weight part:
[0083]
[0084]The preparation method of the polyester polyol is as follows: mix 1 mol of sebacic acid, 2.5 mol of terephthalic acid and 4.0 mol of ethylene glycol, then add 0.003 mol of isopropyl zirconate, heat up to 200°C for polycondensation reaction to obtain decane Diacid polyester polyol (weight average molecular weight 2000);
[0085] The flame retardant comprises by weight percentage: 20wt% dimethyl phosphite, 40wt% ammonium polyphosphate, 40wt% pentaerythritol;
[0086] The preparation...
Embodiment 3
[0096] A kind of artificial leather texture polyurethane leather for automobiles, comprising successively laminated 0.1mm thick base cloth layer superfine fiber non-woven fabrics (weight per unit area is 200g / m 2 ), a 0.01mm thick TPU hot melt adhesive layer, a composite layer consisting of a 0.05mm thick TPU film layer and a 0.05mm thick PU layer.
[0097] The preparation raw material of described TPU hot-melt adhesive layer comprises following raw material component by weight part:
[0098]
[0099] The preparation method of the polyester polyol is as follows: mix 1 mol of sebacic acid, 2.5 mol of terephthalic acid and 4.0 mol of ethylene glycol, then add 0.003 mol of isopropyl zirconate, heat up to 160°C for polycondensation reaction to obtain decane Diacid polyester polyol (weight average molecular weight 1500);
[0100] The flame retardant comprises by weight percentage: 25wt% dimethyl phosphite, 35wt% ammonium polyphosphate, 35wt% pentaerythritol;
[0101] The prepa...
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