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Low-temperature comprehensive desulfurization and denitration method for boiler flue gas

A boiler flue gas, desulfurization and denitrification technology, applied in the field of desulfurization and denitrification, can solve the problems of high operation cost and secondary pollution, and achieve the effect of stable operation of the device and cost reduction.

Pending Publication Date: 2019-03-22
湖北申昙环保新材料有限公司
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0011] The technical problem to be solved by the present invention is the technical problem of high operating cost and secondary pollution in the treatment process of boiler flue gas in the existing coking plant. It provides a method for low-temperature desulfurization and denitrification of boiler flue gas. , low equipment investment, simple regeneration, low energy consumption, and no secondary pollution

Method used

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  • Low-temperature comprehensive desulfurization and denitration method for boiler flue gas

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Experimental program
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Effect test

Embodiment 1

[0053] The coke oven gas from the coke oven enters the crude debenzene unit, and the crude debenzene forms stream I, wherein the benzene concentration in stream I is 1000-4000 mg / m 3 Between, the concentration of naphthalene is 200~500mg / m 3 Between, the concentration of hydrogen sulfide is 100~500mg / m 3 Between; stream Ⅰ enters the comprehensive purification tower, the comprehensive purification tower contains ZSM molecular sieve adsorbent, removes aromatics and sulfides in the gas at the same time, and forms stream Ⅱ, the benzene concentration in stream Ⅱ is less than 1000mg / m 3 , naphthalene concentration is less than 4 mg / m 3 , the concentration of hydrogen sulfide is less than 4mg / m 3 ;Organic sulfur concentration is less than 4mg / m 3 ; Logistics II enters the boiler for combustion.

[0054] 160,000 cubic meters of boiler flue gas at 240°C, with a nitrogen oxide content of 500mg / m 3 , the sulfide content is 200 mg / m 3 , the flue gas enters the denitrification tower,...

Embodiment 2

[0056] The coke oven gas from the coke oven enters the crude debenzene unit, and the crude debenzene forms stream I, wherein the benzene concentration in stream I is 1000-4000 mg / m 3 Between, the concentration of naphthalene is 200~500mg / m 3 Between, the concentration of hydrogen sulfide is 100~500mg / m 3 Between; stream Ⅰ enters the comprehensive purification tower, the comprehensive purification tower contains ZSM molecular sieve adsorbent, removes aromatics and sulfides in the gas at the same time, and forms stream Ⅱ, the benzene concentration in stream Ⅱ is less than 1000mg / m 3 , naphthalene concentration is less than 4 mg / m 3 , the concentration of hydrogen sulfide is less than 4mg / m 3 ;Organic sulfur concentration is less than 4mg / m 3 ; Logistics II enters the boiler for combustion.

[0057] The specific implementation is as attached figure 1 The shown device flow, 150,000 cubic meters of flue gas at 260°C, the nitrogen oxide content is 400mg / m 3 , the sulfide conte...

Embodiment 3

[0059]The coke oven gas from the coke oven enters the crude debenzene unit, and the crude debenzene forms stream I, wherein the benzene concentration in stream I is 1000-3500 mg / m 3 Between, the concentration of naphthalene is 200~500mg / m 3 Between, the concentration of hydrogen sulfide is 100~500mg / m 3 Between; stream Ⅰ enters the comprehensive purification tower, which contains zinc-modified ZSM-5 molecular sieve adsorbent, and simultaneously removes aromatics and sulfides in the gas to form stream Ⅱ, in which benzene Concentration less than 60mg / m 3 , the concentration of naphthalene is less than 1 mg / m 3 Between, hydrogen sulfide concentration is less than 1mg / m 3 ; Concentration in toluene, xylene, ethylbenzene, trimethylbenzene, naphthalene, anthracene, and fennel is less than 1 mg / m 3 Between; sulfides are hydrogen sulfide, sulfur dioxide, mercaptan, thioether, thiophene, methyl mercaptan, and methyl sulfide, the concentration of which is less than 1mg / m 3 Between,...

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Abstract

Low-temperature comprehensive desulfurization and denitration method for boiler flue gas. The invention relates to a desulfurization and denitration method for boiler flue gas. The method is mainly used for solving the problem that the existing boiler flue gas desulfurization and denitration are high in operating cost and secondary pollution is caused. According to the method, through adopting thetechnical scheme that coke-oven gas or blast furnace gas entering a boiler furnace for combustion is subjected to sulfide removal prior to entering a coke oven and then is burnt, nitrogen oxides andsulfides are removed from the boiler flue gas by an adsorption method, and the nitrogen oxides and the sulfides in the regenerated flue gas are subjected to salt making treatment, the above problem isbetter solved; the method can be applied to industrial production of desulfurization and denitration of the boiler flue gas.

Description

technical field [0001] The invention belongs to the technical field of desulfurization and denitrification, and in particular relates to a method for desulfurization and denitrification of boiler flue gas. Background technique [0002] SO 2 and NO X Both are important air pollutants in my country. Excessive emissions will cause smog, acid rain and photochemical smog, which seriously endanger the ecological environment and human health. The combustion of fossil fuels is SO 2 and NO X main source of . Coal is the most important natural energy in my country. As the second largest coal-consuming field in China, coal coking is one of the main pollution sources in the field of industrial coal use, and boiler flue gas is an important pollution source of the atmosphere. [0003] At present, wet desulfurization technology and semi-dry desulfurization technology represented by ammonia method, lime / limestone method, double alkali method and magnesium oxide method are widely used i...

Claims

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Application Information

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IPC IPC(8): B01D53/75B01D53/60B01D53/72B01D47/06B01D53/04
CPCB01D47/06B01D53/04B01D53/60B01D53/72B01D53/75B01D2253/106B01D2258/0283B01D2259/4009Y02A50/20
Inventor 马广伟宋晶孙广亿
Owner 湖北申昙环保新材料有限公司
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