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A kind of preparation method of graphene coated porous material

A graphene-coated, porous material technology, applied in the direction of structural parts, electrical components, battery electrodes, etc., can solve the problems of complex preparation process and lack of broad spectrum, achieve uniform pore size distribution, easy large-scale production, process stable effect

Active Publication Date: 2020-11-06
SHANDONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Patent CN108232160A reports a method for preparing porous metal-carbon composites. Firstly, this method is suitable for metals and does not have broad spectrum. Secondly, this method requires high-speed ball milling and argon gas, and the preparation process is complicated.

Method used

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  • A kind of preparation method of graphene coated porous material
  • A kind of preparation method of graphene coated porous material
  • A kind of preparation method of graphene coated porous material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] A preparation method of graphene-coated porous material: take 0.1g graphene oxide and 1gZnSb alloy material, mix them evenly, hang them in a vacuum heat treatment furnace (model: OTF-1200X-S-II, MTI), and keep them warm at 500°C After 2 hours, the vacuum degree was set to 10 Pa to obtain graphene-coated porous antimony.

Embodiment 2

[0046] A kind of preparation method of graphene-coated porous material: get 0.1g graphene oxide and 2gZn 2 Sb 3 The materials were mixed evenly and suspended in a vacuum heat treatment furnace (model: OTF-1200X-S-II, MTI), kept at 600°C for 1 hour, and the vacuum degree was set to 8Pa to obtain graphene-coated porous antimony.

Embodiment 3

[0048] A kind of preparation method of graphene-coated porous material: get 0.1g graphene oxide and 1gAlZn material, mix uniformly, hang in laboratory small vacuum heat treatment furnace (model: OTF-1200X-S-II, MTI), in 300 ℃ for 2 hours, and the vacuum degree is set to 9Pa to obtain graphene-composite porous aluminum.

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Abstract

The invention relates to a preparation method of graphene-coated porous material, belonging to the technical field of batteries. The method comprises the following steps: (1) uniformly mixing grapheneoxide and AB alloy material for standby; In the AB alloy material, element A is a metal element with high melting point and high boiling point, element B is a metal element with lower boiling point and lower melting point relative to element A; (2) heating and holding the graphene oxide and the AB alloy material in the step (1) under the vacuum condition, removing the B element gradually, and reducing the graphene oxide in situ to obtain the graphene-coated porous alloy composite electrode material. The invention uniformly coats graphene oxide on the surface of porous metal through vacuum in-situ reduction, realizes the synchronization of graphene coating and porous metal preparation, and can prepare porous alloy composite electrode material coated by graphene in one step. The process issimple and practical, and the cost is low.

Description

technical field [0001] The invention relates to the technical field of batteries, in particular to a method for preparing a graphene-coated porous material. Background technique [0002] Porous material, that is, a large number of directional or random pores are dispersed in the material, and the diameter of these pores is generally 2μm-3mm. Due to the different design requirements for the holes and the influence on the performance of the material, the holes can be foam type, lotus type or honeycomb type, etc. Porous materials can also be divided into two categories according to their pore shape: independent pore type and continuous pore type. Among them, the independent type porous material has the characteristics of small specific gravity, high rigidity, high specific strength, good vibration absorption and sound absorption performance; the continuous type porous gold material not only has the above characteristics, but also has the characteristics of good permeability an...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/62
CPCH01M4/625Y02E60/10
Inventor 冯金奎安永灵
Owner SHANDONG UNIV
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