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System and method used for simultaneous on-line monitoring of plurality of heavy metals in water

A monitoring system, heavy metal technology, applied in measuring devices, color/spectral characteristic measurement, material analysis through optical means, etc., can solve the problem of inability to simultaneously measure two or more heavy metal ions, low sensitivity of heavy metal online analysis, and instrument volume and cost increase, to achieve the effects of short measurement time, low operation and maintenance requirements, and wide measurement range

Pending Publication Date: 2018-11-13
GUANGDONG INST OF ANALYSIS CHINA NAT ANALYTICAL CENT GUANGZHOU
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, when the colorimetric method is used for online analysis of water quality, different heavy metal components require different color reagents. In order to eliminate the interference of other components, special methods are required for sample processing. A single instrument cannot simultaneously measure two or more heavy metals. ions (when the monitoring parameters of heavy metals are increased, the volume and cost of the instrument will be greatly increased). At the same time, the online analysis of heavy metals in this method has low sensitivity and is easily interfered by coexisting ions. It is more suitable for high-concentration water samples and wastewater, and cannot meet the requirements of Application in surface water, groundwater, drinking water and other water environments with low concentrations of heavy metals
Electrochemical online detection mostly uses anodic stripping voltammetry, which has good sensitivity, but poor reproducibility in monitoring, and is easily interfered by organic matter in water, etc. Water samples need to be pretreated, and the heavy metals to be measured are required to be in an ionic state ; In addition, in order to prolong the service life of the electrode, in addition to the high requirements for the electrode maintenance technicians, the upper limit of the measurement of this method is low, and the measurement range is not wide

Method used

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  • System and method used for simultaneous on-line monitoring of plurality of heavy metals in water
  • System and method used for simultaneous on-line monitoring of plurality of heavy metals in water
  • System and method used for simultaneous on-line monitoring of plurality of heavy metals in water

Examples

Experimental program
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Effect test

Embodiment 1

[0041] The letters in the figure of this embodiment are respectively represented as: A, signal acquisition and control; B, operation control and information processing; C, sample.

[0042] refer to figure 1 , figure 2 and Figure 6 , is a simultaneous online monitoring system for multiple heavy metals in water, including an online sampling module 10 for regularly collecting samples and performing pretreatment, an online digestion module 20 for continuous online thermal digestion, and an online enrichment module for enrichment Module 30, online detection module 40, data processing / output module 50 for comparing and analyzing the detection results with corresponding water quality standard standard limits, system control module 60 for controlling the operation of each module; online sampling module 10, online The digestion module 20, the online enrichment module 30, and the online detection module 40 are connected in sequence; the sample solution digested by the online digesti...

Embodiment 2

[0064] refer to image 3 , the present embodiment provides a method for online monitoring of multiple heavy metals in water at the same time, and its specific process is as follows:

[0065] a) On-line sampling: On-line use the module to control the water pump 12 to suck the water sample into the water pipe filter and lift it into the settling cup 13, and separate the coarse impurities such as gravel and waste residue in the water sample under the action of gravity, after reaching the preset settling time , the control module starts the two-way electromagnetic valve 14 and the water sample after the sedimentation is passed through the fiber (or nylon) screen 15 to filter the suspended solids of fine particle size, and then the filtered water sample is passed through three stages by the first DC motor peristaltic pump 16. Through the reversing ball valve 17 and the first three-way solenoid valve 19 and lift to the online digestion module 20.

[0066] Further, the settling time...

Embodiment 3

[0084] see Figure 4 , this embodiment provides a simultaneous online monitoring system and method for multiple heavy metals in water. The difference from Embodiment 2 is that the solution after digestion and cooling directly enters the emission spectrum detection device 42 for detection, which is applicable to various types of surface water and ground water. , On-line monitoring of heavy metals in industrial wastewater. The specific process of the method is as follows:

[0085] a) According to steps 1 and 2 described in Example 1, online sampling and digestion of water samples are carried out.

[0086] b) By switching the circuit, the control module controls the fourth DC motor peristaltic pump 36 to lift the solution flowing out of the condensation pipe 28 through the third three-way solenoid valve 31 and the seventh three-way solenoid valve 314 to the online detection module 40 .

[0087] c) Analyzing, detecting and data processing the solution according to Step 4 describ...

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Abstract

The invention discloses a system used for simultaneous on-line monitoring of a plurality of heavy metals in water. The system comprises an on-line sampling module which is used for timing sampling andpretreatment, an on-line digestion module which is used for continuous on-line heat digestion, an on-line enriching module which is used for enrichment, an on-line detection module, a data processing / output module which is used for comparison analysis of detected results with corresponding water quality standard limit values, and a system control module which is used for controlling running of the above modules; the data processing / output module is connected with the on-line detection module; the system control module is connected with the on-line sampling module, the on-line digestion module, the on-line enriching module, and the on-line detection module respectively. The system is high in sensitivity, accuracy, and precision, wide in detection range; simultaneous detection of a plurality of parameters is realized, the response speed is high, and real time and dynamic change monitoring of the content of heavy metals in water is realized.

Description

technical field [0001] The invention relates to the technical field of environmental monitoring, in particular to a simultaneous online monitoring system and monitoring method for multiple heavy metals in water. Background technique [0002] The current situation of my country's water resources has problems such as total shortage, low per capita occupancy, uneven regional distribution, increasing water pollution, and prominent urban water shortages. At present, the daily discharge of sewage and wastewater in my country has reached 100 million cubic meters. According to the Bulletin of the State of the Environment in China in recent years, nearly 1 / 3 of the monitoring sections of my country's surface water is below Class IV, and 60% of the monitoring points of my country's groundwater have poor or extremely poor water quality. Heavy metal pollution is one of the most harmful water pollution problems. In my country, the problem of heavy metal pollution in surface water is ver...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N21/25G01N21/01
CPCG01N21/01G01N21/25
Inventor 郭鹏然梁维新雷永乾潘佳钏刘宁
Owner GUANGDONG INST OF ANALYSIS CHINA NAT ANALYTICAL CENT GUANGZHOU
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