Method for repairing secondary fiber or recycled fiber keratinization
A technology for recycling fibers and secondary fibers, which is applied in the field of pulping and papermaking to achieve the effect of mild conditions and simple repairing process
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Embodiment 1
[0019] Embodiment 1: The method for repairing secondary fiber or recycled fiber keratinization, the specific method is:
[0020] (1) Use a shredder to crush commercially available unbleached eucalyptus kraft dry pulp into 0.3´1cm 2 fragments of
[0021] (2) Add the dry pulp board fragments to the NaOH-urea solution that has been precooled to -13°C, and stir rapidly for 2 minutes. The mass ratio of the dry pulp board fragments to the NaOH-urea solution is 1:10, and the NaOH-urea solution In the solution, the mass concentration of NaOH in the solution is 3%, and the mass concentration of urea in the solution is 5%;
[0022] (3) At room temperature, add regeneration solution to the mixed solution in step (2), add sulfuric acid-sodium sulfate solution, regenerate for 5 minutes under magnetic stirring conditions, and carry out hydrogen bond network reconstruction, wherein the volume of sulfuric acid-sodium sulfate solution and alkaline urine solution The ratio is 1:1, the total m...
Embodiment 2
[0025] Embodiment 2: The method for repairing secondary fiber or recycled fiber keratinization, the specific method is:
[0026] (1) The handwritten sheet made in the laboratory with unbleached eucalyptus kraft dry pulp board as raw material, that is, the handwritten sheet made for the 0th time, and shredded into 0.3´1cm by shredder 2 fragments of
[0027] (2) Add the fragments in step (1) to the NaOH-urea solution that has been pre-cooled to -5°C, and stir rapidly for 2 minutes. The mass ratio of the fragments to the NaOH-urea solution is 1:50, and the NaOH-urea solution The mass concentration of NaOH in the solution is 5%, and the mass concentration of urea in the solution is 10%;
[0028] (3) At 15°C, add regeneration solution to the mixed solution in step (2), add sulfuric acid-sodium sulfate solution, regenerate for 10 minutes under magnetic stirring conditions, and carry out hydrogen bond network reconstruction, in which sulfuric acid-sodium sulfate solution and alkalin...
Embodiment 3
[0031] Embodiment 3: The method for repairing secondary fiber or recycled fiber keratinization, the specific method is:
[0032] (1) Take the 0th handwritten sheet of Example 2 as the raw material and copy it back in the laboratory, that is, the 1st recycled handwritten sheet, and use a shredder to crush the 1st recycled handwritten sheet into 1´1cm 2 fragments of
[0033] (2) Add the fragments in step (1) to the NaOH-urea solution that has been precooled to -10°C, and stir rapidly for 4 minutes. The mass ratio of the fragments to the NaOH-urea solution is 1:100. In the NaOH-urea solution The mass concentration of NaOH in the solution is 8%, and the mass concentration of urea in the solution is 15%;
[0034] (3) At 40°C, add regeneration solution to the mixed solution in step (2), add sulfuric acid-sodium sulfate solution, regenerate for 15 minutes under magnetic stirring conditions, and carry out hydrogen bond network reconstruction, in which sulfuric acid-sodium sulfate sol...
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