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Preparation method of conductive polymer material

A conductive polymer and ultrasonic technology, applied in the field of polymer materials, can solve problems affecting material flexibility, physical and mechanical properties and processability, electrical conductivity and processing properties, mechanical properties, and poor compatibility of resins. Achieve the effect of enhancing mechanical properties, improving mechanical properties, and excellent thermal conductivity

Inactive Publication Date: 2018-08-24
HEBEI JIASHICHENG ENERGY TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the volume resistivity required by highly conductive polymer materials is extremely low, and more conductive channels are required, so a large amount of carbon black must be added, which will easily lead to poor dispersion of carbon black and poorer compatibility with resins, which greatly affects the performance of the material. Flexibility, Physico-Mechanical Properties and Processability
[0003] At present, there are many kinds of composite high-conductive polymer materials, but there are contradictions between their electrical conductivity, processing performance and mechanical properties. Therefore, a better conductive polymer material is needed to improve the shortcomings of the existing technology.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] A method for preparing a conductive polymer material, comprising the steps of:

[0025] a. Mix the waste steel slag and send it into a pulverizer for crushing, and then introduce it into a ball mill for ball milling for 1 hour, then use ultrasonic oscillation for 20 minutes, and then use alcohol to wash it for 3 times, and then put it in a drying oven and dry it at 90°C for 40 minutes to obtain a powder ;

[0026] b. Mix powder 1, polyaniline and organic resin into a kneader for melting, the melting temperature is 450°C, the time is 45min, and then keep warm to obtain mixture 1;

[0027] c. Mix calcium carbonate, carbon black and graphene oxide, add ethanol solution, stir for 40 minutes at a speed of 120r / min, disperse by ultrasonic oscillation for 10 minutes, add a pH value regulator, adjust the pH value to 5, and then place Heated in a water bath at 80°C for 3 hours, filtered, rinsed with distilled water 8 times, and dried in a vacuum oven for 40 minutes at a drying ...

Embodiment 2

[0037] A method for preparing a conductive polymer material, comprising the steps of:

[0038] a. Mix the waste steel slag and send it into a pulverizer for crushing, and then introduce it into a ball mill for ball milling for 1 hour, then use ultrasonic oscillation for 20 minutes, and then wash it with alcohol for 3 times, then put it in a drying oven and dry it at 80°C for 40 minutes to obtain a powder ;

[0039] b. Mix powder 1, polyaniline and organic resin into a kneader for smelting at a melting temperature of 360°C for 45 minutes, and then keep warm to obtain mixture 1;

[0040] c. Mix calcium carbonate, carbon black and graphene oxide, add ethanol solution, stir at a speed of 100r / min for 40min, then use ultrasonic oscillation to disperse for 10min, add a pH value regulator, adjust the pH value to 5, and then place Heated in a water bath at 60°C for 2 hours, filtered, rinsed with distilled water for 5 times, and then dried in a vacuum oven for 40 minutes at a drying t...

Embodiment 3

[0050] A method for preparing a conductive polymer material, comprising the steps of:

[0051] a. Mix the waste steel slag and send it into a pulverizer for crushing, then introduce it into a ball mill for ball milling for 2 hours, then use ultrasonic oscillation for 30 minutes, and then use alcohol to wash it for 5 times, then put it in a drying oven and dry it at 90°C for 50 minutes to obtain a powder ;

[0052] b. Mix powder 1, polyaniline and organic resin into a kneader for smelting at a melting temperature of 450°C for 55 minutes, and then keep warm to obtain mixture 1;

[0053] c. Mix calcium carbonate, carbon black and graphene oxide, add ethanol solution, stir at a speed of 120r / min for 60min, then use ultrasonic oscillation to disperse for 20min, add a pH value regulator, adjust the pH value to 6, and then place Heated in a water bath at 80°C for 3 hours, filtered, rinsed with distilled water 8 times, and dried in a vacuum oven for 50 minutes at a drying temperature...

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PUM

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Abstract

The invention provides a preparation method of a conductive polymer material. The preparation method comprises the following steps: a, mixing and delivering waste steel slag into a pulverizer for pulverizing, carrying out ball milling by using a ball mill, carrying out ultrasonic oscillation, carrying out cleaning by using alcohol, and then, carrying out drying to obtain powder I; b, mixing the powder I, polyaniline and organic resin, introducing the mixture into a mixing mill for mixing, and carrying out thermal insulation to obtain a mixture I; c, mixing calcium carbonate, carbon black and graphene oxide, adding an ethanol solution, carrying out stirring and ultrasonic oscillation, regulating the pH value, carrying out water-bath heating, carrying out filtration, then, carrying out flushing with distilled water, and carrying out drying to obtain a mixture II; and d, introducing the mixture I and the mixture II into a reactor, adding carbon nanotubes, magnetic nanoparticles and an ionic solution, carrying out ultrasonic dispersion, then, adding filling oil, a lubricant, filler, a dispersant and an antioxidant to be stirred, introducing all the components into a double-screw extruder for extrusion and pelletization, and then, carrying out injection molding. The conductive polymer material is resistant to acid and alkaline corrosion; and the preparation method is low in cost andsimple in process.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, and in particular relates to a preparation method of conductive polymer materials. Background technique [0002] Composite conductive polymers are composed of polymer materials as the matrix and a certain amount of conductive substances (such as carbon black, graphite, carbon fiber, metal powder, metal fiber, metal oxide, etc.). Composite conductive polymer material is a functional polymer material composed of polymer materials and conductive substances through dispersion compounding, lamination compounding, and surface conductive film formation. The materials made by lamination and forming surface conductive film are easy to cause a lot of inconvenience after use, so the application field is also limited. Dispersion compounding is to add a large amount of conductive fillers, such as carbon black, carbon fiber, metal powder, etc., to high polymers, and then process them into composite ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08L53/02C08L79/04C08L81/02C08L65/00C08L79/02C08K13/02C08K3/08C08K3/04C08K3/26C08K5/098
CPCC08L23/0853C08K2003/0856C08K2003/265C08K2201/001C08K2201/011C08L2205/02C08L2205/035C08L23/0869C08L23/0815C08L53/02C08L79/04C08L81/02C08L65/00C08L79/02C08K13/02C08K3/08C08K3/04C08K3/26C08K3/042C08K3/041C08K5/098
Inventor 白莉莉
Owner HEBEI JIASHICHENG ENERGY TECH CO LTD
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