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A kind of preparation method and obtained product of iron ion-doped carbon nitride nanotube

A carbon nitride and iron ion technology is applied in the preparation of carbon nitride nanotubes and the preparation of ion-doped carbon nitride, which can solve the problems of uneven ion doping and easy oxidation of doped ions, and achieve high Reactivity, improved separation and transfer, good reproducibility

Inactive Publication Date: 2020-07-07
UNIV OF JINAN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] Aiming at the deficiencies in the existing ion-doped carbon nitride preparation process, such as uneven ion doping and easy oxidation of doped ions, the present invention provides a method for preparing iron ion-doped carbon nitride nanotubes and the obtained Product, the method has simple operation process, good repeatability, and good controllability. The obtained graphitic carbon nitride is in the shape of nanotubes, and the distribution of iron ions is uniform, and it is not easy to oxidize.

Method used

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  • A kind of preparation method and obtained product of iron ion-doped carbon nitride nanotube
  • A kind of preparation method and obtained product of iron ion-doped carbon nitride nanotube
  • A kind of preparation method and obtained product of iron ion-doped carbon nitride nanotube

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Embodiment 1

[0033] 1.1 Reflux 2 g of melamine and 100 ml of deionized water at 100 °C until the melamine is completely dissolved to obtain an aqueous solution of melamine.

[0034] 1.2 Make anhydrous ferric chloride into ferric chloride aqueous solution with a concentration of 0.02 g / ml, add 100 microliters of ferric chloride aqueous solution into melamine aqueous solution, and reflux at 100°C for 30 min under stirring to make melamine and ferric chloride Mix well.

[0035] 1.3 Lower the temperature of the solution in 1.2 above in stages. The specific operation is: lower the temperature of the solution in 1.2 above 100°C at a cooling rate of 1°C / min until it drops to room temperature. During the cooling process, crystals gradually precipitate.

[0036] 1.4 After the crystallization is complete, the precipitated crystals are taken out from the solution, and the solution on the crystals is blotted dry on filter paper to obtain iron-doped melamine crystals.

[0037] 1.5 The iron-doped melam...

Embodiment 2

[0042] 2.1 Reflux 2 g of melamine and 100 ml of deionized water at 100 °C until the melamine is completely dissolved to obtain an aqueous solution of melamine.

[0043]2.2 Make anhydrous ferric chloride into ferric chloride aqueous solution with a concentration of 0.02 g / ml, add 500 microliters of ferric chloride aqueous solution into melamine aqueous solution, and reflux at 100°C for 30 min under stirring to make melamine and ferric chloride Mix well.

[0044] 2.3 Lower the temperature of the solution in 2.2 above in stages. The specific operation is: lower the temperature of the 100°C solution in 2.2 above at a cooling rate of 1°C / min until it drops to room temperature. During the cooling process, crystals gradually precipitate.

[0045] 2.4 After the crystallization is complete, the precipitated crystals are taken out from the solution, and the solution on the crystals is blotted dry on filter paper to obtain iron-doped melamine crystals.

[0046] 2.5 The iron-doped melami...

Embodiment 3

[0050] 3.1 Reflux 2 g of melamine and 100 ml of deionized water at 100 °C until the melamine is completely dissolved to obtain an aqueous solution of melamine.

[0051] 3.2 Make anhydrous ferric chloride into ferric chloride aqueous solution with a concentration of 0.02 g / ml, add 1 ml of ferric chloride aqueous solution into melamine aqueous solution, and reflux at 100°C for 30 min under stirring to fully dissolve melamine and ferric chloride. well mixed.

[0052] 3.3 Lower the temperature of the solution in 3.2 above in stages. The specific operation is: lower the temperature of the 100°C solution in 3.2 above at a cooling rate of 1°C / min until it drops to room temperature. During the cooling process, crystals gradually precipitate.

[0053] 3.4 After the crystallization is complete, the precipitated crystals are taken out from the solution, and the solution on the crystals is blotted dry on filter paper to obtain iron-doped melamine crystals.

[0054] 3.5 The iron-doped mel...

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Abstract

The invention discloses a preparation method of an iron-ion-doped carbon nitride nanotube and the obtained product. The method comprises the steps that a nitrogen-containing organic precursor, ferricsalt and water are prepared into a uniform solution, the temperature rises until boiling is achieved, cooling crystallization is conducted at a specific cooling speed, and obtained crystals are calcined to obtain the final product. According to the method, iron ions are uniformly doped by utilizing the self-crystallization of the crystals, the preparation process is simple, the yield is high, theobtained product is nano-tubular, the wall thickness is 3-20 nanometers, the thin-walled nanotube has a large specific surface area and high reactivity, the iron ions distributed in a C3N4 piperazinering network and cannot be oxidized, and the method has important application significance in the field of energy materials.

Description

technical field [0001] The invention relates to a method for preparing ion-doped carbon nitride, in particular to a method for preparing iron ion-doped carbon nitride nanotubes and the resulting product, and belongs to the technical field of semiconductor material preparation. Background technique [0002] As a non-toxic, easy-to-synthesize, stable physical and chemical properties, narrow bandgap (band gap about 2.7 eV) and high earth content organic semiconductor, carbon nitride has attracted widespread attention in recent years. Carbon nitride in the graphite phase has a graphene-like layered structure and has a series of properties similar to graphene, so people have conducted a lot of exploration on it and applied it to photocatalytic degradation and photocatalytic hydrogen production. , analytical chemistry and many other fields. [0003] For carbon nitride, increasing carbon nitride active sites and ion doping are effective means to improve the separation and transfer...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J27/24B01J35/00B01J35/02B01J35/10
CPCB01J27/24B01J35/004B01J35/023B01J35/1004
Inventor 杨萍江志翔
Owner UNIV OF JINAN
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