A kind of high temperature resistant Portland cement slurry and preparation method thereof

A technology of portland cement and portland, which is applied in the field of oil well cement, can solve the problems that the cement sheath loses its interlayer isolation ability, easily causes cementing accidents, and the compressive strength is easy to decline, so as to reduce the cementing construction work cost, improve the safety of cementing construction, and the effect of no decline in compressive strength

Active Publication Date: 2020-10-09
CHINA NAT PETROLEUM CORP +2
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] (1) The 350°C high temperature compressive strength of Portland cement plus quartz sand declines very seriously, and the cement sheath easily loses the ability to seal between layers
[0005] (2) The price of aluminate cement or aluminophosphate cement is very expensive, generally more than ten times that of Portland cement
[0007] (4) At present, the application of Portland cement in the cementing industry still occupies the main market. Almost all the cementing equipment of each cementing construction unit has been in contact with Portland cement, and once the aluminate cement or aluminophosphate cement is in contact with Portland cement will flocculate, which is very sensitive and can easily cause cementing accidents
[0008] (5) Ordinary Portland cement plus quartz sand, aluminate cement, and aluminophosphate cement have a high temperature compressive strength of about 20MPa at 350°C, and the long-term compressive strength tends to decline to about 5MPa.

Method used

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  • A kind of high temperature resistant Portland cement slurry and preparation method thereof
  • A kind of high temperature resistant Portland cement slurry and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0051]This example provides a high-temperature resistant portland cement slurry, which is composed of the following components in proportion by weight: 100 parts of grade A portland cement, 69 parts of high-temperature reinforcing materials, 73 parts of fresh water, and 1 part of sulfonated Acetone formaldehyde polymer dispersant, 3 parts of 2-acrylamido-2-methylpropanesulfonic acid polymer fluid loss reducer, 0.6 part of 2-acrylamido-2-methylpropanesulfonic acid polymer retarder, 0.3 parts of tributyl phosphate, 0.1 parts of attapulgite and 2 parts of iron ore powder.

[0052] Among them, the high-temperature reinforcing material is composed of silica minerals, plagioclase, whiskers and sulfate in a mass ratio of 50:10:4:5; the particle size of the high-temperature reinforcing material formed by mixing is 0.01mm-0.15mm.

[0053] The high temperature resistant Portland cement slurry of the present embodiment is prepared through the following steps:

[0054] Dry mix the high-t...

Embodiment 2

[0058] This embodiment provides a high temperature resistant Portland cement slurry, which is composed of the following components in proportion by weight: 100 parts of Portland cement, 70 parts of high temperature reinforcing materials, 75 parts of fresh water, and 1.2 parts of sulfonated acetone formaldehyde Polymer dispersant, 3 parts of 2-acrylamido-2-methylpropanesulfonic acid polymer fluid loss reducer, 1.2 parts of 2-acrylamido-2-methylpropanesulfonic acid polymer retarder, 0.3 parts Tributyl phosphate, 0.2 parts of attapulgite and 4 parts of iron ore powder.

[0059] Among them, the high-temperature reinforcing material is composed of silica minerals, aluminates, mineral fibers, calcium hydroxide, phosphate minerals and magnesium silicate minerals in a mass ratio of 60:2:3:2:2:1; The particle size of the high-temperature reinforcing material formed by mixing is 0.01mm-0.15mm, and then the density regulator is used to adjust the density of the prepared high-temperature ...

Embodiment 3

[0061] This embodiment provides a high temperature resistant Portland cement slurry, which is composed of the following components in proportion by weight: 100 parts of Portland cement, 78 parts of high temperature reinforcing materials, 77 parts of fresh water, and 1.2 parts of sulfonated acetone formaldehyde Polymer dispersant, 3 parts of 2-acrylamido-2-methylpropanesulfonic acid polymer fluid loss reducer, 1.2 parts of 2-acrylamido-2-methylpropanesulfonic acid polymer retarder, 0.3 parts Tributyl phosphate, 0.1 parts of attapulgite and 2 parts of iron ore powder.

[0062] Among them, the high-temperature reinforcing material is composed of silica minerals, metakaolin, mineral fibers, phosphate minerals and magnesium silicate minerals in a mass ratio of 60:10:4:3:1; the high-temperature reinforcing materials formed by mixing The particle size is 0.01mm-0.15mm, and then the density regulator is used to adjust the density of the prepared high temperature Portland cement slurry...

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Abstract

The invention provides a high temperature resistant portland cement slurry and a preparation method thereof. The high temperature Portland cement slurry comprises the following components by weight: 100 parts of oil well portland cement, 60-85 parts of high-temperature reinforcing materials, 68-80 parts of fresh water, 1-200 parts of density regulator, 0.1-1.5 parts Suspension stabilizer, 0.8-1.5 parts of dispersant, 3-4 parts of fluid loss reducer, 0-3 parts of retarder and 0.2-0.8 parts of defoamer. The high-temperature resistant portland cement slurry has good settlement stability at room temperature, and its strength develops rapidly at low temperature, and its compressive strength is as high as 40MPa or more at 350°C. It meets the field application requirements of heavy oil thermal recovery wells and reaches the level of Portland G grade cement for oil and gas well cementing.

Description

technical field [0001] The invention belongs to the technical field of oil well cement, and relates to a high-temperature resistant Portland cement slurry and a preparation method thereof. Background technique [0002] At present, heavy oil recovery is mainly based on thermal oil recovery, and the steam temperature is usually as high as 350°C during thermal oil recovery. Under the condition of high-temperature thermal recovery, the wellbore will repeatedly withstand the high temperature generated by steam for multiple cycles. The compressive strength of the oil well cement sheath will decline under high temperature, the permeability will increase, and the stability and homogeneity of cement stone will be destroyed, which directly affects the wellbore. Integrity greatly shortens the production life of heavy oil thermal recovery wells and reduces production efficiency. Therefore, it is necessary to develop a cement slurry system that can improve the compressive strength at hi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B28/04C09K8/467
CPCC04B28/04C09K8/467C04B2201/20C04B2201/50C04B22/002C04B24/16C04B24/163C04B24/045C04B14/102C04B18/142C04B14/06C04B14/383C04B14/36C04B14/041C04B22/0093C04B14/46C04B22/064C04B14/366C04B14/042C04B14/106C04B2103/0029C04B2103/0035C04B2103/0036C04B2111/763C04B14/02C04B14/04C04B14/08C04B14/20C04B14/303C04B14/308C04B14/368C04B22/142C04B24/383C04B2103/20C04B2103/46C04B2103/50C04B14/043C04B14/066C04B14/34C04B24/003C04B24/166C04B2103/408C09K8/48C09K8/487
Inventor 张华靳建洲刘硕琼齐奉忠于永金徐明袁进平丁志伟周崇峰张弛刘子帅冯宇思郭玉超
Owner CHINA NAT PETROLEUM CORP
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