Bicyclo-imidazoline laurate, synthesis method therefor and application of bicyclo-imidazoline laurate

A technology of bicyclic imidazoline and monocyclic imidazoline, which is applied in the field of bicyclic imidazoline laurate and its synthesis, can solve the problems of fast penetration, poor anti-rust effect, weak electromigration ability, etc., and achieve a firm and dense film layer , increase the electron cloud density, and the effect of easy processing

Inactive Publication Date: 2018-06-15
NINGBO INST OF TECH ZHEJIANG UNIV ZHEJIANG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the current research on electromigration rust inhibitors is still in its infancy, and many problems have not been resolved.
Existing concrete electromigration rust inhibitors are mainly amines or alcohol amine organic compounds, and there are few studies on other types of compounds. Alcohol amine organic compounds are very mature and can be purchased in the market, but the synthesis purity is low, only About 40%, the anti-rust effect is not good when used
The main reason is that the cations dissociated from alcohol amines in the aqueous solution are relatively small, so the electromigration ability is weak, and they cannot quickly and fully penetrate the surface of the steel bar.

Method used

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  • Bicyclo-imidazoline laurate, synthesis method therefor and application of bicyclo-imidazoline laurate
  • Bicyclo-imidazoline laurate, synthesis method therefor and application of bicyclo-imidazoline laurate
  • Bicyclo-imidazoline laurate, synthesis method therefor and application of bicyclo-imidazoline laurate

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Effect test

Embodiment 1

[0053] A bicyclic imidazoline laurate has the following structure:

[0054]

Embodiment 2

[0056] A kind of lauric acid bicyclic imidazoline, the synthetic route of described lauric acid bicyclic imidazoline is as follows:

[0057]

Embodiment 3

[0059] According to the synthetic route of embodiment two, the synthetic method of described bicyclic imidazoline laurate comprises the following steps:

[0060] 1) Add 50 ml of thionyl chloride dropwise to 0.5 mol of lauric acid, and after half an hour, stir and react at 40°C for 5 hours; after the reaction is completed, remove excess thionyl chloride to obtain lauroyl chloride;

[0061] 2) To the solution containing 10gNaHCO 3 Add 20g of lauroyl chloride to a mixed solvent of 100ml of water and 150ml of diethyl ether, then dropwise add 1g of ethylenediamine, stir at 10°C for 10h after the dropwise addition, filter out the solid, wash with water 3 times, dry, and recrystallize in ethanol to obtain Ethylenediamine bislauramide;

[0062] 3) Add 0.5mol phenoxyphosphoryl dichloride dropwise to 20wt% ammonia water (NH 3 ·H 2O content is 1mol), after the completion of the dropwise addition, react at a temperature of -20°C for 5h, after the reaction, filter out the solid, wash wi...

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Abstract

The invention discloses bicyclo-imidazoline laurate. The bicyclo-imidazoline laurate has a symmetrical molecular structure, comprises two imidazoline heterocycles and two alkyl long chains of lauric acid, and thus, plenty and dense electronic clouds and good hydrophobicity can be provided. The invention further discloses a bicyclo-imidazoline laurate synthesis method, which is low in raw materialcost and high in reaction yield and can achieve industrial production. The invention further discloses an application of the bicyclo-imidazoline laurate. The electrotransport type cationic bicyclo-imidazoline laurate is obtained through activating bicyclo-imidazoline laurate and is applied to the rusting prevention of reinforced concrete.

Description

technical field [0001] The invention relates to the technical field of rust inhibitors, in particular to a bicyclic imidazoline laurate and its synthesis method and application. Background technique [0002] The durability of concrete structures under the chloride salt environment is a major problem bothering the world. For a long time, most of the damage to reinforced concrete structures is caused by the corrosion of steel bars, and 30-40% of concrete structures need to be repaired due to steel bar corrosion, and the economic losses caused by the corrosion of concrete and steel bars are huge. There are a large number of cases of corrosion damage to steel bars in seaports, docks, coastal facilities, and hydraulic projects in my country, most of which do not meet the requirements of the design life, and the corrosion losses are heavy. It can be seen that it is of great social and economic value to carry out the research on the prevention and control of steel corrosion, espec...

Claims

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Application Information

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IPC IPC(8): C07D233/16C25D9/02
Inventor 潘崇根金伟良毛江鸿杨超
Owner NINGBO INST OF TECH ZHEJIANG UNIV ZHEJIANG
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