Bicyclo-imidazoline laurate, synthesis method therefor and application of bicyclo-imidazoline laurate
A technology of bicyclic imidazoline and monocyclic imidazoline, which is applied in the field of bicyclic imidazoline laurate and its synthesis, can solve the problems of fast penetration, poor anti-rust effect, weak electromigration ability, etc., and achieve a firm and dense film layer , increase the electron cloud density, and the effect of easy processing
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Embodiment 1
[0053] A bicyclic imidazoline laurate has the following structure:
[0054]
Embodiment 2
[0056] A kind of lauric acid bicyclic imidazoline, the synthetic route of described lauric acid bicyclic imidazoline is as follows:
[0057]
Embodiment 3
[0059] According to the synthetic route of embodiment two, the synthetic method of described bicyclic imidazoline laurate comprises the following steps:
[0060] 1) Add 50 ml of thionyl chloride dropwise to 0.5 mol of lauric acid, and after half an hour, stir and react at 40°C for 5 hours; after the reaction is completed, remove excess thionyl chloride to obtain lauroyl chloride;
[0061] 2) To the solution containing 10gNaHCO 3 Add 20g of lauroyl chloride to a mixed solvent of 100ml of water and 150ml of diethyl ether, then dropwise add 1g of ethylenediamine, stir at 10°C for 10h after the dropwise addition, filter out the solid, wash with water 3 times, dry, and recrystallize in ethanol to obtain Ethylenediamine bislauramide;
[0062] 3) Add 0.5mol phenoxyphosphoryl dichloride dropwise to 20wt% ammonia water (NH 3 ·H 2O content is 1mol), after the completion of the dropwise addition, react at a temperature of -20°C for 5h, after the reaction, filter out the solid, wash wi...
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