Supercapacitor, electrodes therefor, and method for preparing active material of electrodes

An active material and electrode technology, which is applied in the field of preparation of supercapacitors, electrodes and active materials thereof, can solve the problems of slow redox reaction rate, ineffective active area, and increase the burden on electrodes, and avoid poor thermal conductivity and good circulation. properties, and the effect of promoting redox reactions

Inactive Publication Date: 2018-06-01
SHENZHEN INST OF ADVANCED TECH CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Traditional materials generally need to be mixed with a binder and coated on the electrode, which increases the burden on the entire electrode, easily leads to invalid active area, is easy to fall off and increases internal resistance, and has low electrical conductivity, poor thermal conductivity, and poor cycle life. weakness
And considerin

Method used

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  • Supercapacitor, electrodes therefor, and method for preparing active material of electrodes
  • Supercapacitor, electrodes therefor, and method for preparing active material of electrodes

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] A kind of preparation method of tubular copper hydroxide active material is characterized in that, comprises the steps:

[0031] S1. Choose a 0.1mm thick copper sheet with a size of 2cm×2cm.

[0032] S2. Soak the copper sheet in dilute hydrochloric acid and deionized water in sequence, so as to clean the surface of the copper sheet.

[0033] S3, then soak the cleaned copper sheet in 20mL of NaOH (concentration is 1mol / mL) and (NH 4 ) 2 S 2 o 8 (concentration of 0.5mol / mL) in the mixed solution, soak for 5min until the color of the copper sheet changes from orange to blue.

[0034] S4, take out the copper sheet, and wash it several times with water and ethanol.

[0035] S5, the copper sheet is placed in a vacuum drying oven for drying, thereby obtaining a tubular copper hydroxide active material grown on the surface of the copper sheet, which can be directly used as a pseudocapacitive integrated electrode material and used for Supercapacitor electrodes.

[0036] S...

Embodiment 2

[0039] A kind of preparation method of tubular copper hydroxide active material is characterized in that, comprises the steps:

[0040] S1. Choose a 0.2mm thick copper sheet with a size of 2cm×2cm.

[0041] S2. Soak the copper sheet in dilute hydrochloric acid and deionized water in sequence.

[0042] S3, then soak the cleaned copper sheet in 20mL of NaOH (concentration is 0.5mol / mL) and (NH 4 ) 2 S 2 o 8 (concentration of 0.5mol / mL) mixed solution; soak for 5min until the color of the copper sheet changes from orange to blue.

[0043] S4, take out the copper sheet, and wash it several times with water and ethanol.

[0044] S5, the copper sheet is placed in a vacuum drying oven for drying, thereby obtaining a tubular copper hydroxide active material grown on the surface of the copper sheet, which can be directly used as a pseudocapacitive integrated electrode material and used for Supercapacitor electrodes.

Embodiment 3

[0046] A method for preparing a tubular copper hydroxide active material is characterized by comprising the following steps.

[0047] S1. Choose a 0.2mm thick copper sheet with a size of 2cm×2cm.

[0048] S2. Soak the copper sheet in dilute hydrochloric acid and deionized water in sequence.

[0049] S3, then soak the cleaned copper sheet in 20mL of NaOH (concentration is 0.5mol / mL) and (NH 4 ) 2 S 2 o 8 (concentration of 0.5mol / mL) in the mixed solution, soak for 10min until the color of the copper sheet changes from orange to blue.

[0050] S4, take out the copper sheet, and wash it several times with water and ethanol.

[0051] S5, the copper sheet is placed in a vacuum drying oven for drying, thereby obtaining a tubular copper hydroxide active material grown on the surface of the copper sheet, which can be directly used as a pseudocapacitive integrated electrode material and used for Supercapacitor electrodes.

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Abstract

The invention discloses a supercapacitor, electrodes therefor, and a method for preparing an active material of electrodes, and the method comprises the following steps: S1, sequentially placing a copper piece in hydrochloric acid and deionized water; S2, enabling the copper piece to be immersed in a mixed solution of NaOH and (NH4)2S2O8 till the color of the copper piece is changed into blue fromorange; S3, taking out the copper piece, and washing the copper piece through water and ethyl alcohol; S4, drying the copper piece, and obtaining a tubular copper hydroxide active material growing onthe surface of the copper piece. The method promotes the invertible redox reaction of the electrode, achieves the quick charging and discharging of the electrode, prevents the ineffective area from increasing after a binder is added to a conventional powder material, solves the problems that the loosening is liable to happen the thermal conductivity and electric conductivity are poor, and obtainsthe better circularity. Meanwhile, the method is simple, is low in cost, causes no pollution, is low in energy consumption, and is suitable for batch production.

Description

technical field [0001] The invention relates to a supercapacitor, in particular to a method for preparing a supercapacitor, an electrode thereof and an active material thereof. Background technique [0002] Supercapacitors, as one of the most promising energy storage devices, are widely used in hybrid electric vehicles, portable electronic devices, and energy systems due to their high energy density, fast charging, and good cycle stability. Supercapacitors can be divided into electric double layer supercapacitors without Faraday effect and Faradaic pseudocapacitor supercapacitors based on charge storage mechanism. Supercapacitors have a higher power density than batteries and a higher energy density than general capacitors due to the fast electron transfer rate and reversible charge transfer efficiency between the electrolyte and the active material interface. [0003] At present, oxides and metal hydroxide nanomaterials of transition metal elements, such as Ni, Co, Mn, Fe,...

Claims

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Application Information

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IPC IPC(8): H01G11/24H01G11/26H01G11/30H01G11/86
CPCY02E60/13H01G11/24H01G11/26H01G11/30H01G11/86
Inventor 符显珠康佳慧盛家利谢金麒孙蓉
Owner SHENZHEN INST OF ADVANCED TECH CHINESE ACAD OF SCI
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