High-adhesion automobile putty and preparation method thereof
A technology for automobiles and putty, applied in the direction of filling slurry, etc., can solve the problems of easy shrinkage and cracking of putty, high requirements for construction conditions, and rough surface.
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Embodiment 1
[0022] (1) Preparation of high-viscosity polyester resin: 7kg maleic anhydride, 4kg tetrahydrophthalic anhydride, 3kg diethylene glycol, 5.5kg triethylene glycol, 3kg dicyclopentadiene, 1kg pentaerythritol triallyl ether, 0.004 kg p-phenylene ether, 0.6kg xylene weight ratio After weighing each component, first put diethylene glycol and triethylene glycol into the reaction kettle, heat up to 195°C under stirring and nitrogen protection conditions, and then Add maleic anhydride and tetrahydrophthalic anhydride, and cool down to 160°C when the acid value drops to 40mgKOH / g. After adding dicyclopentadiene, pentaerythritol triallyl ether, p-phenylene ether and xylene, continue to heat up React at 195°C for 35 minutes, and finally cool down to obtain a high-viscosity polyester resin, which is ready for use.
[0023](2) Mixing: 380g high-viscosity polyester resin, 15g diisocyanate, 70g 25wt% shellac ethanol solution, 7g nanometer metal powder (nanocopper powder), 6g octadecyl mercap...
Embodiment 2
[0024] (1) Preparation of high-viscosity polyester resin: 8kg maleic anhydride, 5kg tetrahydrophthalic anhydride, 4kg diethylene glycol, 6kg triethylene glycol, 4kg dicyclopentadiene, 1.5kg pentaerythritol triallyl ether, 0.005 kg p-phenylene ether, 1kg xylene weight ratio After weighing each component, first put diethylene glycol and triethylene glycol into the reaction kettle, raise the temperature to 200°C under the condition of stirring and nitrogen protection, and then add When maleic anhydride and tetrahydrophthalic anhydride are reacted until the acid value drops to 50mgKOH / g, the temperature is lowered to 170°C, and after adding dicyclopentadiene, pentaerythritol triallyl ether, p-phenylene ether and xylene, continue to heat up to React at 200°C for 40 minutes, and finally cool down to obtain a high-viscosity polyester resin, which is ready for use.
[0025] (2) Mixing materials: 400g high-viscosity polyester resin, 20g diisocyanate, 100g30wt% shellac ethanol solution,...
Embodiment 3
[0026] (1) Preparation of high-viscosity polyester resin: 5kg maleic anhydride, 3kg tetrahydrophthalic anhydride, 2kg diethylene glycol, 5kg triethylene glycol, 2kg dicyclopentadiene, 0.5kg pentaerythritol triallyl ether, 0.003 kg p-phenylene ether, 0.5kg xylene weight ratio After weighing each component, first put diethylene glycol and triethylene glycol into the reaction kettle, and raise the temperature to 190°C under the condition of stirring and nitrogen protection, and then Add maleic anhydride and tetrahydrophthalic anhydride, and cool down to 150°C when the acid value drops to 30mgKOH / g, add dicyclopentadiene, pentaerythritol triallyl ether, p-phenylene ether and xylene, and continue to heat up React at 190°C for 30 minutes, and finally cool down to obtain a high-viscosity polyester resin, which is ready for use.
[0027] (2) Mixing: 350g high-viscosity polyester resin, 10g diisocyanate, 500g 20wt% shellac ethanol solution, 5g nano-metal powder (nano-aluminum powder), ...
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