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High-adhesion automobile putty and preparation method thereof

A technology for automobiles and putty, applied in the direction of filling slurry, etc., can solve the problems of easy shrinkage and cracking of putty, high requirements for construction conditions, and rough surface.

Inactive Publication Date: 2018-03-27
HEFEI WISDOM DRAGON MACHINERY DESIGN CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The putty is atomic ash, which has the following disadvantages: (1) The curing time is too fast, the operating time is about 10 minutes, and the construction performance is poor; (2) It is easy to absorb moisture, which is not conducive to drying, and has high requirements for construction conditions; (3) ) During the construction process, it is prone to sagging, resulting in thin top and bottom thick; (4) When curing, the putty is easy to shrink and crack; (5) After curing, the surface is relatively rough, and it is easy to produce trachoma and air bubbles; (7) Adhesion Poor anti-shock performance, easy to loosen and collapse under strong vibration or impact

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] (1) Preparation of high-viscosity polyester resin: 7kg maleic anhydride, 4kg tetrahydrophthalic anhydride, 3kg diethylene glycol, 5.5kg triethylene glycol, 3kg dicyclopentadiene, 1kg pentaerythritol triallyl ether, 0.004 kg p-phenylene ether, 0.6kg xylene weight ratio After weighing each component, first put diethylene glycol and triethylene glycol into the reaction kettle, heat up to 195°C under stirring and nitrogen protection conditions, and then Add maleic anhydride and tetrahydrophthalic anhydride, and cool down to 160°C when the acid value drops to 40mgKOH / g. After adding dicyclopentadiene, pentaerythritol triallyl ether, p-phenylene ether and xylene, continue to heat up React at 195°C for 35 minutes, and finally cool down to obtain a high-viscosity polyester resin, which is ready for use.

[0023](2) Mixing: 380g high-viscosity polyester resin, 15g diisocyanate, 70g 25wt% shellac ethanol solution, 7g nanometer metal powder (nanocopper powder), 6g octadecyl mercap...

Embodiment 2

[0024] (1) Preparation of high-viscosity polyester resin: 8kg maleic anhydride, 5kg tetrahydrophthalic anhydride, 4kg diethylene glycol, 6kg triethylene glycol, 4kg dicyclopentadiene, 1.5kg pentaerythritol triallyl ether, 0.005 kg p-phenylene ether, 1kg xylene weight ratio After weighing each component, first put diethylene glycol and triethylene glycol into the reaction kettle, raise the temperature to 200°C under the condition of stirring and nitrogen protection, and then add When maleic anhydride and tetrahydrophthalic anhydride are reacted until the acid value drops to 50mgKOH / g, the temperature is lowered to 170°C, and after adding dicyclopentadiene, pentaerythritol triallyl ether, p-phenylene ether and xylene, continue to heat up to React at 200°C for 40 minutes, and finally cool down to obtain a high-viscosity polyester resin, which is ready for use.

[0025] (2) Mixing materials: 400g high-viscosity polyester resin, 20g diisocyanate, 100g30wt% shellac ethanol solution,...

Embodiment 3

[0026] (1) Preparation of high-viscosity polyester resin: 5kg maleic anhydride, 3kg tetrahydrophthalic anhydride, 2kg diethylene glycol, 5kg triethylene glycol, 2kg dicyclopentadiene, 0.5kg pentaerythritol triallyl ether, 0.003 kg p-phenylene ether, 0.5kg xylene weight ratio After weighing each component, first put diethylene glycol and triethylene glycol into the reaction kettle, and raise the temperature to 190°C under the condition of stirring and nitrogen protection, and then Add maleic anhydride and tetrahydrophthalic anhydride, and cool down to 150°C when the acid value drops to 30mgKOH / g, add dicyclopentadiene, pentaerythritol triallyl ether, p-phenylene ether and xylene, and continue to heat up React at 190°C for 30 minutes, and finally cool down to obtain a high-viscosity polyester resin, which is ready for use.

[0027] (2) Mixing: 350g high-viscosity polyester resin, 10g diisocyanate, 500g 20wt% shellac ethanol solution, 5g nano-metal powder (nano-aluminum powder), ...

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Abstract

The invention discloses high-adhesion automobile putty which is prepared from the following components in parts by weight: 350-400 parts of high viscosity polyester resin, 10-20 parts of diisocyanate,50-100 parts of 20-30wt% of shell-lac ethanol solution, 5-10 parts of nano metal powder, 5-10 parts of octadecanethiol 50-80 parts of nano-kaolin, 10-20 parts of magnesium oxide, 20-30 parts of magnesium chloride, 10-20 parts of basalt fibers, 5-10 parts of sodium fluoride, 20-30 parts of styrene, 100-150 parts of talcum powder, 50-60 parts of titanium dioxide, 5-10 parts of cobalt octoate and 200-250 parts of cyclohexanone peroxide. The high-adhesion automobile putty disclosed by the invention is high in adhesive force, high in drying speed, easy in knife coating, excellent in construction performance, smooth, flat and crack-less in appearance after curing and easy to polish. The invention further provides a preparation method of the high-adhesion automobile putty. The preparation methodis simple in process steps and high in operability and does not have special requirement on equipment.

Description

[0001] This application is the application number: 2016101433964, the application date: March 14, 2016, the title of the invention: a divisional application of a high-adhesion automobile putty and its preparation method. technical field [0002] The invention relates to a putty, in particular to a high adhesion automobile putty and a preparation method thereof. Background technique [0003] When defects such as seams, welds, and pits and scratches caused by scratches appear on the surface of the car body, it needs to be filled with putty and carefully polished to form a smooth surface for the final surface spraying. [0004] At present, the commonly used putties include acid alcohol putty, epoxy putty and putty. The drying of acid alcohol putty is greatly affected by drying temperature and humidity, and its hardness is low, and its adhesion is poor, so it is gradually eliminated; epoxy putty uses a large amount of organic solvents to reduce viscosity, resulting in the phen...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D5/34C08G63/676
CPCC08G63/676C09D5/34
Inventor 不公告发明人
Owner HEFEI WISDOM DRAGON MACHINERY DESIGN CO LTD
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