Removing method for benzopyrene in edible vegetable oil

A technology of edible vegetable oil and benzopyrene, which is applied in the direction of fat oil/fat refining and fat production, etc. It can solve problems such as food-grade solvents not being completely removed, oil drying not in time, and benzopyrene exceeding the standard, so as to eliminate potential safety hazards, Short heating time and good removal effect

Inactive Publication Date: 2018-03-16
青岛天祥食品集团有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Most edible oil production raw materials, such as camellia seed, olive, sesame, rapeseed, soybean, etc., do not contain benzopyrene. Among them, the excess of benzopyrene in oil must be related to pollution. Most of the oil plants are scattered and grown by farmers. Farmers pick and dry by themselves. Due to the limitation of drying conditions, part of the oil is dried on the asphalt road. The asphalt is exposed to high temperature and pollutes the oil. The workshops in various villages press the tea cakes, and the pressed tea cakes are then sent to the factory for leaching. Due to the limitation of production conditions, the workshops often use the method of kang drying to dry the water in the tea seeds. Roasted smoke pollutes camellia oleifera seeds, or repeatedly bakes and steams tea seeds. If the temperature is not well controlled, it is easy to cause scorching and generate benzopyrene.
In addition, if the oil is not dried in time or stored properly, mildew occurs, which will also cause benzopyrene to exceed the standard.
When solvent leaching is used in the production of vegetable oil, the food-grade solvent may not be completely removed, which will also lead to excessive benzopyrene

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] The method for removing benzopyrene in edible vegetable oil specifically includes the following steps:

[0021] (1) Degumming: select edible grade citric acid as degumming agent, add degumming agent according to 0.5% of edible vegetable oil weight, control degumming temperature 40 ℃, stirring speed 180r / min, degumming time is 50min;

[0022] (2) Deacidification: input the degummed edible vegetable oil into the molecular distillation equipment, control the vacuum degree to 2Pa, and the heating temperature to 200°C to separate free fatty acids;

[0023] (3) Preparation of adsorbent: Add twice the weight of hydrochloric acid solution with a mass fraction of 10% to diatomite, ultrasonically oscillate for 30 minutes, and then add sodium dodecylsulfonate accounting for 2-4% by weight of diatomite , continue to ultrasonically oscillate for 30 minutes, and then centrifuge to collect the precipitate; put the precipitate into 50°C water for 30 minutes, take it out, place it at 35...

Embodiment 2

[0028] The method for removing benzopyrene in edible vegetable oil specifically includes the following steps:

[0029] (1) Degumming: select edible grade citric acid as degumming agent, add degumming agent according to 0.6% of edible vegetable oil weight, control degumming temperature 45 ℃, stirring speed 180-200r / min, degumming time is 45min;

[0030] (2) Deacidification: input the degummed edible vegetable oil into the molecular distillation equipment, control the vacuum degree to 3Pa, and the heating temperature to 180°C to separate free fatty acids;

[0031] (3) Preparation of adsorbent: add twice the weight of hydrochloric acid solution with a mass fraction of 10% to diatomite, ultrasonically oscillate for 35 minutes, then add sodium dodecylsulfonate accounting for 3% by weight of diatomite, and continue Ultrasonic oscillation for 35 minutes, and then centrifuge to collect the precipitate; put the precipitate into 55°C water for 30 minutes, take it out, put it in 380°C fo...

Embodiment 3

[0036] The method for removing benzopyrene in edible vegetable oil specifically includes the following steps:

[0037] (1) Degumming: select edible grade citric acid as degumming agent, add degumming agent according to 0.8% of edible vegetable oil weight, control degumming temperature 50 ℃, stirring speed 180r / min, degumming time is 50min;

[0038] (2) Deacidification: Input the degummed edible vegetable oil into the molecular distillation equipment, control the vacuum degree to 5Pa, and the heating temperature to 170°C to separate free fatty acids;

[0039] (3) Prepare the adsorbent: add twice the weight of hydrochloric acid solution with a mass fraction of 10% to the diatomite, ultrasonically oscillate for 40 minutes, then add sodium dodecylsulfonate accounting for 4% by weight of diatomite, and continue Ultrasonic vibration for 40 minutes, and then centrifuge to collect the precipitate; put the precipitate into 60°C water for 30 minutes, take it out, place it at 400°C for 3...

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PUM

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Abstract

The invention discloses a method for removing benzopyrene from edible vegetable oil, which specifically includes the following steps: (1) degumming; (2) deacidification; (3) preparing an adsorbent; (4) preparing a mixed adsorbent; (5) decolorizing, Deodorization; (6) Filtration. The invention does not destroy any beneficial components in the edible oil through degumming first, has no influence on the quality of the edible oil, and does not cause loss of the edible oil, and the degumming effect is good; because it works under high vacuum, the heating time of the material is short, and the oil Nutrients will not be destroyed. This method is especially suitable for deodorization and deacidification of oils with high content of unsaturated fatty acids and easy oxidation. In addition, it is a large-pore particle adsorption material with large specific surface area and strong adsorption capacity, which ensures that there is no residue in the oil and can be reused. The removal effect of benzopyrene is good, which greatly improves the quality of the oil and eliminates potential safety hazards. .

Description

technical field [0001] The invention belongs to the technical field of edible oil treatment, in particular to a method for removing benzopyrene from edible vegetable oil. Background technique [0002] Edible vegetable oil Vegetable oil is a natural high molecular compound composed of fatty acid and glycerol, which is widely distributed in nature. All fats extracted from plant seeds, pulp and other parts are collectively referred to as vegetable oils. The types of edible vegetable oils. Currently, household edible vegetable oils include peanut oil, rapeseed oil, soybean oil, cottonseed oil, sesame oil, sunflower oil and many other types. Most edible oil production raw materials, such as camellia seed, olive, sesame, rapeseed, soybean, etc., do not contain benzopyrene. Among them, the excess of benzopyrene in oil must be related to pollution. Most of the oil plants are scattered and grown by farmers. Farmers pick and dry by themselves. Due to the limitation of drying conditi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C11B3/00C11B3/12C11B3/10
CPCC11B3/001C11B3/008C11B3/10C11B3/12
Inventor 于强孔德程杨增龙王青宋福荣
Owner 青岛天祥食品集团有限公司
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