A kind of preparation method of the catalyst that is used for vocs catalytic oxidation

A catalytic oxidation and catalyst technology, applied in the direction of catalyst activation/preparation, physical/chemical process catalyst, molecular sieve catalyst, etc., can solve the problems of reduced catalyst service life, poor catalytic activity, high light-off temperature, etc., to achieve good catalytic effect, Reduced usage, moderate intensity effects

Active Publication Date: 2020-07-28
TIANJIN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

These catalyst materials have their own advantages and disadvantages. For example, noble metals have very high catalytic oxidation activity for VOCs, and VOCs can be completely converted at lower temperatures, but noble metals are expensive and easily react with hydrogen chloride and hydrogen sulfide to form metal chlorides and metal sulfides. , causing it to be easily poisoned and deactivated, thereby reducing the service life of the catalyst; although transition metal oxides are abundant in reserves and low in price, they require a higher light-off temperature, and their catalytic activity is not as good as that of noble metal catalysts; It has good catalytic activity and low price, but its stability is poor and it is easy to deposit carbon

Method used

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  • A kind of preparation method of the catalyst that is used for vocs catalytic oxidation
  • A kind of preparation method of the catalyst that is used for vocs catalytic oxidation
  • A kind of preparation method of the catalyst that is used for vocs catalytic oxidation

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preparation example Construction

[0022] A preparation method for a catalyst for VOCs catalytic oxidation, comprising the following steps:

[0023] (1) Dissolve NaOH solid and 3-mercaptopropyltrimethylsilane in deionized water at a molar ratio of 20 to 25:1, and stir magnetically at 20 to 25°C to obtain the first ligand solution, usually stirring for 8 hours That’s it; in this process, the methanol produced by the hydrolysis of the 3-mercaptopropyltrimethylsilane ligand is all volatilized to prevent the subsequent addition of gold ions from being reduced;

[0024] (2) the chloroauric acid solid that contains crystal water is dissolved in water, is configured into chloroauric acid solution, drips hydrochloric acid and makes the pH of chloroauric acid solution remain between 5~6.5, to prevent the chloroauric acid solution from decomposing; then The prepared chloroauric acid solution and the first ligand solution are magnetically stirred and mixed according to the molar ratio of chloroauric acid: 3-mercaptopropyl...

Embodiment 1

[0031] (1) Dissolve 4.00g of NaOH solid and 0.82g of 3-mercaptopropyltrimethylsilane ligand in deionized water, and magnetically

[0032] Stir for 8 hours;

[0033] (2) 0.23g of chloroauric acid solid containing crystal water is dissolved in water, configured into a chloroauric acid solution, and a few drops of hydrochloric acid are added dropwise to make the pH value of the chloroauric acid solution at 5, preventing it from decomposing; the chloroauric acid solution Add dropwise to the above ligand solution, stir magnetically for 0.5h to make it evenly mixed;

[0034] (3) Take 8.10g colloidal SiO 2 Place in a sealed plastic container, stir magnetically at 80°C for 50 minutes, and then mix with the above ligand solution;

[0035] (4) 4.92g NaAlO 2 The solid was dissolved in deionized water, added dropwise to the ligand solution mixed with silica colloidal solution, and magnetically stirred at 25°C for 2 hours to form a gel solution;

[0036] (5) The above gel solution was ma...

Embodiment 2

[0042] (1) Dissolve 5.00 g of NaOH solid and 0.82 g of 3-mercaptopropyltrimethylsilane ligand in deionized water, and stir magnetically at 22°C for 8 hours;

[0043] (2) 0.45g of chloroauric acid solid containing crystal water is dissolved in water, configured into a chloroauric acid solution, and a few drops of hydrochloric acid are added dropwise to make the pH value of the chloroauric acid solution at 6.5, preventing it from decomposing; the chloroauric acid solution Add dropwise to the above ligand solution, stir magnetically for 0.5h to make it evenly mixed;

[0044] (3) Take 10.50g colloidal SiO 2 Place in a sealed plastic container, stir magnetically at 110°C for 1 hour, and then mix with the above ligand solution;

[0045] (4) 6.15g NaAlO 2 The solid was dissolved in deionized water, added dropwise to the ligand solution mixed with the silica colloidal solution, and magnetically stirred at 22°C for 2 hours to form a gel solution;

[0046] (5) The above gel solution ...

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Abstract

The invention discloses a preparation method of catalyst for VOCs catalytic oxidation, which includes steps of (1), dissolving NaOH solid and 3-mercaptopropyltrimethylsilane in the deionized water; evenly stirring to obtain first ligand solution; (2), dissolving the chloroauric acid solid containing crystalized water in the water, and preparing to be chloroauric acid solution; dropwise adding hydrochloric acid; then stirring and mixing the prepared chloroauric acid solution with the first ligand solution to obtain second ligand solution; (3), mixing gel silica and the second ligand solution toobtain third ligand solution; (4), adding NaAlO2 in the third ligand solution, filtering, drying and roasting to obtain the catalyst. The catalyst prepared by the method is good in anti-aging performance and phase change resistance.

Description

technical field [0001] The invention relates to a preparation method of a catalyst, in particular to a preparation method of a catalyst used for catalytic oxidation of VOCs. Background technique [0002] According to the definition of the World Health Organization (WHO), volatile organic compounds (VOCs, Volatile Organic Compounds) are a class of organic compounds with a boiling point between 50 and 250 °C. The saturated vapor pressure at room temperature exceeds 133.32 Pa, and they exist in the form of vapor at room temperature. A class of organic compounds in the air. [0003] VOCs come from a wide range of sources, mainly divided into industrial sources and domestic sources. Industrial sources mainly include VOCs production industries such as petroleum refining and petrochemicals, coal processing and transformation, production of basic chemical raw materials, production processes that use VOCs as raw materials such as paint, ink, and synthetic material production, as wel...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J29/068B01J37/08B01J37/18B01J37/03B01D53/86B01D53/72
CPCB01D53/86B01D53/8668B01D2257/708B01J29/068B01J37/036B01J37/086B01J37/088B01J37/18B01J2229/18
Inventor 刘庆岭苏赟宋春风纪娜马德刚
Owner TIANJIN UNIV
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