Melamine grafting modified polyurethane plastic and preparation method thereof
A technology of melamine and graft modification, applied in the field of plastics, can solve the problems of insignificant flame retardant effect of flame retardants, decline in physical and mechanical properties, loss of polyurethane performance advantages, etc., achieve excellent anti-light aging performance, and obvious flame retardant effect , good elasticity
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[0019] The melamine graft modified polyurethane plastic of the present embodiment is prepared by the following steps:
[0020] (1) Use sodium hydroxide solution to adjust the pH value of formaldehyde to 8-9, transfer it to the reaction kettle, start stirring, add melamine and urea, blow nitrogen, slowly raise the temperature to 85°C, stir and react at constant temperature for 4 hours, and then add polyether polyol , raise the temperature to 98°C, continue to stir the reaction at constant temperature for 6 hours, raise the temperature to 120°C to remove unreacted monomers and moisture in a vacuum, and cool down to obtain polyol compounds; among them, formaldehyde, melamine, urea and polyether polyols The mass ratio is 1:0.4:0.2:8;
[0021] (2) Mix silicone-modified anti-ultraviolet particles with toluene diisocyanate evenly, add the catalyst dibutyltin dilaurate, oscillate ultrasonically at 70°C for 2h, add polyol compound, raise the temperature to 85°C and stir with constant t...
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