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Modification method of alginate dressing taken as lithium battery diaphragm

A technology for lithium battery diaphragm and modification method, which is applied in the field of alginate dressing used as a modification of lithium battery diaphragm, can solve the problems of side reactions, many uncontrollable factors, high impurity content, etc., and achieve improved conductivity, simple equipment, The effect of easy operation

Inactive Publication Date: 2017-12-26
HENAN NORMAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, because it is natural cellulose, it contains a large amount of impurity ions, and the material is too fluffy, which affects the ionic conductivity and the assembly of the battery; more importantly, due to the high content of impurities and many uncontrollable factors, it affects the electrode reaction of lithium-ion batteries, such as of which Ca 2+ Side reactions will occur during battery operation, which will affect the charge and discharge performance of the battery.

Method used

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  • Modification method of alginate dressing taken as lithium battery diaphragm
  • Modification method of alginate dressing taken as lithium battery diaphragm
  • Modification method of alginate dressing taken as lithium battery diaphragm

Examples

Experimental program
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Effect test

Embodiment 1

[0017] Soak the medical alginate dressing with a slice thickness of 1.5-2.0mm in the mixed solution of absolute ethanol and lithium hydroxide, seal it and react at room temperature for 48 hours, then use filter paper to dry the surface moisture, and blow air at 80°C Dry for 8 hours, and then vacuum-dry at 100° C. for 18 hours to obtain an alginate coating film for a lithium battery separator.

Embodiment 2

[0019] Soak the medical alginate dressing with a slice thickness of 1.5-2.0mm in the mixed solution of absolute ethanol, lithium hydroxide and PAA, seal it and react it at room temperature for 48 hours, then use filter paper to dry the moisture on the surface. Blast drying for 8 hours, and then vacuum drying at 100° C. for 18 hours to obtain an alginate coating film for lithium battery separators.

Embodiment 3

[0021] Soak the medical alginate dressing with a slice thickness of 1.5-2.0mm in the mixed solution of absolute ethanol, lithium hydroxide and PEO, seal it and react it at room temperature for 48 hours, then press dry the moisture on the surface with filter paper, and heat it at 80°C Blast drying for 8 h, and then vacuum drying at 100 °C for 18 h to obtain an alginate coating film for lithium battery separators.

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Abstract

The invention discloses a modification method of an alginate dressing taken as a lithium battery diaphragm, and belongs to the technical field of alginate dressing modification. The modification method comprises the following steps: slicing a medical alginate dressing to obtain slices with a thickness of 1.5 to 2.0 mm; then soaking the medical alginate dressing in a chemical processing liquid, sealing, carrying out reactions for 10 to 72 hours at a room temperature, absorbing the solvent in the alginate dressing by liquid absorbing paper, drying alginate dressing at a temperature of 80 DEG C for 6 to 12 hours, and then drying alginate dressing in vacuum at a temperature of 100 DEG C for 10 to 48 hours to obtain a alginate dressing film, which has a thickness of 0.5-2.0 mm and porosity of 60-80% and is used as a lithium battery diaphragm. A technology with a low cost is used to modify a lithium ion battery diaphragm, the structure of the lithium ion battery diaphragm becomes more compact, the lithium ions can go through the battery diaphragm more easily, impurities such as Ca2+ are removed; the side reactions, which may influence the performance of lithium ion batteries, are effectively prevented; and the properties of prepared lithium ion battery diaphragm are excellent, in particular, lithium ion transmission performance.

Description

technical field [0001] The invention belongs to the technical field of modifying an alginate dressing used as a lithium battery diaphragm, and in particular relates to a modification method for an alginate dressing used as a lithium battery diaphragm. Background technique [0002] Due to the characteristics of high energy density, high cell voltage, good rate performance, small self-discharge and environmental protection, lithium-ion batteries are widely used in digital products, electric vehicles and electric vehicles. The most commonly used diaphragm material for lithium-ion batteries is polyolefin material, but because polyolefin material itself is non-polar, it has poor wettability to water and electrolyte, which seriously affects its liquid absorption rate to electrolyte Electrochemical properties such as , liquid retention rate and ionic conductivity also affect the further modification of the separator surface. Therefore, this patent proposes an innovative material—m...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M2/14H01M2/16H01M10/0525H01M50/403H01M50/429H01M50/497
CPCH01M10/0525H01M50/431H01M50/403Y02E60/10
Inventor 李苞牛瑾王新博代冬梅刘晓阳常照荣汤宏伟
Owner HENAN NORMAL UNIV
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