A Method for Dynamically and Reversibly Tuning the Properties of Surface Plasmon Resonance
A technology of surface plasmon and surface plasmon, applied in the field of excitonic photonics, can solve the problems of complex control process, poor repeatability, high cost, etc., and achieve the effect of strong controllability, good effect and high sensitivity
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[0041] In some embodiments, the preparation method of the chalcogenide-copper compound-coated noble metal nanomaterial comprises:
[0042] In a protective atmosphere, the noble metal nanoparticles are dispersed in deionized water, and a surfactant is added to form a nanoparticle dispersion;
[0043] maintaining a protective atmosphere, while adding a selenium source and / or a sulfur source to the nanoparticle dispersion, and then adding a reducing agent to obtain a reaction system containing selenium and / or sulfur-coated noble metal nanoparticle intermediates;
[0044] A copper source is added to the reaction system containing the selenium and / or sulfur-coated noble metal nanoparticle intermediate to carry out the reaction to form the chalcogen copper compound-coated noble metal nanomaterial.
[0045] In some more specific embodiments, the method for dynamically and reversibly regulating surface plasmon resonance properties includes: dispersing a noble metal salt in a solvent c...
Embodiment 1
[0075] Embodiment 1 Embodiment 1 of the present invention provides a composite nanomaterial, which is prepared according to the following steps:
[0076] (1) First, a gold seed solution is prepared. Stir the chloroauric acid solution and cetyltrimethylammonium bromide solution evenly at room temperature, quickly add the reducing agent sodium borohydride solution stored in an ice bath, keep stirring for 2 minutes, and then stand at 25-30°C 30min to 1h to get the gold seed solution. Second, prepare gold rod growth solution. Stir cetyltrimethylammonium bromide aqueous solution, silver nitrate solution and chloroauric acid solution evenly at room temperature, then add reducing agent ascorbic acid solution, and keep stirring until the solution is colorless. Finally, adding a certain amount of the prepared gold seed solution into the gold rod growth solution, stirring for 10 seconds, and then standing at 25-35°C for 8-12 hours to obtain rod-shaped gold nanoparticles;
[0077] (2)...
Embodiment 2
[0082] Embodiment 2 The present invention adjusts the method of Embodiment 1: increase the air exposure time in step (5), carry out an absorption spectrum measurement every 30min at the beginning, carry out an absorption spectrum measurement every 1h in the mid-term, and carry out once every 2h in the later stage Absorption spectroscopy measurements, the results are as follows Figure 4 as shown ( Figure 4 The middle arrow shows the variation trend of the absorption spectrum gradually increasing with the air exposure time), it can be seen that this embodiment can realize the controllable adjustment of the surface plasmon resonance properties of the material.
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