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Scale inhibitor for sewage treatment, and preparation method thereof

A technology for sewage treatment and scale inhibitor, which is applied in water/sludge/sewage treatment, chemical instruments and methods, descaling and water softening, etc. Enterprise production costs and other issues, to achieve the effect of good inhibition ability, good scale inhibition effect, and lower operating costs

Inactive Publication Date: 2017-08-04
陕西丝路愿景环境能源科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] With the increasing shortage of water resources and the further deterioration of the water quality environment, sewage treatment has become a key research object in the field of environment, and scaling often occurs in various types of sewage, and high scaling will be used in most water treatment technologies. serious impact on equipment, etc., which in turn affects its purification effect on sewage
In the water treatment method, the reverse osmosis method has the advantages of saving land area, low operating cost, no secondary pollution, stable effluent water quality and high degree of automation control. It is widely used and has become the main technology for pure water preparation in many industries; however, in the actual operation process, the fouling on the surface of the reverse osmosis membrane will seriously affect the normal and stable operation of the system, deteriorate the quality of the effluent, shorten the service life of the reverse osmosis membrane, Increase the production cost of the enterprise; adding antiscalant is an important means to prevent scaling
[0003] The currently developed environmentally friendly antiscalants such as polyepoxysuccinic acid and polyaspartic acid have unsatisfactory antiscaling effects in practical applications, while phosphorus-containing antiscalants on the market have better Antiscalant effect, but cannot meet the requirements of environmental protection, so it is necessary to provide an antiscalant with good antiscaling effect and environment friendly

Method used

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  • Scale inhibitor for sewage treatment, and preparation method thereof
  • Scale inhibitor for sewage treatment, and preparation method thereof
  • Scale inhibitor for sewage treatment, and preparation method thereof

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preparation example Construction

[0031] The preparation method of the above-mentioned scale inhibitor for sewage treatment is specifically implemented according to the following steps:

[0032] Step 1, get the following raw materials respectively by mass percentage:

[0033] Maleic anhydride 2.75% to 5.34%, sodium p-styrene sulfonate 1.86% to 1.93%, hydroxyethyl methacrylate 0.94% to 1.21%, initiator 0.45% to 0.82%, molecular regulator 0.45% to 0.82%, Distilled water 90.11% ~ 93.45%, the total content of the above raw materials is 100%;

[0034] Wherein, what initiator adopts is ammonium persulfate or other peroxides; Molecular regulator is tert-butanol;

[0035] Step 2, fix the three-neck flask, constant pressure dropping funnel and reflux condenser on the constant temperature heating magnetic stirrer, then add the maleic anhydride, sodium p-styrenesulfonate and hydroxyethyl methacrylate weighed in step 1 , Molecular regulator and distilled water are added in the three-necked flask, stirred and heated unti...

Embodiment 1

[0047] Step 1. Weigh respectively: 17.7608g of maleic anhydride, 6.1857g of sodium p-styrenesulfonate, 3.1234g of hydroxyethyl methacrylate, 2.707g of ammonium persulfate, 2.707g of tert-butanol, and 300g of distilled water;

[0048] Step 2, fix the three-neck flask, constant pressure dropping funnel and reflux condenser on the constant temperature heating magnetic stirrer, then add the maleic anhydride, sodium p-styrene sulfonate and hydroxyethyl methacrylate weighed in step 1 , tert-butanol and distilled water were added into a three-necked flask for stirring and heated to 85°C until all the solids in the three-necked flask were dissolved to obtain a mixed solution a;

[0049] Step 3. Add the initiator weighed in step 1 dropwise to the mixed solution a obtained in step 2 using a constant pressure dropping funnel. After the dropwise addition, carry out heat preservation treatment for 2.5 hours. After the reaction is completed, cool to room temperature, and then Adjust the pH ...

Embodiment 2

[0054] Step 1. Weigh respectively: maleic anhydride 8.8254g, sodium p-styrenesulfonate 6.1857g, hydroxyethyl methacrylate 3.1234g, ammonium persulfate 1.4508g, tert-butanol 1.4508g, distilled water 300g;

[0055] Step 2, fix the three-neck flask, constant pressure dropping funnel and reflux condenser on the constant temperature heating magnetic stirrer, then add the maleic anhydride, sodium p-styrenesulfonate and hydroxyethyl methacrylate weighed in step 1 , tert-butanol and distilled water were added to a three-necked flask for stirring and heated to 80°C until all the solids in the three-necked flask were dissolved to obtain a mixed solution a;

[0056] Step 3. Add the initiator weighed in step 1 dropwise to the mixed solution a obtained in step 2 using a constant pressure dropping funnel. After the dropwise addition, carry out heat preservation treatment for 3 hours. After the reaction is completed, cool to room temperature, and then use Sodium hydroxide solution adjusts th...

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Abstract

The invention discloses a scale inhibitor for sewage treatment. The scale inhibitor is a copolymer synthesized through a reaction of 2.75-5.34 mass% of maleic anhydride, 1.86-1.93 mass% of sodium p-styrenesulfonate, 0.94-1.21 mass% of hydroxyethyl methylacrylate, 0.45-0.82 mass% of an initiator, 0.45-0.82 mass% of a molecular regulator and 90.11-93.45 mass% of distilled water. The invention also discloses a preparation method of the scale inhibitor. The preparation method comprises the following steps: weighing certain amounts of the maleic anhydride, odium p-styrenesulfonate, hydroxyethyl methacrylate, the molecular regulator and distilled water, heating to dissolve above materials, adding the initiator, and finally carrying out precipitation purification, suction filtration and vacuum drying to finally obtain the finished scale inhibitor. The scale inhibitor disclosed in the invention has the advantages of solving of low scale inhibition efficiency and pollution of nitrogen and phosphorus elements to environment of existing scale inhibitors, avoiding of the problem of reverse osmosis membrane scaling in a water treatment system, simple synthesis method and low cost.

Description

technical field [0001] The invention belongs to the technical field of water treatment chemicals, and in particular relates to a scale inhibitor for sewage treatment, and also relates to a preparation method of the scale inhibitor. Background technique [0002] With the increasing shortage of water resources and the further deterioration of the water quality environment, sewage treatment has become a key research object in the field of environment, and scaling often occurs in various types of sewage, and high scaling will be used in most water treatment technologies. It will seriously affect the instruments and equipment, and then affect its purification effect on sewage. In the water treatment method, the reverse osmosis method has the advantages of saving land area, low operating cost, no secondary pollution, stable effluent water quality and high degree of automation control. It is widely used and has become the main technology of pure water preparation in many industrie...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F5/10C08F222/06C08F212/14C08F220/28
CPCC02F5/10C08F222/06C08F212/14C08F220/281
Inventor 余嵘张桐
Owner 陕西丝路愿景环境能源科技有限公司
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