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Foamy carbon based heat-insulation composite material with light weight and high strength

A technology of composite materials and carbon foam, which is applied in applications, household utensils, ceramic products, etc., can solve the problems of limited temperature tolerance and mechanical performance improvement, loose structure and poor compactness of SiC coating materials, and improve oxidation resistance ability, improving mechanical properties, and reducing size

Active Publication Date: 2017-06-30
NANJING UNIV OF AERONAUTICS & ASTRONAUTICS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the SiC coating material obtained by this preparation method has a loose structure and poor compactness, and the temperature tolerance and mechanical properties of carbon foams in an aerobic environment are limited.

Method used

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  • Foamy carbon based heat-insulation composite material with light weight and high strength
  • Foamy carbon based heat-insulation composite material with light weight and high strength

Examples

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Effect test

Embodiment 1

[0016] refer to figure 1 , the foam carbon-based composite material includes substrate foam carbon, silicon carbide coating, network silicon carbide nanowires, the silicon carbide coating is coated on the surface of the foam carbon skeleton, and the network silicon carbide nanowires fills the three-dimensional pores with a porosity of 96 %, the average pore size is 100nm, and the apparent density is 0.05g / cm 3 , the compressive strength is 6MPa, the silicon carbide coating thickness is 0.5μm, the silicon carbide nanometer diameter is 100nm, and the average length is 42μm.

Embodiment 2

[0018] refer to figure 2 , the foamed carbon-based composite material includes substrate foamed carbon, silicon carbide coating, and networked silicon carbide nanowires. The silicon carbide coating is coated on the surface of the foamed carbon skeleton, and the networked silicon carbide nanowires fills three-dimensional pores. %, the average pore diameter is 60nm, and the apparent density is 0.06g / cm 3 , the compressive strength is 9MPa, the silicon carbide coating thickness is 0.7μm, the silicon carbide nanometer diameter is 60nm, and the average length is 40μm.

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Abstract

The invention provides a foamy carbon based heat-insulation composite material with light weight and high strength. The foamy carbon based heat-insulation composite material with light weight and high strength is characterized by comprising a base material foamy carbon, an SiC coating and reticulated SiC nanowires, wherein a foamy carbon skeleton is coated with the SiC coating; three-dimensional pores are filled with the reticulated SiC nanowires, porosity is 90%-95%, average pore diameter is 50 nm-500 nm, apparent density is 0.05-0.2 g / cm<3>, and compressive strength is 5-15 MPa. Foamy carbon is flexible foamy carbon and is prepared from melamine foam through high-temperature pyrolysis, the porosity is 99% or higher, and the average pore diameter is 20-50 mu m; the thickness of the SiC coating is 0.5-1 mu m, the diameter of the SiC nanowires is 50-300 nm, the average length is 30-50 mu m, and all the SiC nanowires are prepared with a chemical vapor deposition method. The light foamy carbon based heat-insulation composite material with high strength has the advantages as follows: 1, the foamy carbon skeleton is coated with SiC, so that oxidation resistance of the composite material is improved; 2, the foamy carbon skeleton is coated with SiC, and mechanical properties of the composite material are improved accordingly; 3, internal pores of foam are segmented by the SiC nanowires, the internal pore diameter is reduced, and the heat conductivity of the composite material is reduced.

Description

technical field [0001] The invention relates to a foamed carbon-based heat-insulating composite material, in particular to a lightweight and high-strength foamed carbon-based heat-insulated composite material. Background technique [0002] With the development of space vehicles and missiles, new hypersonic vehicles will suffer severe aerodynamic heating during long-duration cruise or re-entry in dense atmosphere. In order to prevent thermal damage to internal structures and instruments caused by aerodynamic heating during long-term flight of high-speed aircraft, this type of aircraft requires a high-temperature resistant, efficient, and lightweight thermal protection system. However, the use temperature of existing organic heat insulation materials is not high, and the heat insulation effect of inorganic fiber heat insulation materials used for high temperature heat insulation is limited by the production process and it is difficult to further improve, especially in high tem...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/524C04B38/06C04B41/89
CPCC04B35/524C04B38/0615C04B41/009C04B41/52C04B41/89C04B2235/77C04B2235/96C04B38/0074C04B38/0054C04B41/5059C04B41/4531C04B41/4596C04B41/526
Inventor 陈照峰余盛杰汪洋
Owner NANJING UNIV OF AERONAUTICS & ASTRONAUTICS
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