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Lithium iron phosphate preparing method

一种磷酸亚铁锂、酸液的技术,应用在锂离子电池领域,能够解决无记忆效应、环境危害等问题,达到良好技术效果、容易脱附、净化效率高的效果

Active Publication Date: 2017-06-30
RIZHAO HUAXUAN NEW ENERGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

④No memory effect
However, harmful gases will be produced during the solid phase sintering process, the main components are ammonia, carbon dioxide, carbon monoxide and other harmful gases
[0006] In the prior art, there is no suitable treatment method for purifying the tail gas generated in the production process of the above-mentioned solid-phase sintering method of lithium iron phosphate. If the above-mentioned tail gas is directly discharged outside, it will bring great harm to the environment.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] A preparation method for lithium iron phosphate, comprising the steps of:

[0036] Step (1), select raw materials for preparing lithium ferrous phosphate and prepare lithium ferrous phosphate products by high-temperature solid-state reaction method; the raw materials described in step (1) are iron source, phosphorus source, lithium source, specifically iron source, phosphorus source Source, lithium source are ferrous oxalate, ammonium dihydrogen phosphate, lithium carbonate respectively; Described high-temperature solid phase reaction method is: according to iron source: phosphorus source: lithium source=1:1:1 Molar ratio mixing grinding; After grinding and drying, transfer the material to a pre-calcining furnace for calcination at 600°C under a nitrogen atmosphere. The sintering time is 1 hour. After the first sintering, the material is ball-milled, and then the second sintering is carried out. The temperature of the second sintering is 650°C. The sintering time is 1 h...

Embodiment 2

[0046] A preparation method for lithium iron phosphate, comprising the steps of:

[0047] Step (1), select raw materials for preparing lithium iron phosphate and prepare lithium iron phosphate product by high-temperature solid-state reaction method. The raw materials described in the step (1) are iron source, phosphorus source, and lithium source, and the specific iron source, phosphorus source, and lithium source are respectively ferrous oxalate, ammonium dihydrogen phosphate, and lithium carbonate. The high-temperature solid-phase reaction method is: mixing and grinding according to the molar ratio of iron source: phosphorus source: lithium source = 1:1:1. After grinding and drying, the material is transferred to a pre-calcining furnace for calcination under a nitrogen atmosphere at 700°C. The sintering time is 5 hours. After the first sintering, the material is ball-milled, and then the second sintering is carried out. The temperature of the second sintering is 750°C. The ...

Embodiment 3

[0056] A preparation method for lithium iron phosphate, comprising the steps of:

[0057] Step (1), select raw materials for preparing lithium iron phosphate and prepare lithium iron phosphate product by high-temperature solid-state reaction method. In step (1), the iron source, phosphorus source, lithium source and carbon source are weighed, and the specific iron source, phosphorus source, lithium source and carbon source are respectively ferrous oxalate, ammonium dihydrogen phosphate, lithium carbonate and glucose. The added amount is iron: phosphorus: lithium = 1:1:1 (molar ratio), and the molar ratio of glucose to lithium source is 0.2:1. The high-temperature solid-phase reaction method is: mixing and grinding the raw materials according to the molar ratio. After grinding and drying, transfer the material to a pre-calcining furnace for calcination at 600°C under a nitrogen atmosphere. The sintering time is 1 hour. After the first sintering, the material is ball-milled, an...

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PUM

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Abstract

Disclosed is a lithium iron phosphate preparing method.. The lithium iron phosphate preparing method can efficiently purify exhaust generated during production of lithium iron phosphate through the high-temperature solid state method and obtain good technical effects and considerable economic and environmental benefits. According to the lithium iron phosphate preparing method, ammonia gas in exhaust gas is processed through an ammonia gas purifying tower to obtain fertilizer containing ammonium sulfate for sale, so that ammonia content during a roasting process can be effectively utilized, the cost of scale production can be reduced, environment protection can be achieved and considerable economic benefits can be obtained; the ammonia gas exchanges heat with high-temperature exhaust, so that ammonia can be preheated before roasting, heat of the exhaust can be effectively utilized, reaction rate and product purity can be improved, energy can be saved and energy consumption can be further reduced; carbon monoxide absorbent are used for removing carbon monoxide in the exhaust, so that harmful gas can be further reduced, and significant environmental benefits can be achieved.

Description

technical field [0001] The invention belongs to the field of lithium-ion batteries, and is a branch case of the invention patent application "A Preparation Method for Lithium-Ion Battery Material Lithium Ferrous Phosphate" (application number: 2015102532337). Specifically, it relates to a preparation method of lithium iron phosphate. The method efficiently purifies tail gas generated in the production process of lithium iron phosphate, and has considerable economic and environmental benefits by turning waste into treasure. Background technique [0002] As a high-energy chemical power source, lithium-ion batteries have been widely used in mobile communications, notebook computers, video cameras, cameras, portable instruments and other fields. . [0003] Lithium iron phosphate is a recently developed lithium-ion battery electrode material, mainly used in power lithium-ion batteries, as a positive electrode active material. It is also called lithium iron phosphate in the field...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B25/45C01C1/242C05C3/00H01M4/58B01D53/02
CPCB01D53/02B01D2253/25B01D2257/502C01B25/45C01C1/242C05C3/00H01M4/5825Y02E60/10Y02P20/50
Inventor 王海峰谷亦杰朱友坤
Owner RIZHAO HUAXUAN NEW ENERGY
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