Non-destructive detection method for pesticide residues in fruits and vegetables
A non-destructive testing and pesticide residue technology, applied in measuring devices, instruments, and material analysis through optical means, can solve problems such as inappropriate on-site detection of pesticide residues, difficult and complex detection methods, etc., and achieve information volume and complexity The effect of increasing, increasing the difficulty of distinguishing, and removing material interference
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Embodiment 1
[0049] Example 1: SERS non-destructive detection of pesticide residues on the surface of spinach
[0050] 1. Experimental materials
[0051] Deltamethrin pesticide: emulsifiable concentrate preparation, active ingredient content is 25g / L, purchased from Bayer Crop Science (China) Co., Ltd., Germany, production date 2016 / 3 / 2; surface enhancer: Easy Peak (Shufeng TM) scientific research type No. 2 silver sol, purchased from Shanghai Nateng Instrument Co., Ltd.; spinach: commercially available, with uniform leaf size and color.
[0052] 2. Sample Preparation
[0053] According to the provisions of the national standard GB 2763-2014 on the maximum residue limits of pesticide residues in food, the deltamethrin content in spinach should not exceed 0.5mg / kg, so the experimental implementation plan is as follows:
[0054] Prepare 15 standard solutions of deltamethrin with different concentrations, using deionized water as solvent, 25g / L deltamethrin EC as solute, and the mass fracti...
Embodiment 2
[0070] Example 2: Non-destructive testing of multiple pesticide residues on the surface of apples
[0071] 1. Experimental materials
[0072] Chlorpyrifos, malathion, and imidacloprid are three pesticide standard substances, the standard value of which is 1.0mg / ml, all purchased from the Institute of Standard Materials, China Institute of Metrology; surface enhancer: Easy Peak (Shufeng TM) scientific research type 2 Silver sol, purchased from Shanghai Nateng Instrument Co., Ltd.; Fuji apple: commercially available, uniform in shape, size and color.
[0073] 2. Sample Preparation
[0074] Three pesticide standard substances, chlorpyrifos, malathion and imidacloprid, were used as residues to prepare pesticide residue samples. Six commercially available Fuji apples with uniform shape and size were selected to add the three kinds of pesticide residue samples respectively. A sample of pesticide residues can be used to explore the influence of the background on the modeling later....
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