Flame-retarding liquid and preparation method of flame-retarding liquid

A technology of flame retardant liquid and mixed liquid, which is applied in the direction of coating, fireproof coating, starch coating, etc., can solve the problems of inability to exert flame retardant effect, easy cracking, complicated preparation process, etc., and achieve commercial mass production, Good flame retardant function and simple preparation process

Active Publication Date: 2017-05-31
FUJIAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] So far, there are roughly four types of water-based flame retardant fluids: (1) The liquid composite system based on hydrated sodium silicate has the advantages of low cost, no aldehyde pollution, and the ability to form an inorganic film on the surface of the flame retardant. However, the weather resistance of this system is relatively poor, which shows that the cured flame retardant coating is prone to pan-alkali and brittle and cracks when it is damp; (2) a liquid composite system based on ammonium polyphosphate and amino resin, and the amino resin is mainly urea-formaldehyde resin , melamine resin or phenol or melamine modified products of the above resins. This kind of flame retardant liquid has the advantages of wide sources, good flame retardant performance, and high cost performance, but it contains aldehydes, which cause volatile pollution and contact toxicity. (3) Liquid composite system based on ammonium polyphosphate and non-aldehyde resins such as water-based polyurethane and / or water-based acrylic acid; (4) Liquid composite system based on ammonium polyphosphate and inorganic silicon, boron or rare earth compounds
The latter two types of flame retardant liquids have the advantages of being green, harmless or low-toxic and pollution-free, but they not only have complicated preparation processes and high application costs, but also cannot exert ideal flame-retardant effects in most occasions, and often need to be combined with other System synergies

Method used

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  • Flame-retarding liquid and preparation method of flame-retarding liquid
  • Flame-retarding liquid and preparation method of flame-retarding liquid
  • Flame-retarding liquid and preparation method of flame-retarding liquid

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] (a) Put 7000 grams of water, 800 grams of phytic acid, 400 grams of melamine and 200 grams of ethylene urea into the reaction kettle equipped with mechanical stirring and temperature control system, and mix them at 30°C, 20°C, and 10°C respectively Carry out the first reaction for 0.1h;

[0021] (b) Then add 1000 grams of water-soluble polyamide, 1000 grams of starch, 30 grams of phosphomolybdic acid and 20 grams of nickel sulfamate to the mixing system, and heat up at 120°C for a second mixing reaction for 0.5 hours;

[0022] (c) Then add 1350 grams of sodium methyl silicate and 150 grams of direct orange S water-soluble dye to the mixing system, and cool down at 10°C to implement the third mixing reaction for 5 hours;

[0023] (d) Finally, the obtained mixture was left to age at room temperature of 10°C for 48 hours, filtered, and the filter residue was removed to obtain the flame retardant liquid product 1.

Embodiment 2

[0025] (a) Add 5000 grams of water, 1300 grams of phytic acid, 500 grams of melamine and 280 grams of ethylene urea to a reaction kettle equipped with a mechanical stirring and temperature control system, and mix them at 20°C for the first reaction for 0.5 h;

[0026] (b) Then add 1000 grams of water-soluble polyamide ester, 300 grams of starch, 50 grams of phosphomolybdic acid and 30 grams of nickel sulfamate to the mixing system, and heat up at 80°C for a second mixing reaction for 2 hours;

[0027] (c) Then add 1850 g of sodium methyl silicate to the mixing system, and cool down at 30°C to implement the third mixing reaction for 2.8 hours;

[0028] (d) Finally, the obtained mixture was left to age at room temperature of 30°C for 36 hours, filtered, and the filter residue was removed to obtain the flame retardant liquid product 2.

Embodiment 3

[0030] (a) Add 4000 grams of water, 1800 grams of phytic acid, 600 grams of melamine and 350 grams of ethylene urea to a reaction kettle equipped with a mechanical stirring and temperature control system, and mix them at 30°C for the first reaction of 0.1 h;

[0031] (b) Then add 1000 grams of water-soluble polyamide, 650 grams of starch, 10 grams of phosphomolybdic acid and 10 grams of nickel sulfamate to the mixing system, and heat up at 120°C for a second mixing reaction for 0.5 hours;

[0032] (c) Then add 800 grams of sodium methyl silicate and 75 grams of 2-(2-hydroxy-1-naphthalene azo)-1-naphthalenesulfonate barium water-soluble pigment to the mixing system, and cool down to 50 ° C Implement the third mixing reaction for 0.5h;

[0033] (d) Finally, the obtained mixture was left to age at room temperature of 40°C for 24 hours, filtered, and the filter residue was removed to obtain the flame retardant liquid product 3.

[0034] The above-mentioned water-soluble polyamid...

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PUM

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Abstract

The invention discloses flame-retarding liquid and a preparation method of the flame-retarding liquid. The flame-retarding liquid is prepared from the following components in parts by weight: 100 parts of water-soluble polyesteramide, 30 to 100 parts of starch, 1 to 5 parts of phosphomolybdic acid, 1 to 3 parts of nickel aminosulfonate, 40 to 60 parts of melamine, 80 to 180 parts of phytic acid, 20 to 35 parts of ethylene urea, 400 to 700 parts of water and 80 to 185 parts of sodium methyl silicate through mixing and reacting. The preparation method can be implemented according to the following steps: mixing the melamine, the phytic acid, the ethylene urea and the water and reacting; then adding the water-soluble polyesteramide, the starch, the phosphomolybdic acid and the nickel aminosulfonate and heating to carry out the second time of reaction; then adding the sodium methyl silicate, and cooling and carrying out the third time of reaction; finally, ageing and standing at room temperature, and filtering to remove dreg. The flame-retarding liquid disclosed by the invention is water-based flame-retarding liquid and does not contain halogen and aldehydes substances; the flame-retarding liquid is used as a flame-retarding coating and has good flame-retarding and weather-resisting performances.

Description

technical field [0001] The invention relates to the technical field of flame retardant and fire protection, in particular to a flame retardant liquid and a preparation method thereof. Background technique [0002] Liquid substances with flame retardant and fireproof functions can be called flame retardant liquids. Flame retardant liquid mainly plays the role of flame retardant and fire prevention through dipping, coating, spraying and curing wrapping, etc. It has extensive and important applications in the aspects of coating flame retardant, interlayer fire prevention and flame retardant finishing. Water-based flame retardant fluids have the advantages of wide sources, low cost, environmental protection, high adhesion to polar substrates, and impregnation, and have been favored in this field. [0003] So far, there are roughly four types of water-based flame retardant fluids: (1) The liquid composite system based on hydrated sodium silicate has the advantages of low cost, n...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D177/12C09D103/02C09D5/18C09D7/12
CPCC08L2201/02C09D5/18C09D7/61C09D7/63C09D103/02C09D177/12C08L3/02C08K13/02C08K3/32C08K5/42C08K5/5419
Inventor 陈荣国陈潇川林国良肖荔人陈庆华钱庆荣
Owner FUJIAN UNIV OF TECH
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