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Antibacterial PA66/ABS composite material and preparation method thereof

The technology of composite material and antibacterial agent is applied in the field of antibacterial nylon composite material and its preparation.

Active Publication Date: 2017-05-31
ZHUZHOU TIMES NEW MATERIALS TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The above existing patents all use organic antibacterial agent and inorganic antibacterial agent compound antibacterial system, which has achieved good antibacterial effect, but the PA content contained in the system is small, and the material has excellent wear resistance, self-lubrication and surface matte effect, etc. Poor aspects, resulting in limited application in some fields
In addition, because the organic antibacterial agent in the compound antibacterial system has problems such as poor heat resistance, short life, easy to decompose, and difficult to degrade, it is not conducive to the promotion in the PA66 / ABS alloy system with high PA66 content.

Method used

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  • Antibacterial PA66/ABS composite material and preparation method thereof

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Embodiment 1-3

[0037] The antibacterial PA66 / ABS composite material of three embodiments of the present invention shown in the formula of Table 1, the antibacterial PA66 / ABS composite material is mainly obtained by blending and melting the components shown in the following Table 1:

[0038] Table 1: PA66 / ABS composite material formulation

[0039] components Example 1 Example 2 Example 3 Comparative example 1 Comparative example 2 Comparative example 3 PA66 50 60 70 50 60 70 processing activator 15 20 25 15 20 / ABS 50 40 30 50 40 30 Compatibilizer 5 5 5 5 5 5 Toughener 15 15 12 15 / 12 Diffuser oil 0.1 0.2 0.2 0.1 0.2 0.2 Antibacterial agents 0.8 1.1 1.5 / 1.1 1.5 antioxidant 0.3 0.3 0.3 0.3 0.3 0.3

[0040] The processing activator used in the above examples is binary copolymerized nylon of nylon 6 and nylon 66, with a melting point of 185° C. and a relative viscosity of 2.2.

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Abstract

The invention relates to an antibacterial PA66 / ABS composite material. The antibacterial PA66 / ABS composite material is mainly prepared through blending the following ingredients in parts by mass and carrying out melting: 50-70 parts of polyhexamethylene adipamide, 10-30 parts of processing activator, 30-50 parts of acrylonitrile-butadiene-styrene, 5-10 parts of compatibilizer, 5-20 parts of toughener, 0.1-0.3 part of diffusion oil, 0.6-1.5 parts of antibacterial agent and 0.2-2 parts of auxiliaries. The antibacterial PA66 / ABS composite material is prepared through firstly, thoroughly mixing weighed polyhexamethylene adipamide, weighed processing activator, weighed acrylonitrile-butadiene-styrene, weighed compatibilizer and weighed diffusion oil in a high-speed mixer, then, adding the antibacterial agent and the auxiliaries into the mixture, and finally, adding the toughener into the mixture and carrying out thorough mixing, so as to obtain a premix; carrying out melt extrusion on the premix through a twin-screw extruder, and carrying out drawing, cooling and pelleting. The product provided by the invention has the advantages of easiness in processing, high antibacterial performance, excellent mechanical properties, and the like.

Description

technical field [0001] The invention belongs to the technical field of thermoplastic engineering plastics and its preparation, and in particular relates to an antibacterial nylon composite material and a preparation method thereof. Background technique [0002] Polyhexamethylene adipamide, commonly known as nylon 66 (PA66), is a thermoplastic engineering plastic widely used in automobiles, electronics, machinery and other fields. It has excellent wear resistance, impact resistance and self-lubricating properties. It is resistant to chemicals, but it is not resistant to strong alkali, and has high water absorption and creep. These shortcomings limit its application to a large extent. The PA66 / ABS composite material prepared by blending and modifying PA66 with acrylonitrile-butadiene-styrene (ABS) not only has the wear resistance, impact resistance and self-lubricating properties of nylon, but also has the toughness of ABS And rigidity, in addition to better surface matte eff...

Claims

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Application Information

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IPC IPC(8): C08L77/06C08L55/02C08L77/00C08L51/00C08L51/04C08L83/04C08K13/06C08K5/134C08K5/526C08K9/12C08K3/08
CPCC08L55/02C08L77/06C08L2205/02C08L2205/035C08L77/00C08L51/003C08L51/04C08L83/04C08K13/06C08K5/1345C08K5/526C08K9/12C08K2003/0806
Inventor 李雄武李方军黄彩霞朱志勇王雄刚
Owner ZHUZHOU TIMES NEW MATERIALS TECH
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