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Thermosetting resin composition, and resin varnish, metal foil with resin, resin film, metal-clad laminate, and printed wiring board using the same

A resin composition, thermosetting technology, applied in the direction of metal layered products, synthetic resin layered products, printed circuits, etc., can solve the problem that the signal propagation delay time and dielectric constant deviation between differential circuit wiring cannot be completely eliminated. , narrowing of the gap, etc., to achieve the effects of excellent heat resistance, suppression of variation in dielectric constant, and suppression of warpage of the substrate

Active Publication Date: 2017-02-15
PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] However, since the glass cloth forming the substrate material (prepreg) has a higher dielectric constant than the cured resin in the case of substrates through which high-speed and high-frequency signals exceeding 10 Gbps flow, there is a problem that in the presence of glass The part where the glass yarn is not present causes a local variation in the dielectric constant (Dk) in the substrate
In particular, in the high-frequency range, the single wavelength becomes millimeter units, so this deviation cannot be ignored, and there is a risk of adversely affecting high-level applications
[0007] So far, there have been reports of narrowing the gap between glass fibers, suppressing the variation in dielectric constant in the substrate surface, and suppressing the propagation delay time of signals by using an expanded glass cloth substrate. However, the gap between differential circuit wiring cannot be completely eliminated. Signal Propagation Delay Time

Method used

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  • Thermosetting resin composition, and resin varnish, metal foil with resin, resin film, metal-clad laminate, and printed wiring board using the same
  • Thermosetting resin composition, and resin varnish, metal foil with resin, resin film, metal-clad laminate, and printed wiring board using the same
  • Thermosetting resin composition, and resin varnish, metal foil with resin, resin film, metal-clad laminate, and printed wiring board using the same

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~9、 comparative example 1~3

[0169] In this example, the components used when preparing a thermosetting resin composition are demonstrated.

[0170] (A component: polyphenylene ether)

[0171] ·Modified PPE1: Modified polyphenylene ether obtained by the above synthesis method

[0172] (B: Styrene Butadiene Copolymer)

[0173] ・Styrene-butadiene copolymer (“Ricon 181 (product name)”, manufactured by CRAY VALLEY, styrene: 28% by mass, butadiene: 72% by mass; 1,2 vinyl in butadiene: 30% ; Number average molecular weight is 3200)

[0174] ・Styrene butadiene copolymer (SBR1): SBR1 obtained by the above synthesis method

[0175] Styrene butadiene copolymer (SBR2): SBR2 obtained by the above-mentioned synthesis method

[0176] Styrene butadiene copolymer (SBR3): SBR3 obtained by the above synthesis method

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PUM

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Abstract

The invention provides a thermosetting resin composition capable of preventing a variation in in-plane dielectric constants while retaining excellent dielectric characteristics of a hardened product of a resin composition and preventing curling (warping) of a substrate material. There is provided a thermosetting resin composition including: (A) a modified polyphenylene ether compound which is terminal-modified by using a substituent having a carbon-carbon unsaturated double bond at a molecular terminal; (B) a styrene-butadiene copolymer having a number average molecular weight less than 10,000 and including 1,2 vinyl having cross-linking properties in molecules; (C) a hardening accelerator; and (D) an inorganic filler, in which a compound ratio of (A) component:(B) component is in a range of 80:20 to 20:80.

Description

technical field [0001] The present invention relates to a thermosetting resin composition, a resin varnish using the same, a resin film, a resin-coated metal foil, a metal-clad laminate, a printed wiring board, and the like. Background technique [0002] In recent years, electrical devices have been required to have dielectric properties such as low dielectric constant and low dielectric loss tangent, which are required for high-speed communication, due to the increase in the capacity of signals in electrical equipment. [0003] It is known that polyphenylene ether (PPE) has excellent dielectric properties such as dielectric constant and dielectric loss tangent, and also has excellent dielectric properties in the high frequency band (high frequency region) from the MHz band to the GHz band. Therefore, studies have been conducted on the use of polyphenylene ether as, for example, a high-frequency molding material. More specifically, polyphenylene ether has been studied as a ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L71/12C08L9/06C08K5/14C08K3/36C09D171/12C09D109/06C09D7/12B32B15/08B32B15/082B32B27/18B32B27/26B32B27/20
CPCC09D7/61C09D7/63B32B15/08B32B15/082B32B27/18B32B27/20B32B27/26C08J5/18C08L9/06C08L71/126C09D5/18C09D109/06C09D171/12B32B2457/08C08J2371/12C08J2309/06C08J2471/12C08J2409/06C08L2203/20C08L2203/16C08L2201/08C08K5/14C08K3/36C08L25/10H05K1/0237H05K1/0373C08L2201/02
Inventor 林琳藤原弘明北井佑季
Owner PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD
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