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Fireproof soybean-based plate adhesive and preparing method thereof

An adhesive and soybean technology, applied in the directions of adhesives, adhesive additives, adhesive types, etc., can solve the problems that the water resistance of the adhesive does not work, it will endanger human health, and the product is not degradable, and it is difficult to achieve equipment. Corrosion, low hydrophilicity, and improved water resistance

Inactive Publication Date: 2016-12-07
QUANJIAO HAIFENG PRINTING PACKAGING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Aldehyde adhesives are used in the largest amount in wood industry adhesives, but they have many disadvantages: the main raw materials are mostly from non-renewable resources such as petroleum and coal; carcinogens (such as formaldehyde) are continuously emitted during production and use, which will harm the human body Healthy; the product is non-degradable and easy to pollute the environment
[0005] The current research methods all focus on modifying the soybean protein in it, but do not involve 40% carbohydrates, causing this component to have no effect on the water resistance of the adhesive after curing, or even have a negative effect, and waste raw materials

Method used

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Embodiment Construction

[0024] A kind of fireproof soybean-based board adhesive, it is made up of the raw material of following weight part:

[0025] Zinc hydroxystannate 3, polyvinyl alcohol 2, defatted soybean powder 170, ferric chloride 0.3, ferrous chloride 0.1, epichlorohydrin 0.8, N methylol acrylamide 2, styrene 16, potassium persulfate 0.1, Hemicellulase 3, polydiphenylmethane diisocyanate 10, 20% hydrochloric acid solution 60, decabromodiphenyl ether 1, polyphthalamide 0.6, diacetone alcohol 2, triethanolamine borate 0.7, poly Glycerol oleate 0.3, borax 2, tri-n-butyltetradecylphosphine chloride 1, sodium lignosulfonate 1, triphenylphosphine 0.1.

[0026] A kind of preparation method of described fireproof soybean base material adhesive, comprises the following steps:

[0027] (1) Mix the above-mentioned ferric chloride and ferrous chloride, add to 20% hydrochloric acid solution, stir evenly to obtain ferric salt solution;

[0028] (2) Add the above-mentioned sodium lignosulfonate to deion...

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PUM

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Abstract

The invention discloses a fireproof soybean-based plate adhesive. The fireproof soybean-based plate adhesive is prepared from, by weight, 3-4 parts of zinc hydroxystannate, 2-4 parts of polyvinyl alcohol, 170-200 parts of defatted soybean powder, 0.3-0.4 part of ferric chloride, 0.1-0.2 part of ferrous chloride, 0.8-1 part of epoxy chloropropane, 2-3 parts of N-hydroxymethyl acrylamide, 16-20 parts of styrene, 0.1-0.2 part of potassium persulfate, 3-4 parts of hemicellulase, 10-19 parts of poly diphenylmethane 4,4'-diisocyanate, 60-70 parts of a hydrochloric acid solution with the concentration of 20-30%, 1-2 parts of deca-brominated diphenyl ether, 0.6-1 part of polyphthalamide, 2-3 parts of diacetone alcohol, 0.7-1 part of triethanolamine borate and the like. The styrene copolymerization modified soybean-based adhesive has the advantages of being not likely to cause corrosion of equipment, long in shelf and storage period, free of formaldehyde, low in content of residual monomers, high in environment friendliness and water resistance and the like.

Description

technical field [0001] The invention relates to the technical field of adhesives, in particular to a fire-resistant soybean base material adhesive and a preparation method thereof. Background technique [0002] Aldehyde adhesives are used in the largest amount in wood industry adhesives, but they have many disadvantages: the main raw materials are mostly from non-renewable resources such as petroleum and coal; carcinogens (such as formaldehyde) are continuously emitted during production and use, which will harm the human body Healthy; the product is non-degradable and easy to pollute the environment. Therefore, the research and development of biomass-based adhesives to replace aldehyde-based adhesives has received global attention. Among various biomass materials, soybeans (including genetically modified soybeans) have the characteristics of large yield, low cost, and high plant protein content, and are good raw materials for adhesives; study soybean-based adhesives to make...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J151/00C09J11/08C09J11/06C09J11/04
CPCC09J151/00C08L2201/02C08L2205/035C09J11/04C09J11/06C09J11/08
Inventor 毕全中
Owner QUANJIAO HAIFENG PRINTING PACKAGING
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