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Polymerizable composition comprising compound having mesogenic group, and polymer thereof

A technology for polymerizable compositions and compounds, applied in the directions of liquid crystal materials, nonlinear optics, chemical instruments and methods, etc., can solve the problems of increased components, easy formation of polymers, and changes in composition viscosity, and achieves high increases and is not easy to change color. , good orientation effect

Active Publication Date: 2016-10-12
DIC CORPORATION
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When an optically anisotropic body that has discolored or is prone to discoloration is used, for example, in liquid crystal displays, etc., for purposes such as widening the viewing angle and switching polarization, there is a problem that the brightness and / or contrast of the display decreases. , or with the use of the monitor, the color of the image changes, and the quality of the monitor product is greatly reduced
[0004] Furthermore, in this field, various polymeric compounds have been reported, and an optically anisotropic body is produced using a composition containing the above polymeric compound, but the composition containing those polymeric compounds has the following problems: It is easy to generate high molecular (polymer) components, and the storage stability is not enough
When using a composition that easily generates a polymer (polymer) component, there is a high possibility that the polymer (polymer) component will increase during storage or transportation from the preparation of the composition to the process of producing the polymer
In this case, there is a problem that the viscosity and the like of the composition change, which affects optical properties such as transmittance and discoloration of the polymer obtained by using the composition.

Method used

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  • Polymerizable composition comprising compound having mesogenic group, and polymer thereof
  • Polymerizable composition comprising compound having mesogenic group, and polymer thereof
  • Polymerizable composition comprising compound having mesogenic group, and polymer thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1～30、 comparative example 1～30

[0426]

[0427] As the compound having a mesogenic group in the polymerizable liquid crystal composition, the compound represented by formula (A1) was prepared in a ratio of 34%, the compound represented by formula (A2) in a ratio of 10%, and the compound represented by formula (A2) in a ratio of 28%. A material (M1) containing the compound represented by the formula (B1) and the compound represented by the formula (B2) in a ratio of 28%. The YI / Δn values ​​of each compound are shown in Table 1. The yellowness of this material, that is, the material (M1) obtained by combining all the compounds having mesogenic groups in the polymerizable liquid crystal composition was 2.24, and YI / Δn was 15.7. In addition, regarding the yellowness of this material (M1), the material (M1) was dissolved in the tetrahydrofuran solution so that it may become a 20% solution, and it measured similarly to the measuring method of the said compound. In addition, regarding the refractive index anisot...

Embodiment 2～21

[0429]

[0430] In the same manner as the preparation of the liquid crystal composition of Example 1, the preparation contained the formulas (A1) to (A13) and formulas (B1) to (B10) shown in Tables 1 to 16 in the ratios shown in the tables. Compound materials (M2) to (M60). Moreover, YI and the value of YI / Δn of materials (M2)-(M60) were measured similarly to material (M1).

Embodiment 1

[0431] In the liquid crystal composition of Example 1, the material (M1) is replaced by materials (M2)-(M11), (M14)-(M17), (M31)-(M41), (M44)-(M47), Other than that, it carried out similarly to the liquid crystal composition of Example 1, and obtained the liquid crystal composition of Examples 2-11, 14-17, Comparative Examples 1-11, 14-17.

[0432] In addition, in the liquid crystal composition of Example 1, material (M1) is replaced by materials (M13), (M22)-(M28), (M43), (M52)-(M58), and (H1) is further set Except having been 0.1 part, it carried out similarly to the liquid crystal composition of Example 1, and obtained the liquid crystal composition of Example 13, 22-28, and Comparative Examples 13, 22-28.

[0433] In addition, in the liquid crystal composition of Example 1, material (M1) was replaced with material (M12) and material (M42), respectively, and 11.0 parts of material (C6) was further added. In addition, the liquid crystal composition of Example 1 was combined ...

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Abstract

The present invention is a polymerizable composition that comprises a compound having a mesogenic group, and that satisfies formula (1) 1.0>=YI / [Delta]n<=50.0 (in the formula, YI represents the yellowness index of the material consisting of the compound having a mesogenic group in the polymerizable composition, [Delta]n represents the refractive index anisotropy of the material consisting of the compound having a mesogenic group in the polymerizable composition, and the aforementioned material consisting of the compound having a mesogenic group excludes chiral compounds having a mesogenic group). When the polymerizable composition is added to polymerizable liquid crystal compositions, the polymerizable composition is not susceptible to an increase in polymer components, has excellent storage stability, and, when used as an optically anisotropic body, has excellent adhesion to a substrate, is not susceptible to discoloration, and has good coating properties and orientation properties.

Description

technical field [0001] The present invention relates to a polymerizable composition having a value of YI / Δn in a specific range, a polymer obtained by polymerizing it, an optically anisotropic body, and a retardation film, and further relates to a composition having a polymer, an optically anisotropic body , and retardation films, display devices, optical elements, light emitting devices, printed matter, optical information recording devices, and the like. Background technique [0002] The polymerizable liquid crystal composition is useful as a constituent member of an optically anisotropic body, and the optically anisotropic body is used in various display devices, optical elements, and the like as polarizing films and retardation films, for example. The polarizing film and the retardation film are obtained by coating a polymerizable liquid crystal composition on a substrate, orienting the polymerizable liquid crystal composition with an alignment film, etc., heating in thi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G02F1/13363C09K19/38C09K19/54G02B5/30
CPCC09K19/02C09K19/322C09K19/3411C09K2019/0448C09K2019/2035C09K2019/2078C09K2019/2092C09K2019/3083C09K19/2014C09K19/3804C09K19/3833G02B5/30C09K2019/3413
Inventor 山本美花堀口雅弘桑名康弘
Owner DIC CORPORATION
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