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Nano-indium modified transparent heat-insulating nano glass coating and preparation method thereof

A nano-glass and nano-indium technology, applied in anti-corrosion coatings, polyurea/polyurethane coatings, coatings, etc., can solve the problems of affecting the heat insulation effect, wrinkling and falling off, nano-indium tin oxide denaturation, etc., to prevent water absorption denaturation, The effect of preventing oxidative deterioration and making the coating film transparent

Inactive Publication Date: 2016-08-24
ANHUI RONGCHENG GLASS PROD CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, the coating film has certain water absorption and water permeability. After absorbing water, it is easy to cause wrinkles and fall off. Nano-indium tin oxide will be denatured under the action of long-term water, which will affect the heat insulation effect. Water resistance needs to be improved.
[0004] In addition, there are still some problems to be solved in the glass coating film, such as heat resistance, wear resistance, antistatic property, toughness, antibacterial property, acid and alkali resistance, transparency, scratch resistance, environmental performance, radiation resistance, anti-discoloration , Flame retardancy, UV resistance and other properties will have different requirements in different occasions. The current coatings still cannot meet the needs of all environments, and the performance needs to be further improved to meet the needs of production.

Method used

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Embodiment Construction

[0014] A nano-indium modified transparent heat-insulating nano-glass coating, made of the following raw materials in parts by weight (kg): 20 nanometer antimony tin oxide, dispersant SN-5040 0.2, water-based polyurethane resin 79, deionized water 30, N, N'-dimethylformamide 40, 20% sulfuric acid solution 20, perfluorooctanoic acid 20, methyl methacrylate 3, potassium persulfate 0.1, isocyanate 3, nano-indium 0.7, 10-undecylenic acid 0.4, ferrocene Formaldehyde 0.4.

[0015] The preparation method of the nano-indium modified transparent heat-insulating nano-glass coating comprises the following steps:

[0016] (1) Mix nano-tin antimony oxide and perfluorooctanoic acid into N,N'-dimethylformamide, ultrasonicate for 30 minutes, then add sulfuric acid solution dropwise while stirring, and then heat to 80°C and stir for 20 minutes to complete the reaction. After the reaction, filter and vacuum dry to obtain fluorinated nano-indium tin oxide;

[0017] (2) Add dispersant SN-5040 an...

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PUM

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Abstract

The invention discloses nano-indium modified transparent heat-insulating nano glass coating, made from the following materials according to parts by weight: 20-21 parts of nano antimony tin oxide, 0.2-0.3 part of dispersant SN-5040, 79-81 parts of waterborne polyurethane resin, 30-35 parts of deionized water, 40-50 parts of N,N'-dimethylformamide, 20-22 parts of 20% sulfuric acid solution, 20-22 parts of perfluoro caprylic acid, 3-4 parts of methyl methacrylate, 0.1-0.2 part of potassium persulfate, 3-3.5 parts of isocyanate, 0.7-0.9 part of nano-indium, 0.4-0.6 part of 10-undecylenic acid, and 0.4-0.6 part of ferrocenecarboxaldehyde. By using the nano-indium, 10-undecylenic acid and ferrocenecarboxaldehyde in mixture modifying, compatibility of the nano-indium with resin is improved, the nano-indium is dispersed more homogenously, a coating film is clearer, antioxidant performance of the nano-indium is improved, and the nano-indium is protected from affected clarity due to oxidative deterioration.

Description

technical field [0001] The invention relates to the technical field of glass coatings, in particular to a nano-indium modified transparent heat-insulating nano-glass coating and a preparation method thereof. Background technique [0002] As society pays more and more attention to energy saving and environmental protection requirements, insulating glass that can be used in different places has become a common demand of people, but the existing insulating glass has the disadvantages of imperfect performance, complicated process or high cost. Nano antimony tin oxide (ATO) has good visible light transmittance and infrared barrier, and is an ideal heat insulation material. The method of adding nano-tin antimony oxide into the paint to make a transparent heat-insulating paint can effectively solve the heat-insulating problem of glass. Compared with similar products, it has the advantages of simple process and low cost, and has extremely high application value and broad application...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D175/04C09D7/12C09D5/08
CPCC08K3/08C08K3/22C08K3/2279C08K9/04C08K13/06C08K2003/2231C08K2201/011C08K2201/014C09D5/08C09D7/62C09D175/04
Inventor 程言俊
Owner ANHUI RONGCHENG GLASS PROD CO LTD
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