A kind of preparation method of glass conductive fiber with cuprous sulfide as conductive layer

Abstract

The invention discloses a preparation method of conductive glass fibers with cuprous sulfide as a conductive layer and belongs to the field of preparation of composite conductive fibers. According to the method, firstly, glass fibers which are washed clean are subjected to hydroxylation treatment in a hydrochloric acid solution and soaked in a silk fibroin aqueous solution, crosslinking is performed through glutaraldehyde, and accordingly, firm silk fibroin layers are formed on surfaces of the glass fibers; finally, copper sulfate pentahydrate and sodium thiosulfate are taken as raw materials and subjected to a chemical reaction, and then cuprous sulfide is produced on surfaces of the glass fibers. With the adoption of the method, adsorption of metal sulfides on the surfaces of the glass fibers is effectively improved, the interface adhesion is high, and the method has the advantages that the preparation process condition is easy to guarantee, the cost is saved, the conductive performance of the fibers is excellent and the like.

Description

technical field [0001] The invention belongs to the field of preparation of composite conductive fibers, in particular to a method for preparing glass conductive fibers with cuprous sulfide as a conductive layer. Background technique [0002] Glass fiber exhibits a series of excellent properties that make it an indispensable raw material for industries such as electronics, electrical, chemical, metallurgy, construction, transportation, environmental protection, national defense, etc. Therefore, glass fiber is increasingly valued by people. In recent years, with the development of new energy technology and photovoltaic technology, people have begun to use electrically insulating glass as a substrate to prepare nano-films of new functional materials for light, electrocatalysis and photoelectric conversion. [0003] Conductive glass fiber is coated with a conductive layer on the surface of glass fiber to make it have superior conductivity. The way to make the glass fiber have ...

AI Technical Summary

Problems solved by technology

Because the cyano group on the polyacrylonitrile fiber can complex with copper ions, the fiber has conductivity; the surface of ordinary glass fiber lacks groups that complex with copper ions, and the conductive substance cannot complex with the fiber, so it affects The adsorption and adsorption fastness of fibers to metal sulfides are affected, so fibers with excellent electrical conductivity cannot be obtained.