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Quantum dot assembly as well as preparation method and application thereof

A technology of quantum dots and quantum dot materials, applied in the field of quantum dot components and their preparation, can solve the problems of affecting the light transmittance of the water-oxygen barrier film, affecting the brightness of the quantum dot film passing through, etc. The effect of low brightness and water oxygen transmittance

Inactive Publication Date: 2016-07-13
HISENSE VISUAL TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] Due to the characteristic that quantum dot materials are prone to failure due to contact with water vapor and oxygen, water and oxygen barrier treatment is required during use. In the prior art, quantum dot materials are usually distributed in an organic matrix to form a quantum dot film, and then The two surfaces of the dot film are provided with a water-oxygen barrier diaphragm (for preventing water and oxygen from permeating); wherein, the water-oxygen barrier diaphragm is usually made of Al 2 o 3 Inorganic coatings are formed on the surface of the PET film. It can be seen that the existence of the coating will affect the light transmittance of the water-oxygen barrier film, thereby affecting the brightness of the quantum dot film.

Method used

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  • Quantum dot assembly as well as preparation method and application thereof
  • Quantum dot assembly as well as preparation method and application thereof
  • Quantum dot assembly as well as preparation method and application thereof

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Embodiment 1

[0030] Figure 2A It is a schematic flow chart of Embodiment 1 of the preparation method of the quantum dot component of the present invention. In the embodiment of the present invention, a microemulsion method is used to prepare a quantum dot assembly with a core-shell structure. Such as Figure 2A As shown, the preparation method of the quantum dot assembly of this embodiment may include:

[0031] Step 1), put the polyethylene glycol ether and the organic solvent into the first container, undergo emulsification, dispersion and stirring treatment in turn until transparent, and obtain the first dispersion liquid.

[0032] In this step, a certain amount of polyethylene glycol ether and an organic solvent are put into a first container (such as a flask), and are sequentially emulsified, dispersed, and stirred until transparent to obtain a first dispersion; optionally, the polyglycol ether The ratio of glycol ether and organic solvent is 1:3~1:5; Optionally, described polyethy...

Embodiment 2

[0047] image 3 It is a schematic flow chart of Embodiment 2 of the preparation method of the quantum dot component of the present invention. In the embodiment of the present invention, a sol-gel method is used to prepare a quantum dot assembly with a core-shell structure. Such as image 3 As shown, the preparation method of the quantum dot assembly of this embodiment may include:

[0048] Step 1), put the quantum dot material into the first container filled with absolute ethanol for emulsification and dispersion, and add diethylamine, diethyl orthosilicate, water and ethanol sequentially under stirring to obtain the first mixed liquid; wherein, the volume of the diethylamine is 0.8%-1.5% of the preset volume, the volume ratio of the volume of the diethylamine to the diethyl orthosilicate is 1:9, the water and The volume of the mixed solution of ethanol is the same as that of the mixed solution of diethylamine and diethyl orthosilicate, and both are 8%-10% of the preset vol...

Embodiment 3

[0061] An embodiment of the present invention provides a quantum dot assembly with a core-shell structure prepared according to the method for preparing a quantum dot assembly described in the first or second embodiment above, wherein the core of the quantum dot assembly with a core-shell structure is a quantum dot group, the shell is SiO 2 , the quantum dot group includes one or more quantum dots. Visible, due to SiO 2 Compact structure, low water and oxygen transmission rate, optical transparency and light-gathering and astigmatism effects, using thin-layer silicon dioxide (SiO 2 ) As a core-shell quantum dot component obtained by coating the quantum dot group with a shell, it not only has high water and oxygen barrier properties, high light transmittance, and SiO 2 The shell has a certain divergence and brightening effect on light, which further improves the brightness of the quantum dot film composed of these core-shell quantum dot components.

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Abstract

The invention provides a quantum dot assembly as well as a preparation method and application thereof. The preparation method comprises the following steps: (1) putting polyglycol ether and an organic solvent in a first container, and sequentially performing emulsifying, dispersing, and stirring treatment till a solution is transparent, so as to obtain first dispersion fluid; (2) dispersing a quantum dot material in a dispersing agent in a second container, and performing stirring and dispersing so as to obtain second dispersion fluid; (3) pouring the first dispersion fluid and the second dispersion fluid in a third container, performing mixing and stirring until the solution in the third container is transparent, adding water, and performing ultrasonic dispersion so as to obtain a first microemulsion system; (4) adding strong ammonia water and ethyl orthosilicate to the first microemulsion system, and performing ultrasonic dispersion and mixing and a reaction so as to obtain a second microemulsion system; (5) sequentially performing demulsification treatment and centrifugation treatment on the second microemulsion system so as to obtain precipitates, then sequentially washing the precipitates, and performing vacuum drying on the washed precipitates so as to obtain the quantum dot assembly adopting a nucleocapsid structure. The prepared quantum dot assembly adopting the nucleocapsid structure is high in transmittance.

Description

technical field [0001] The invention relates to the technical field of high color gamut liquid crystal backlight modules, in particular to a quantum dot component and its preparation method and application. Background technique [0002] With the development of electronic products, consumers have higher and higher requirements for the picture quality of TVs, and high color gamut TVs quickly occupy the position of flagship products of major TV brands. At present, the mainstream method to achieve about 100% NTSC high color gamut is quantum dot technology. [0003] Due to the characteristic that quantum dot materials are prone to failure due to contact with water vapor and oxygen, water and oxygen barrier treatment is required during use. In the prior art, quantum dot materials are usually distributed in an organic matrix to form a quantum dot film, and then The two surfaces of the dot film are provided with a water-oxygen barrier diaphragm (for preventing water and oxygen from...

Claims

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Application Information

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IPC IPC(8): C09K11/88C09K11/54C09K11/02B82Y30/00B82Y20/00C08L63/00C08L33/12C08L25/06C08K9/10C08K3/30C08J5/18H01L33/56
CPCC09K11/883B82Y20/00B82Y30/00C08J5/18C08J2325/06C08J2333/12C08J2363/00C08L25/06C08L33/12C08L63/00C08L2205/025C08L2205/03C08L2205/035C09K11/025C09K11/54H01L33/56
Inventor 刘振国宋志成杜强
Owner HISENSE VISUAL TECH CO LTD
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