Composite scale and corrosion inhibitor, and applications thereof in circulated cooling water treatment
A technology of scale and corrosion inhibitor and cyclodextrin, which is used in composite scale and corrosion inhibitor and its application in circulating cooling water treatment, to avoid environmental problems, have good scale and corrosion inhibition performance, and meet the requirements of scale and corrosion inhibition. The effect of eclipse requirements
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Embodiment 1
[0045] Weigh 30.0g carboxymethyl inulin (the degree of substitution is 1.0), 10.0g α-cyclodextrin (purchased from Shandong Binzhou Zhiyuan Biotechnology Co., Ltd.) and 18.0g polyepoxysuccinic acid (limiting viscosity at 30°C 0.078dl / g), add 42.0g of water, and shake well to obtain composite scale and corrosion inhibitor stock solution S1.
[0046] Take 1g of the prepared composite scale and corrosion inhibitor stock solution S1 and add it to 10L of test water 1, so that the effective concentrations of carboxymethyl inulin, α-cyclodextrin and polyepoxysuccinic acid in the water are 6mg / L and 10mg respectively / L and 9mg / L, and then measure the calcium carbonate scale inhibition performance and corrosion inhibition performance according to the method in the test example.
Embodiment 2
[0048] Weigh 3.14g of zinc chloride, dissolve it in 9.0g of polyaspartic acid (limited viscosity number is 0.074dl / g at 30°C), then add 15.0g of carboxymethyl inulin raw material (degree of substitution is 0.6) and 18.0 gγ-cyclodextrin (purchased from Shandong Binzhou Zhiyuan Biotechnology Co., Ltd.), and then add 34.86 g of water, and shake well to obtain the composite scale and corrosion inhibitor stock solution S2.
[0049] Take 0.8g of the prepared composite scale and corrosion inhibitor stock solution S2 and add it to 10L of test water 2 or 10L of test water 3, so that the concentration of carboxymethyl inulin, γ-cyclodextrin, polyaspartic acid and zinc ions in the water The effective concentrations are 3mg / L, 18mg / L, 4.5mg / L and 1.5mg / L respectively, and then the calcium carbonate scale inhibition performance is measured according to the method in the test example.
[0050] Use sulfuric acid to adjust the pH value of the test water 2 to 7.8-8.3, then add the compound sca...
Embodiment 3
[0052] Weigh 1g of benzotriazole, dissolve it in 12g of polyaspartic acid (at 30°C, the limiting viscosity is 0.079dl / g), then add 80.0g of carboxymethyl inulin (the degree of substitution is 0.8) and Add 6.0g of β-cyclodextrin (purchased from Shandong Binzhou Zhiyuan Biotechnology Co., Ltd.), and then add 21g of water, and shake well to obtain the composite scale and corrosion inhibitor stock solution S3.
[0053] Take 1.2g of the prepared composite scale and corrosion inhibitor stock solution S3 and add it to 10L of test water 1, so that the effective concentration of carboxymethyl inulin, β-cyclodextrin, polyaspartic acid and benzotriazole in the water They are 16mg / L, 6mg / L, 6mg / L and 1mg / L respectively, and then the calcium carbonate scale inhibition performance and corrosion inhibition performance are measured according to the method in the test example.
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