Polymer with surface active function and preparation method thereof
A surface-active, polymer technology, applied in drilling compositions, chemical instruments and methods, etc., can solve the problems of blockage of reservoir voids, slow development of medium and low permeability reservoirs, and high injection pressure, and achieve strong viscosity enhancement. , Increase the effect of oil washing, improve the effect of the sweep coefficient
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[0030] The present invention also provides a method for preparing a polymer with surface-active functions, the method comprising: under the conditions of a pH value of 6-10, under polymerization conditions, the monomer represented by formula (4), The monomer shown in formula (5), the monomer shown in formula (6), the solution that water, complexing agent and auxiliary agent form contact with initiator, with the total consumption mole number of monomer in the described polymkeric substance as Standard, the amount of the monomer shown in the formula (4) is 8-45 mol%, the amount of the monomer shown in the formula (5) is 50-91 mol%, and the amount of the monomer shown in the formula (6) The amount of the monomer used is 0.001-5 mole %; the conditions of the polymerization reaction make the viscosity-average molecular weight of the polymer obtained after the polymerization reaction be 10 million-28 million; wherein, R 1 , R 2 , R 3 , R 4 and R 5 The same or different, each ind...
preparation example 1
[0066] This preparation example is used to illustrate the synthetic method of the monomer shown in the formula (6) in the embodiment 1:
Embodiment 1
[0069] In this embodiment, the method provided by the present invention is used to prepare the polymer 1-A with surface active function provided by the present invention, wherein the monomer described in formula (4) is 2-acrylamido-2-methylpropanesulfonic acid The monomer described in formula (5) is acrylamide; m=1, n=3, p=1 in the monomer (hereinafter also referred to as functional monomer) described in formula (6), R is CF 3 , R 5 It is H, M is H, and its molecular weight is 458.
[0070] Specifically, this embodiment adopts the following method to carry out:
[0071] 1) Add acrylamide (166.2mmol), 2-acrylamido-2-methylpropanesulfonic acid (38.6mmol) and functional monomer (0.4mmol) into the polymerization reaction bottle (ie polymerization bottle), add deionized 50.0 g of water was dissolved to form an aqueous solution, and then sodium hydroxide was added to adjust the pH value to 8.0 to obtain a mixture solution;
[0072] 2) Add 1.0 g of 1% by weight EDTA-2Na aqueous so...
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