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Process for producing high yield methyl isocyanate

A technology of methyl isocyanate and production process, which is applied in the field of production technology for improving the yield of methyl isocyanate monomer, can solve problems such as unfavorable production of methyl isocyanate, high cost, complexity, etc., achieves a friendly natural environment, reduces labor intensity, The effect of inhibiting self-aggregation

Active Publication Date: 2016-03-23
海利贵溪新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

These methods are too complex and costly for the economical production of methyl isocyanate

Method used

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  • Process for producing high yield methyl isocyanate
  • Process for producing high yield methyl isocyanate
  • Process for producing high yield methyl isocyanate

Examples

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Embodiment Construction

[0014] In the conventional production process of heating methylcarbamoyl chloride solution in a decomposer to decompose and generate methyl isocyanate, it is generally believed that the molecular weight of methyl isocyanate is small and difficult to polymerize, and it is generally believed that the polymerization inhibitor is only good for polymers with relatively large molecular weights. Therefore, no one in the prior art has tried to use a polymerization inhibitor in the process of heating carbamoyl chloride solution to decompose and generate methyl isocyanate. The inventor unexpectedly discovered in the experiment that adding a polymerization inhibitor under specific conditions can effectively reduce the formation of methyl isocyanate trimer, prevent process pipeline blockage, and help ensure the continuity of production and reduce production costs.

[0015] The technical solutions of the present invention will be further described below in conjunction with examples and comp...

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Abstract

The invention discloses a process for producing high yield methyl isocyanate. Trimerization methyl isocyanate is effectively reduced by adding a polymerization inhibitor to methyl isocyanate which is produced when a methylamine formyl chloride solution is heated in a decomposer and decomposed. The process for producing the high yield methyl isocyanate is simple in process operation, reduces nearly 60% production rate of terpolyesters, and reduces production cost. The process for producing the high yield methyl isocyanate can prevent a process pipeline from being plugged simultaneously, is excellent in production fluency, reduces labor strength of solid waste, improves work environment, is friendly in natural environment, reduces solid waste, and reduces production cost by about 3%.

Description

technical field [0001] The invention relates to a production process for increasing the yield of methyl isocyanate monomer. Background technique [0002] Methyl isocyanate is a widely used chemical raw material and an important intermediate for the synthesis of pharmaceuticals or pesticides. [0003] The general production of methyl isocyanate mainly has four steps of chemical reactions. Oxygen reacts with coke to generate carbon monoxide, carbon monoxide reacts with chlorine to generate phosgene, phosgene reacts with monomethylamine to generate carbamoyl chloride, and carbamoyl chloride is dissolved in a solvent In the decomposer, it is heated and decomposed to generate methyl isocyanate. During the heating process, part of the methyl isocyanate self-polymerizes to generate trimeric methyl isocyanate. The daily production of 10,000L methyl isocyanate can produce about 400 kg of solid waste trimer, which is blocked The process pipeline, the production is not smooth, and the...

Claims

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Application Information

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IPC IPC(8): C07C263/04C07C265/04
CPCC07C263/04C07C265/04
Inventor 尹霖陈军彭立宏雷粮林涂小妹王小宝邵剑江百巨雷华珍毛林生李龙水汪皆辉朱杰彭军刘胜
Owner 海利贵溪新材料科技有限公司
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