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Hybrid curing peelable coating material and preparation method thereof

A hybrid curing and coating technology, used in anti-corrosion coatings, epoxy resin coatings, polyurea/polyurethane coatings, etc., can solve the problems of easy inhibition by oxygen, poor adhesion, low precision, etc., and achieves short drying time, easy Control, the effect of drying faster

Inactive Publication Date: 2016-03-09
SHANGHAI INSTITUTE OF TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The free radical photocuring system has the advantages of fast curing speed and easy adjustment of properties, but there are also problems such as severe shrinkage, low precision, poor adhesion, easy to be inhibited by oxygen, and difficult to cure in dark environments, which limit its practical application.

Method used

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  • Hybrid curing peelable coating material and preparation method thereof
  • Hybrid curing peelable coating material and preparation method thereof
  • Hybrid curing peelable coating material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] A kind of hybrid cured strippable coating, calculated by weight, its raw material composition and content are as follows:

[0040]

[0041] Wherein, the epoxy resin is a mixture of Daicel CEL2021P and TTA22 cycloaliphatic epoxy resin provided by Jiangsu Taitel New Material Technology Co., Ltd. in a mass ratio of 2:1;

[0042] Described UV curable resin is the mixture that epoxy acrylate and polyurethane acrylate form by mass ratio 2:1;

[0043] Described photoinitiator A is BASF Irgacure184D, Irgacure369, Irgacure819, the mixture that forms by mass ratio 1:1:1;

[0044] The photoinitiator B is the photoinitiator sulfonium salt Easepi6992 provided by Shanghai Guangyi Chemical Company;

[0045] The UV leveling agent is German BYK BYK-348;

[0046] Described UV dispersant is the NP-100 of U.S. Dow Company;

[0047] Described defoamer is the NopcoNXZ of German Henkel Company;

[0048] Described fumed silica is German Degussa hydrophobic silica R972;

[0049]The abov...

Embodiment 2

[0054] A kind of hybrid cured strippable coating, calculated by weight, its raw material composition and content are as follows:

[0055]

[0056]

[0057] Wherein, the epoxy resin is JZ-501 epoxy resin of Nanjing Jiazhong Chemical Technology Co., Ltd.;

[0058] The UV curable resin is polyurethane acrylate;

[0059] Described photoinitiator A is the mixture that BASF Irgacure1173 and IrgacureTPO form by mass ratio 1:1;

[0060] The photoinitiator B is a mixture of photoinitiator sulfonium salt Easepi6992 and Irgacure250 provided by Shanghai Guangyi Chemical Co., Ltd. in a mass ratio of 1:1;

[0061] The UV leveling agent is German BYK-344;

[0062] Described UV dispersant is German BYK333 leveling agent;

[0063] Described defoamer is the NopcoNXZ of German Henkel Company;

[0064] The fumed silica is Cabot fumed silica CAB-O-SILM-5;

[0065] The preparation method of the above-mentioned a kind of hybrid curing peelable coating specifically includes the following s...

Embodiment 3

[0070] A kind of hybrid cured strippable coating, calculated by weight, its raw material composition and content are as follows:

[0071]

[0072] The preparation method of this hybrid curing strippable coating comprises the following steps: according to the formula, add 1 part of UV dispersant and 0.3 part of defoamer in the GFJ-0.4 type high-speed disperser (Shanghai Xinnuo Instrument Equipment Co., Ltd.), and pass through 700r Disperse for 18 minutes at a rotating speed of 2100r / min, then add 16 parts of fumed silica, reduce the rotating speed to 300r / min, add 70 parts of epoxy resin, 70 parts of UV curable resin and the remaining 0.3 parts of defoamer, 1 part of UV dispersant, 0.08 parts of UV leveling agent, 4 parts of photoinitiator A, 4 parts of photoinitiator B, and stir evenly, continue to disperse for 8 minutes, after mixing evenly, pass through GS450 small vibrating screen (Laizhou Jingtai Chemical Machinery Factory) filter to remove the filter residue to obtain ...

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Abstract

The present invention belongs to the technical field of polymer materials, and particularly relates to a hybrid curing peelable coating material, wherein the raw materials comprise, by weight, 45-100 parts of an epoxy resin, 45-100 parts of a UV-curable resin, 0.05-0.1 part of a UV leveling agent, 1-3 parts of a UV dispersing agent, 0.2-1 part of a defoamer, 3-6 parts of a photoinitiator A, 3-6 parts of a photoinitiator B, and 10-20 parts of fumed silica. The preparation method comprises: adding partial UV dispersing agent and partial defoamer to a high-speed disperser, dispersing for 15-20 min at a rotation speed of 600-800 r / min, adding fumed silica, dispersing for 30-50 min at a rotation speed of 1600-2800 r / min, reducing the rotation speed to 300 r / min, adding an epoxy resin, a UV-curable resin, the remaining defoamer, the remaining UV dispersing agent, a UV leveling agent, a photoinitiator A and a photoinitiator B, uniformly stirring, continuously dispersing for 5-10 min, uniformly mixing, filtering, and removing the filter residue to obtain the product. According to the present invention, the hybrid curing peelable coating material of the present invention has a short drying time, the cured product has good rust resistance and the like, and the preparation method has characteristics of simple process and easy control.

Description

[technical field] [0001] The invention belongs to the technical field of polymer materials, in particular to a hybrid cured peelable coating and a preparation method thereof. [Background technique] [0002] Peelable paint is a temporary protective material with polymer as the main film-forming substance. It is sprayed on the surface of the object when it is used, and it will protect the object for a short time after the film is formed; The film layer is gently peeled off from the surface of the object to be coated by hand, which will not only cause no damage to the surface of the object to be coated, but also make the appearance of the original device as clean as new. Strippable coatings are widely welcomed by industries such as instruments, meters, home appliances, machinery, automobiles, and electronic appliances due to their convenient coating and easy peeling, and are developing rapidly. [0003] There are three types of current strippable coatings: 1. Solvent-based str...

Claims

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Application Information

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IPC IPC(8): C09D163/00C09D163/10C09D175/14C09D5/20C09D5/08C09D7/12
CPCC09D163/00C08L2205/02C08L2205/025C08L2205/035C08L2312/06C09D5/08C09D5/20C09D7/61C09D163/10C09D175/14C08L63/10C08L63/00C08L75/14C08K3/36
Inventor 张英强梁华丽李烨
Owner SHANGHAI INSTITUTE OF TECHNOLOGY
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